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- A negative activation energy does not imply the absence of any barrier. The reaction is still hampered by a barrier relative to the reactant complex and a statistical or entropic bottleneck associated with the decrease in the number of available quantum states as one goes from separate reactants to a more tightly bound transition state.
- Typical bond strengths: H–H: 104, C–H: 99, C–C: 83, C–Cl: 78 kcal mol−1, see: A.F. Holleman, N. Wiberg Lehrbuch der Anorganischen Chemie, de Gruyter Berlin 1985
- Extent of bond stretching in the TS: H–H: 85%, C–H: 47%, C–C: 26%, C–Cl: 9%