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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 38, 1979 - Issue 5
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Original Articles

Theory of light scattering from density fluctuations in a two-component reacting fluid

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Pages 1393-1410 | Received 14 Nov 1978, Published online: 23 Aug 2006

References

  • Berne , B.J. and Frisch , H.L. 1967 . J. chem. Phys. , 47 : 3675 – 3675 .
  • Berne , B.J. and Pecora , R. 1976 . Dynamic Light Scattering , John Wiley .
  • In contrast, chemical reactions do change the fluorescent cross-section of some chemical species; e.g., the fluorescent cross-section of ethydium bromide is very substantially changed by binding to deoxyribonucleic acid polymers. Such large changes in the fluorescent scattering cross-section have permitted the measurement of the rate coefficients for this reaction by means of fluorescence correlation spectroscopy Magde D. Elson E. Webb W.W. Phys. Rev. Lett. 1972 29 705 705
  • Alms , G.R. , Bauer , D.R. , Brauman , J.I. and Pecora , R. 1975 . J. chem. Phys. , 59 : 5321 – 5321 .
  • Madden , P. and Kivelson , D. 1975 . J. stat. Phys. , 12 : 167 – 167 .
  • Mori , H. 1965 . Prog. theor. Phys. Japan , 33 : 423 – 423 .
  • Mountain , R.D. and Deutch , J.M. 1976 . J. chem. Phys. , 50 : 1103 – 1103 .
  • Keyes , T. and Kivelson , D. 1972 . J. chem. Phys. , 56 : 1057 – 1057 .
  • Mountain , R.D. 1966 . J. Res. natn. Bur. Stand. A , 70 : 207 – 207 . 1968, Ibid., 72, 95. Weinberg, M., and Oppenheim, I., 1972, Physica, 61, 1.
  • Huang , M.N. and Schwarz , W.H. 1974 . J. chem. Phys. , 60 : 1813 – 1813 . calculated in detail the spectrum of the light scattered from the acetic acid monomer-dimer system under the assumption that the intrinsic polarizabilities of the monomer and dimer are not the same. Their computed spectra are qualitatively similar to those predicted here. They predict the spectrum to contain two unshifted lines (a sharp reactive line and a broad thermal diffusive line) with similar intensities near θ = 0.

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