Publication Cover
Spectroscopy Letters
An International Journal for Rapid Communication
Volume 40, 2007 - Issue 1: Spectrometry and Automation
45
Views
0
CrossRef citations to date
0
Altmetric
Original Articles

Rotational Dynamics of Excited Probes: Analysis of Rate Constants Based on the Predictions of Hydrodynamic Theory

, &
Pages 149-164 | Received 16 Sep 2005, Accepted 12 Jun 2006, Published online: 15 Feb 2011

References

  • Lakowicz , J. R. 1999 . Principles of Fluorescence Spectroscopy , 2nd Ed. 291 – 366 . New York : Kluwer Academic/Plenum .
  • Thulstrup , E. W. and Michl , J. 1986 . Spectroscopy with Polarized Light. Solute Alignment by Photoselection in Liquid Crystals, Polymers and Membranes Deerfield Beach : VCH Publishers .
  • Thulstrup , E. W. and Michl , J. 1989 . Elementary Polarization Spectroscopy Deerfield Beach : VCH Publishers .
  • Ansari , A. and Szabo , A. 1993 . Theory of photoselection by intense laser pulses. Influence of reorientational dynamics and chemical kinetics on absorbance measurements . Biophys. J. , 64 : 838 – 851 .
  • Szabo , A. 1984 . Theory of fluorescence depolarization in macromolecules and membranes . J. Chem. Phys. , 81 : 150 – 167 .
  • Magde , D. 1978 . Photoselection with intense laser pulses . J. Chem. Phys. , 68 : 3717 – 3733 .
  • Fleming , G. R. 1986 . Chemical Applications of Ultrafast Spectroscopy 155 – 200 . New York : Oxford University Press . Chapter 6
  • Sension , R. J. , Repinec , S. T. and Hochstrasser , R. M. 1991 . Femtosecond laser study of the alignment of reactant and products in the photoisomerization reactions of cis‐stilbene . J. Phys. Chem. , 95 : 2946 – 2948 .
  • Repinec , S. T. , Sension , R. J. , Szarka , A. Z. and Hochstrasser , R. M. 1991 . Femtosecond laser studies of the cis‐stilbene photoisomerization reactions. The cis‐stilbene to dihydrophenanthrene reaction . J. Phys. Chem. , 95 : 10380 – 10385 .
  • Sension , R. J. , Repinec , S. T. , Szarka , A. Z. and Hochstrasser , R. M. 1993 . Femtosecond laser studies of the cis‐stilbene photoisomerization reactions . J. Phys. Chem. , 98 : 6291 – 6315 .
  • Arnold , B. R. , Schill , A. W. and Poliakov , P. P. 2001 . Application of time‐resolved linear dichroism spectroscopy: relaxation of excited hexamethylbenzene/1,2,4,5‐tetracyanobenzene charge‐transfer complexes . J. Phys. Chem. A , 105 : 537 – 543 .
  • Barkley , M. D. , Kowalczyk , A. A. and Brand , L. 1981 . Fluorescence decay studies of anisotropic rotations of small molecules . J. Chem. Phys. , 75 : 3581
  • Singh , M. K. 2000 . Rotational relaxation of neutral red in alkanes: effect of solvent size on probe rotation . Photochem. Photobiol. , 72 : 438 – 443 .
  • Bessire , D. R. and Quitevis , E. L. 1994 . Effect of temperature and viscosity on rotational diffusion of Merocyanine 540 in polar solvents . J. Phys. Chem. , 98 : 13083 – 13092 .
  • Ho , N. , Kajimoto , O. and Hara , K. 2002 . High‐pressure studies of rotational dynamics for Coumarin 153 in alcohols and alkanes . J. Phys. Chem. A , 106 : 6024 – 6029 .
  • Brocklehurst , B. and Young , R. N. 1999 . Rotation of aromatic hydrocarbons in viscous alkanes. 1. methylcyclohexane . J. Phys. Chem. A , 103 : 3809 – 3817 .
  • Brocklehurst , B. and Young , R. N. 1999 . Rotation of aromatic hydrocarbons in viscous alkanes. 2. hindered rotation in squalane . J. Phys. Chem. A , 103 : 3818 – 3824 .
