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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 7-8
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Original Articles

An Efficient Synthesis of Dicarbonyl (η5—Cyclopentadien—YL)Iron(II) Complexes of Two Cyclic Enol Ethers

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Pages 1437-1448 | Received 24 Oct 1988, Published online: 24 Oct 2006

References

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  • 6 And 7 were also successfully purified by low temperature chromatography under argon over silanised silica gel (Merck kieselgel 60 silanised, 0,063–0,200 mm). However, chromatography over silica gel resulted in hydrolysis of the acetal grouping followed by ring opening (ref. 7 and 2)
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  • Complexes 2 3 were prepared also from Fp2 without purifying the intermediate 6 7, respectively. The solvent (THF) from which 6 7 were isolated was thoroughly removed by dissolving the residue in CHCl3 and removing the solvent in vacuo again three times. Using this method 2 3 were obtained in 74 and 54% overall yield, respectively
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