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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 12
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Original Articles

Reduction of Steroidal Ketones and Enones by Sodium Dithionite in Presence of Phase Transfer Catalyst

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Pages 1655-1660 | Received 28 Jan 1992, Published online: 23 Sep 2006

References

  • 1957 . Methods der Organische Chemie 437 Houben-Weyl, 4 Auflage, Band XI/1
  • de Vries , J. G. and Kellog , R. M. 1977 . Sythesis , : 246
  • Camps , F. , Coll , J. , Guerrero , A. , Guitart , J. and Riba , M. 1982 . Chem. Lett. , : 715
  • Linz , T. and Schafer , H. J. 1987 . Tet. Lett. , 52 : 6581
  • All the compounds were well characterised by recording IR and PMR spectra. These were idential with the reported spectra
  • Louis , A. O. and Gelbard , G. 1985 . Tet. Lett. , 26 : 831
  • Reduction conditions: Sodium dithionite (9mmol), reaction time 3 hrs., yield >98% (crude), (86% recrystallised), m.p. 147°C, (Lit. 147–149°C)
  • Fried , J. and Edward , J. A. , eds. 1972 . Organic reactions in steriod Chemistry , Vol. I , New York : Van Nostrand Reinhold co. .

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