  • Jas , G. S. , Larson , E. J. , Johnson , C. K. and Kuczera , K. 2000 . Microscopic details of rotational diffusion of perylene in organic solvents: molecular dynamics simulation and experiment vs Debye‐Stokes‐Einstein theory . J. Phys. Chem. A , 104 : 9841 – 9852 .
  • Benzler , J. and Luther , K. 1997 . Rotational relaxation of biphenyl and p‐terphenyl in n‐alkanes: the breakdown of the hydrodynamic description . Chem. Phys. Lett. , 297 : 333 – 338 .
  • Szubiakowski , J. , Balter , A. , Nowak , W. , Kowalczyk , A. , Wisniewski , K. and Wierzbowska , M. 1996 . Anisotropic reorientation of perylene and 3,9‐dibromoperylene in glycerol: fluorescence anisotropy decay and quantum‐mechanical study . Chem. Phys. , 208 : 283 – 296 .
  • Xu , J. , Shen , X. and Knutson , J. R. 2003 . Femtosecond fluorescence upconversion study of the rotations of perylene and tetracene in hexadecane . J. Phys. Chem. A , 107 : 8383 – 8387 .
  • Hartman , R. S. , Alavi , D. S. and Waldeck , D. H. 1991 . An experimental test of dielectric friction models using the rotational diffusion of aminoanthraquinones . J. Chem. Phys. , 95 : 7872 – 7880 .
  • Horng , M.‐ L. , Gardecki , J. A. and Maroncelli , M. 1997 . Rotational dynamics of coumarin 153: time‐dependent friction, dielectric friction, and other nonhydrodynamic effects . J. Phys. Chem. A , 101 : 1030 – 1047 .
  • Belford , G. G. , Belford , R. L. and Weber , G. 1972 . Dynamics of fluorescence polarization in macromolecules . Proc. Nat. Acad. Sci. , 69 : 1392 – 1393 .
  • Chuang , T. J. and Eisenthal , K. B. 1972 . Theory of fluorescence depolarization by anisotropic rotational diffusion . J. Chem. Phys. , 57 : 5094 – 5097 .
  • Arnold , B. R. and Schill , A. W. 2002 . Rotational dynamics of excited probes: the analysis of experimental data . Spec. Lett. , 35 : 229 – 238 .
  • Poliakov , P. and Arnold , B. R. 1999 . An application of time‐resolved linear dichroism spectroscopy: the excited singlet state of 1,2:5,6‐dibenzanthracene . Spec. Lett. , 32 : 747 – 762 .
  • Pedersen , P. B. , Thulstrup , E. W. and Michl , J. 1981 . Magnetic circular dichroism of cyclic pi‐ electron systems. 24. polarizations and assignments in some pentacyclic and hexacyclic benzenoid hydrocarbons . Chem. Phys. , 60 : 187 – 198 .
  • Hodgkinson , K. A. and Munro , I. H. 1973 . Excited singlet state and triplet states of aromatic hydrocarbons determined by a laser flash photolysis technique . J. Molec. Spec. , 48 : 57 – 71 .
  • Sander , L. C. and Wise , S. A. 1997 . Polycyclic Aromatic Hydrocarbon Structure Index Washington, D.C. : U.S. Government Printing Office . NIST Special Publication 922
  • Small , E. W. and Isenberg , I. 1977 . Hydrodynamic properties of a rigid molecule: rotational and linear diffusion and fluorescence anisotropy . Biopolymers , 16 : 1907 – 1928 .
  • Youngren , G. K. and Acrivos , A. 1975 . Rotational friction coefficients for ellipsoids and chemical molecules with the slip boundary condition . J. Chem. Phys. , 63 : 3846 – 3848 .
  • Sension , R. J. and Hochstrasser , R. M. 1993 . Comment on: rotational friction coefficients for ellipsoids and chemical molecules with slip boundary conditions . J. Chem. Phys. , 98 : 2490

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.