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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 20
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Original Articles

Stereocontrolled Iodolactonization of Acyclic Olefinic Amides

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Pages 3645-3650 | Received 03 Aug 1999, Published online: 04 Dec 2007

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  • Solvation enthalpies of dipolar solute enhance conformational energy difference to show the big medium effect. The bigger dielectric constant and more polar character of the solvent CH3CN (e = 36.2, μ = 3.92) compared to THF (e = 7.32, μ = 1.63) yields the bigger energy difference between 3 and 4. ,
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