Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 28, 1998 - Issue 1
171
Views
9
CrossRef citations to date
0
Altmetric
Original Articles

Regioselective Synthesis of 2,2-Dimethylcyclopentanone Using 2-Pyrrolidone Magnesium Salt as Electrogenerated Base.

, , &
Pages 93-98 | Received 16 Jun 1997, Published online: 20 Aug 2006

References and Notes

  • House , H. O. 1972 . Modern Synthetic Reactions , 2nd Ed. , Edited by: Benjamin , W. A. 492 – 570 . California : Menlo Park .
  • Caine , D. 1991 . