On the Crystal Structure of the Organic Charge-Transfer Salt Derived from Hexamethylenetetraselenafulvalene (HMTSF) and Tetrafluoro-7,7,8,8- Tetracyano-p-Quinodimethane (TCNQF4), HMTSF-TCNQF4

References

• Bloch , A. N. , Cowan , D. O. , Bechgaard , K. , Pyle , R. E. , Banks , R. H. and Poehler , T. O. 1975 . Phys. Rev. Lett. , 25 : 1561
   Google Scholar
• Phillips , T. E. , Kistenmacher , T. J. , Bloch , A. N. and Cowan , D. O. 1976 . J. Chem. Soc. Chem. Commun. , : 334
   Google Scholar
• Greene , R. L. , Mayerle , J. J. , Schumaker , R. , Castro , G. , Chaikin , P. M. , Etemad , S. and LaPlaca , S. J. 1976 . Solid State Commun. , 20 : 943
   Web of Science ®Google Scholar
• Chasseau , D. , Comberton , G. , Gaultier , J. and Hauw , C. 1978 . Acta Crystallogr. , B34 : 689 ;B. D. Silverman and S. J. LaPlaca, J. Chem. Phys., 69, 2585 (1978)
   Google Scholar
• Hawley , M. E. , Poehler , T. O. , Carruthers , T. F. , Bloch , A. N. , Cowan , D. O. and Kistenmacher , T. J. 1978 . Bull. Am. Phys. Soc. , 23 : 424 Aspects of the crystal structure and physical properties of HMTSF-TCNQF4 were first discussed in
   Google Scholar
• Tomkiewicz , Y. , Torrance , J. B. , Bechgaard , K. and Mayerle , J. J. 1979 . Bull. Am. Phys. Soc. , 24 : 232
   Google Scholar
• Torrance , J. B. , Mayerle , J. J. , Bechgaard , K. , Silverman , B. D. and Tomkiewicz , Y. 1980 . Phys. Rev. , B, 22 : 4960
   Google Scholar
• Torrance , J. B. , Tomkiewicz , Y. , Bozio , R. , Pecile , C. , Wolfe , C. R. and Bechgaard , K. 1982 . Phys. Rev. , B, 26 : 2267
   Google Scholar
• Kistenmacher , T. J. 1978 . Ann. N. Y. Acad. Sci. , 313 : 333 See, for example,
   Google Scholar
• Gleiter , R. , Kobayashi , M. , Spanget-Larsen , J. , Ferraris , J. P. , Bloch , A. N. , Bechgaard , K. and Cowan , D. O. 1975 . Ber. der Bunsen-Gesellschraft , 79 : 1218 See, for example: a)
   Web of Science ®Google Scholar
• Engler , E. M. , Kaufman , F. B. , Green , D. C. , Klots , C. E. and Compton , R. N. 1975 . J. Am. Chem. Soc. , 97 : 2921
   Web of Science ®Google Scholar
• Metzger , R. M. private communication
   Google Scholar
• Metzger , R. M. 1981 . J. Chem. Phys. , 74 : 3458
   Web of Science ®Google Scholar
• Bramwell , F. B. , Haddon , R. C. , Wudl , F. , Kaplan , M. L. and Marshall , J. H. 1978 . J. Am. Chem. Soc. , 100 : 4612 See, for example,
   Web of Science ®Google Scholar
• Emge , T. J. , Maxfield , M. , Cowan , D. O. and Kistenmacher , T. J. 1981 . Mol. Cryst. Liq. Cryst. , 65 : 161 See, for example,
   Web of Science ®Google Scholar
• Wiygul , F. M. , Ferraris , J. P. , Emge , T. J. and Kistenmacher , T. J. 1981 . Mol. Cryst. Liq. Cryst. , 78 : 279
   Web of Science ®Google Scholar
• Metzger , R. M. and Rhee , C. H. 1982 . Mol. Cryst. Liq. Cryst. , 85 : 1471
   Google Scholar
• Weyl , C. , Engler , E. M. , Bechgaard , K. , Jehanno , G. and Etemad , S. 1976 . Solid State Commun. , 19 : 925 For HMTSF-TCNQ, see:
   Web of Science ®Google Scholar
• Megtert , S. , Pouget , J. P. and Comes , R. 1978 . Molecular Metals Edited by: Hatfield , W. E. 87 – 103 . New York : Plenum Press . for HMTTF-TCNQ, see:, in, Ed., pp.
   Google Scholar
• Chappell , J. S. , Bloch , A. N. , Bryden , W. A. , Maxfield , M. , Poehler , T. O. and Cowan , D. O. 1981 . J. Am. Chem. Soc. , 103 : 2442
   Web of Science ®Google Scholar
• Pytte , E. 1974 . Phys. Rev. B , 10 : 4637
   Web of Science ®Google Scholar
• Jacobs , I. IS. , Bray , J. W. , Hart , H. R. , Interante , L. V. , Kasper , J. S. , Watkins , G. D. , Prober , D. E. and Bonner , J. C. 1976 . Phys. Rev. B , 14 : 3036 ()
   Web of Science ®Google Scholar
• Peierls , R. E. 1955 . Quantum Theory of Solids Oxford : Clarendon Press . ,“,”
   Google Scholar
• Bak , P. and Emery , V. J. 1976 . Phys. Rev. Lett. , 36 : 978
   Web of Science ®Google Scholar
• Bak , P. 1976 . Phys. Rev. Lett. , 37 : 1071
   Web of Science ®Google Scholar
• Bjelis , A. and Barisic , S. 1976 . Phys. Rev. Lett. , 37 : 1517
   Web of Science ®Google Scholar
• Wilson , A. J. C. 1942 . Nature , 150 : 151
   Google Scholar
• Hanson , H. P. , Herman , F. , Lea , J. D. and Skillman , S. 1964 . Acta Crystallogr. , 17 : 1040
   Web of Science ®Google Scholar
• Stewart , R. F. , Davidson , E. R. and Simpson , W. T. 1965 . J. Chem. Phys. , 42 : 3175
   Web of Science ®Google Scholar
• Cromer , D. T. and Liberman , D. 1970 . J. Chem. Phys. , 53 : 1891
   Web of Science ®Google Scholar
• Crystallographic programs employed include: Busing, Martin and Levy's ORFLS (modified); Zalkin's FORDAP; Pippy and Ahmed's MEAN PLANE; Johnson's ORTEP
   Google Scholar
• Herbstein , F. H. 1971 . Perspectives in Structural Chemistry Edited by: Dunitz , J. D. and Ibers , J. A. 166 – 395 . New York : John Wiley . in, Eds., pp.
