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- Potassium bicarbonate functioned equally well in the reaction Other bases such as sodium, potassium, and cesium carbonate gave increased levels of 2 and/or lower yields of 1
- The reaction mixture was analysed using a Hewitt Packard 5980 capillary GC with an DB-1 crosslinked methyl-silicon column, 30m × 0.25mm × −.25μm, at a column temperature of 250° C and flow rate of 1.7 mL/min. The retention times are as follows: 2,4-dichloro-6-methoxy-1,3,5-triazine: 2.5 min; 2-chloro-4,6-dimethoxy-1,3,5-triazine: 3.0 min; 2,4,6-trimethoxy-1,3,5-triazine: 3.4 min
- The endpoint of this reaction is defined as the time at which >97% conversion of the intermediate 2,4-dichloro-6-methoxy-1,3,5-triazine to CDMT has occurred. There is no residual cyanuric chloride
- The conversion of cyanuric chloride to 2,4-dichloro-6-methoxy-1,3,5-triazine is accompanied by an exotherm. This appears to start at around 20° C and facilitates the warm-up to 35° C