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- Long range forces lead to free energy divergences in the thermodynamic limit. For potentials ϕ(r) ∼ r -λ for d = 3, bulk free energy density, surface tension and line tension diverge, respectively, when λ ˇ- 3, λ ˇ- 4 and λ ˇ- 5. See for example, Indekeu J.O. Int. J. mod. Phys. B 1994 8 309 309 According to its density functional expression, the divergence of κ occurs when λ ˇ- 6.
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- Robledo , A. and Varea , C. unpublished