Sulfuric Acid Catalyzed Decarbonylation of Alkoxyacetyl Chlorides

References

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• We have tried decarbonylation with TiCl4 and SnCl4 also. Sulfuric acid gives better results
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• Acid chlorides were obtained by the treatment of the corresponding acid with freshly distilled thionyl chloride. Alkoxyacetic acids (except methoxyacetic acid) were prepared by the reaction of the corresponding alcohols with ethyl bromoacetate in the presence of sodium hydride in THF, followed by hydrolysis
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