References
- Brandsma , L. 1971 . Preparative acetylenic chemistry , New York : Elsevier Publishing Company . Amsterdam, London
- Rutledge , T. F. 1968 . Acetylenic compounds - Preparation and substitution reactions , New York, Amsterdam, London : Rheinhold Book Corp. . N
- Brandsma , L. and Verkruijsse , H. D. 1981 . Synthesis of acetylenes, allenes and cumulenes , Amsterdam : Elsevier Scientific Publishing Company .
- Wotiz , J. H. 1969 . “ Chapter 7 ” . In Chemistry of acetylene , 365 New York : Marcel Dekker .
- Rutledge , T. F. 1969 . Acetylenes and allenes , New York, Amsterdam, London : Rheinhold Book Corp . part II: Acetylene-allene isomerization.
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- Michelot , D. 1976 . Ph.D. Dissertation University of Paris ,
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- Clinet , J. C. and Linstrumelle , G. 1981 . Synthesis , : 875 This procedure has been already explored with a limited number of carbonyl compounds, see: ref. 7, andHooz, J., Calzada, J. and McMaster, D., Tetrahedron Lett., 1985, 26, 271.
- Creary , X. 1977 . J. Am. Chem. Soc. , 99 : 7632 Under diverse experimental procedures the substituted allenyllithium reagent might lead mainly to the allenyl alcohol. The occurrence of allenic alcohols versus to homopropargylic ones still remains unclear; among the different explanations, it has been hypothesized that the ratio of the different products is dependent upon many factors including the degree of substitution in the organometallic reagents and the steric hindrance of the carbonylic electrophile. Aldehydes would produce preferentially homopropargylic alcohols, while hindered ketones more of the allenic alcohols; it has been observed that aromatic substrates give more easily homopropargylic alcohols than their aliphatic homologues, see: