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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 3, 1973 - Issue 4
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Original Articles

Cyanogen Bromide Promoted Thiol Dimerization

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Pages 317-320 | Received 18 Jul 1973, Published online: 05 Dec 2006

References

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  • Ho , T. L. and Wong , C. M. 1973 . Synth. Commun. , 3 : 63
  • Fusco , R. , Rossi , S. and Bianchetti , G. 1961 . Gazz. Chim. Ital. , 91 : 841 cf. M. E. Kuehne (J. Amer. Chem. Soc., 81, 5400 (1959)) who reported α-cyanation of enamines with ClCN in the presence of Et3N
  • Pearson , R. G. 1969 . Survey of Progress in Chemistry Edited by: Scott , A. F. Vol. 5 , 1 – 52 . New YOrk & London : Academic Press .
  • Ho , T. L. and Wong , C. M. 1972 . Can. J. Chem. , 50 : 3740 For a recently developed dethioacetalization method based on soft-soft acid-base interaction between Tl(III) and sulfur, see
  • A very small amount of thiocyanate has been detected from the crude reaction mixture by infrared spectroscopy
  • Fairbrother , F. 1950 . J. Chem. Soc. , 180 (;G. Lord and A. A. Wolf, J. Chem. Soc., 2546 (1954)
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  • B It is implied that a bromosulfonium ion is kinetically generated prior to the formation of
  • Corey , E. J. and Kim , C. U. 1972 . J. Amer. Chem. Soc. , 94 : 7586
  • Baenziger , N. C. , Buckles , R. E. , Kaner , R. J. and Simpson , T. D. 1969 . J. Amer. Chem. Soc. , 91 : 5749 It should be noted that the crystal structure of bis (p-chlorophenyl) sul-fide-chorine complex has been established by X-ray diffraction.For recent studies of other sulfuranes, see I. C. Paul, J. C. Martin, and E. F. Perozzi, J. Amer. Chem. Soc, 94, 5010 (1972) and previous papers

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