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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 15, 1985 - Issue 6
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Original Articles

Stereoselective Synthesis of Steroid Side Chain: Synthesis of (2R∗,3R∗)-2-Methyl-3-[(1R∗)-1,5-Dimethylhexyl]Cyclopentanone

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Pages 507-514 | Published online: 06 Dec 2006

References

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  • Trost , B. M. , Bernstein , P. R. and Fünfschilling , P. C. 1979 . J. Am. Chem. Soc. , 101 : 4378 Grieco, P. A., Takigawa, T., Moore, D. R., ibid., 1979, 101, 4380; Takahashi, T., Naito, Y., Tsuji. J., ibid., 1981, 103, 5261 and references cited therein
  • Tsunemoto , D. , Araki , N. and Kondo , K. 1977 . Tetrahedron Lett. , : 109
  • Nakayama , M. , Ohira , S. , Takata , S. and Fukuda , K. 1983 . Chem. Lett. , : 147
  • Previously, the synthesis of (+)-6 and optically active cyclopentanone (3) has been achieved by two groups via the stereospecific routes, respectively
  • Trost , B. M. , Taber , D. F. and Alper , J. B. 1976 . Tetrahedron Lett. , : 3857
  • Desmaële , D. , Ficini , J. , Guingant , A. and Kahn , P. 1983 . Tetrahedron Lett. , 24 : 3079
  • Braude , E. A. and Coles , J. A. 1951 . J. Chem. Soc. , : 2078
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  • Inhoffen , H. H. , Irmscher , K. , Friedrich , G. , Kampe , D. and Berges , O. 1959 . Chem. Ber. , 92 : 1772
  • The spectral data of synthetic 3 were identical with those of the reported previously ones.6,7

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