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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 6, 1976 - Issue 8
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Original Articles

Studies on the Syntheses of Multilayered [2. 2] Paracyclophanes

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Pages 591-596 | Received 20 Sep 1976, Published online: 05 Dec 2006

References

  • Horita , H. , Otsubo , T. , Sakata , Y. and Misumi , S. Layered Compounds Part XL; Part XXXIX submitted to Tetrahedron Letters
  • Cram , D. J. and Cram , J. M. 1971 . Accounts Chem. Res. , 4 : 204 F. Vögtle and P. Neumann, Synthesis, 85 (1973); S. Misumi, Kagaku no Ryoiki (Japanese), 28, 927 (1974); Y. Sakata, Kagaku no Ryoiki (Japanese), 28, 947 (1974)
  • Otsubo , T. , Mizogami , S. , Otsubo , I. , Tozuka , Z. , Sakagami , A. , Sakata , Y. and Misumi , S. 1973 . Bull. Chem. Soc. Jpn. , 46 : 3519 D. T. Longone and H. S. Chow, J. Amer. Chem. Soc., 92, 994 (1970); for review: S. Misumi, Mem. Inst. Sci. & Ind. Res., Osaka Univ., 33, 53 (1976)
  • Bruhin , J. and Jenny , W. 1973 . Tetrahedron Lett. , : 1215 J. Bruhin, W. Kneubühler, and W. Jenny, Chimia, 27, 277 (1973); V. Boekelheide, I. D. Reingold, M. Tuttle, Chem. Comm., 406 (1973)
  • Kannen , N. , Umemoto , T. , Otsubo , T. and Misumi , S. 1973 . Tetrahedron Lett. , : 4537
  • Mitchell , R. H. , Otsubo , T. and Boekelheide , V. 1975 . Tetrahedron Lett. , : 219 An improved coupling method was reported in a recent paper
  • This method is applicable to a wide range of substituted multilayered cyclophanes
  • The absence of the inhibitor resulted in extremely poor yield because of increasing polymerization
  • Too long time of the irradiation tended to decrease the yield
  • The preparation of all the ammonium salts 7–11 was described in reference 3)

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