   Google Scholar
• Details of the least-squares plane computations for the HMTSF donor and the TCNQF4 acceptor are given in the deposited materials. Briefly, the HMTSF donor is very slightly chair-shaped, with a central fulvalene plane [defined by Se (maximum deviation at 0.016(1) Å), C(1) and C(3) and their symmetry mates] given by the equation: –0.3721X + 0.0Y – 0.9282Z = 0.0 Å, where X, Y Z are orthogonal axes along a, b c*, respectively. The unique methylene carbon atoms C(2) and C(4) lie 0.031(5) and 0.088(6) Å out of the fulvalene plane. For the TCNQF4 acceptor, the entire molecular framework is quite planar [maximum deviation of 0.014(6) Å for C(6)] and described by the equation: –0.5702X + O. OY - 0.8215Z = -1.6167 Å
   Google Scholar
• Kistenmacher , T. J. , Rossi , M. , Urmey , W. F. , Carruthers , T. F. , Cowan , D. O. and Bloch , A. N. to be published
   Google Scholar
• Pauling , L. 1960 . The Nature of the Chemical Bond Ithaca : Cornell University Press .
   Google Scholar
• Kistenmacher , T. J. , Phillips , T. E. and Cowan , D. O. 1974 . Acta Crystallogr. , B30 : 763
   Google Scholar
• Haddon , R. C. 1975 . Aust. J. Chem. , 28 : 2333
   Web of Science ®Google Scholar
• Salahub , D. R. , Messmer , R. P. and Herman , F. 1976 . Phys. Rev. , 13 : 4252 B,
   Google Scholar
• Berlinsky , A. J. , Carolan , J. F. and Weiler , L. 1976 . Solid State Commun. , 19 : 1165
   Google Scholar
• Lowe , J. P. 1980 . J. Am. Chem. Soc. , 102 : 1262
   Web of Science ®Google Scholar
• Emge , T. J. , Wiygul , F. M. , Ferraris , J. P. and Kistenmacher , T. J. 1981 . Mol. Cryst. Liq. Cryst. , 78 : 295
   Web of Science ®Google Scholar
• Emge , T. J. , Wiygul , F. M. , Chappell , J. S. , Bloch , A. N. , Ferraris , J. P. , Cowan , D. O. and Kistenmacher , T. J. 1982 . Mol. Cryst. Liq. Cryst. , 87 : 137
   Web of Science ®Google Scholar
• Kistenmacher , T. J. , Emge , T. J. , Bloch , A. N. and Cowan , D. O. 1982 . Acta Crystallogr. , B38 : 1193
   Google Scholar
• Emge , T. J. , Bryden , W. A. , Wiygul , F. M. , Bloch , A. AN. , Cowan , D. O. and Kistenmacher , T. J. 1982 . J. Chem. Phys. , 77 : 3188
   Web of Science ®Google Scholar
• Shu , P. , Chiang , L. , Emge , T. , Holt , D. , Kistenmacher , T. , Lee , M. , Stokes , J. , Poehler , T. , Bloch , A. and Cowan , D. 1981 . J. Chem. Soc. Chem. Commun. , : 920
   Google Scholar
• Harms , R. H. , Keller , H. J. , Nothe , D. , Wehe , D. , Heimer , N. E. , Metzger , R. M. , Gundel , D. and Sixl , H. 1982 . Mol. Cryst. Liq. Cryst. , 85 : 249
   Web of Science ®Google Scholar
• Soos , Z. G. , Keller , H. J. , Ludolf , K. , Queckborner , J. , Wehe , D. and Flandrois , S. 1981 . J. Chem. Phys. , 74 : 5287
   Web of Science ®Google Scholar
• Johanson , H. 1975 . Int. J. Quant. Chem. , 9 : 459 See reference 27a and
   Google Scholar
• Hoekstra , A. , Spoelder , T. and Vos , A. 1972 . Acta Crystallogr. , B28 : 14 See, for example, and Ref. 28
   Google Scholar
• Burns , G. and Glazer , A. M. 1978 . Space Groups for Solid State Scientists New York : Academic Press . See, for example,“,”
   Google Scholar
• Friend , R. H. , Jerome , D. , Fabre , J. M. , Giral , L. and Bechgaard , K. 1978 . J. Phys. C. , 11 : 263 For pressure studies on HMTTF-TCNQ, see: .For similar studies on HMTSFTCNQ, see, for example: a) J. R. Cooper, M. Weger, D. Jerome, D. Lefur, K. Bechgaard, A. N. Bloch and D. O. Cowan, Solid State Commun., 19, 749 (1976)
   Web of Science ®Google Scholar
• Jerome , D. and Weger , M. 1976 . Chemistry and Physics of One-Dimensional Metals Edited by: Keller , H. J. 341 – 367 . New York : Plenum Press . , in, Ed., pp.
   Google Scholar