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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 11, 1981 - Issue 10
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Original Articles

Synthesis of (−)-α-CIS-Bergamotene. An Efficient Prenylation Procedure

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Pages 859-864 | Published online: 05 Dec 2006

References

  • 1977 . University of Paris . Taken in part from the Doctorat d'Etat thesis of Fadila Derguini
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  • Herout , V. , Ruzicka , V. , Vrany , M. and Sorm , F. 1950 . Collect. Czech. Chem. Comm. , 15 : 373 Isolated from bergamot oil:
  • Bessière‐Chrétien , Y. and Grison , C. 1975 . Bull. Soc. Chim. , : 2499 19V We thank Dr. C. Grison for providing us with copies of the I. R. and NMR spectra of α‐cis‐bergamotene which he originally obtained from Dr. T. Gibson (of the Procter and Gamble Company). These spectra were both of synthetic material 15 and natural α‐cis‐bergamotene extracted from oppopanax oil (by J. A. Wenninger, Division of Color and Cosmetics, Food and Drug Administration) and from black pepper oil (by C. J. Muller and W. G. Jennings 21. We express our thanks to Dr. T. Gibson and to Drs J. A. Wenninger, C. J. Muller and W. G. Jennings
  • Kwart , H. and Miller , R. K. 1954 . J. Amer. Chem. Soc. , 76 : 5403 The “prenyl” Grignard reagent 3 (3‐methyl‐2‐butenyl magnesium chloride) was prepared in anhydrous THF for 1‐chloro‐3‐methyl‐2‐butene, according to the procedure described by
  • Muller , C. J. and Jennings , W. G. 1967 . J. Agr. Food. Chem. , 15 : 762

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