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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 39, 2009 - Issue 9
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Original Articles

Tris(dimethylsilyl)methyllithium: A Reagent for the Synthesis of Vinylbis(silanes) Containing Si–H Functional Groups

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Pages 1601-1610 | Received 20 Aug 2008, Published online: 02 Apr 2009

REFERENCES

  • (a) Pawluc , P. ; Hreczycho , G. ; Marciniec , B. A new selective approach to 1,1-bis(silyl)-2-arylethenes and 1,1-bis(silyl)-1,3-butadienes via sequential silylative coupling–Heck coupling reactions . J. Org. Chem. 2006 , 71 , 8676 – 8679 ; (b) Mise , T. ; Takaguchi , Y. ; Wakatsuki , Y. ; Takaguchi , Y. ; Umemiya , T. ; Shimizu , S. ; Wakatsuki , Y. Ruthenium-catalyzed ring-closing reaction of α,ω-bis(vinylsilyl) compounds via a silyl transfer mechanism . Chem. Commun. 1998 , 6 , 699 – 700 .
  • (a) Atsushi Inoue , A. ; Kondo , J. ; Shinokubo , H. ; Oshima , K. A facile synthesis of 1,1-disilylethenes via Me3MgLi-induced monomethylation of dibromodisilylmethanes . Chem. Lett. 2001 , 956 – 961 ; (b) Safa , K. D. ; Paymard Samani , S. ; Tofangdarzadeh , S. ; Hassanpour , A. Study of the reaction of 1,1-bis(trimethylsilyl)-2-phenylethylene with some acyl chlorides in the presence of AlCl3 . J. Organomet. Chem. 2008 , 693 , 2004 – 2008 .
  • (a) Hodgson , D. M. ; Comina , P. J. ; Drew , M. G. B. Chromium(II)-mediated synthesis of vinylbis(silanes) from aldehydes and a study of acid- and base-induced reactions of the derived epoxybis(silanes): A synthesis of acylsilanes . J. Chem. Soc., Perkin Trans. 1 1997 , 2279 – 2290 : (b) Pawluc , P. ; Marcinic , B. ; Dudziec , B. ; Hreczycho , G. ; Kubicki , M. Novel highly stereoselective approach toward (Z)-1,2-bis(silyl)ethenes . Synthesis 2006 , 3739 – 3745 .
  • (a) Safa , K. D. ; Nasirtabrizi , M. H. One-pot, novel chemical modification of glycidyl methacrylate copolymers with very bulky organosilicon side chain substituents. Eur. Polym. J. 2005, 41, 2310–2319; (b) Safa , K. D. ; Babazadeh , M. Glass transition temperature modification of acrylic and dienic type copolymers of 4-chloromethyl styrene with incorporation of (Me3Si)3C– groups. Eur. Polym. J. 2004, 40, 1659–1669; (c) Safa , K. D. ; Babazadeh , M. ; Namazi , H. ; Mahkam , M. ; Asadi , M. G. Synthesis and characterization of new polymer systems containing very bulky tris(trimethylsilyl)methyl substituents as side chains. Eur. Polym. J. 2004, 40, 459–466.
  • (a) Schubert , H. H. ; Stang , P. J. Application of the Peterson olefination to the preparation of substituted triafulvenes from methoxycyclopropenylium triflates . J. Org. Chem. 1984 , 49 , 5087 – 5090 ; (b) Barrett , A. G. M. ; Flygare , J. A. Triply convergent, stereospecific alkene formation via Peterson olefination . J. Org. Chem. 1991 , 56 , 638 – 642 .
  • Hawrelak , E. J. ; Ladipo , F. T. ; Sata , D. ; Braddock-Wilking , J. Synthesis, characterization, and reactivity of [LiC(SiMe2H)3]·2THF: Formation of 1,1,3,3-tetramethyl-2,2,4,4-tetrakis(dimethylsilyl)-1,3-disilacyclobutane, [Me2SiC(SiMe2H)2]2 . Organometallics 1999 , 18 , 1804 – 1807 .
  • Kahovec , J. Aldehyde functionalization of styrene polymers . Polym. Bull. 1981 , 4 , 731 .
  • (a) Kowalewska , A. ; Stańczyk , W. A. ; Boileau , S. ; Lestel , L. ; Smith , J. D. Novel polymer systems with very bulky organosilicon side chain substituents . Polymer 1999 , 40 , 813 – 818 ; (b) Kim , Y. H. ; Kwon , S.-K. ; Choi , S. K. Synthesis and properties of poly (1,6-heptadiyne) having a bulky siloxy group . Macromolecules 1997 , 30 , 6677 – 6679 .

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