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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 2, 1972 - Issue 5
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Original Articles

Synthesis of Acylacetylenes from α-Diazo-β-Hydroxylcarbonyl Compounds

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Pages 331-334 | Received 30 Jun 1972, Published online: 05 Dec 2006

References

  • U. S. Public Health Service postdoctoral fellow . 1969–1971 .
  • Wenkert , E. and McPherson , C. A. 1972 . J. Amer. Chem. Soc. , 94 : 0000
  • Utilization of less polar solvents results in the formation of yet other products; e. g. treatment of lb with boron trifluoride in ether gave a mixture of 2b and ethyl (E)-2-fluoro-4-methyl-2-pentenoate. while the reaction of 1b in benzene yielded the same two products as well as ethyl 4-methy1–2, 4-pentadienoate
  • Padwa , A. , Cimiluca , P. and Eastman , D. 1972 . J. Org. Chem. , 37 : 805 A formally related reaction is the thermal transformation of methyl trans-N-nitroso-N-(3-pheny1–2, 3-epoxypropyl-) carbamate into 1-phenyl-2-propinol
  • Courtin , A. , Class , E. and Erlenmeyer , H. 1964 . Helv. Chim. Acta. , 47 : 1748

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