A Novel Approach to Synthesis of 1R-Cis-Caronaldehyde a key Intermediate for Photostable Pyrethroid Insecticides

References

• Martel , J. , Tessier , J. , Demoute , J. P. and Jolly , J. German Patent 2, 827, 627 . C.A. 1979, P168138h.
   Google Scholar
• Elliott , M. , Farnham , A. , Janes , N. , Needham , R. and Pulman , D. 1974 . Nature , 248 : 710
   PubMed Web of Science ®Google Scholar
• Hatch , C. E. III , Baum , J. S. , Takashima , T. and Kondo , K. 1980 . J.Org.Chem. , 45 : 3281
   Web of Science ®Google Scholar
• Ozonolysis of (4) in ethyl acetate acetic acid at 0° followed by reductive decomposition (Me2S) and stirring with water (15 hrs) gave (1) in 80–85% yield.
   Google Scholar
• Roman , S. A. U.S. Patent 4,132,717 . 1979 . C.A., P204306x.
   Google Scholar
• Mitra , R. B. , Khanra , A. S. and Deshmukh , A. R. A.S . 1981 . Indian J. Chem. , 20 ( B ) : 436
   Google Scholar
• Mitra , R. , Kulkarni , G. H. , Gore , K. G. , Muljiani , Z. , Joshi , G. D. and Bhawal , B. M. Indian Patent 153336 . 1985 . C.A., P204134f
   Google Scholar
• We thank Dr.Gururao, T. N. for X-ray crystallographic analysis
   Google Scholar
• Mandai , A. K. , Borude , D. P. , Armugasamy , R. , Soni , N. R. , Jawalkar , D. G. , Mahajan , S. W. , Ratnam , K. R. and Goghare , A. D. 1986 . Tetrahedron , 42 : 5715
   Google Scholar
• Martel , J. German Patent 1,935,320 . 1970 . C.A., 121078b
   Google Scholar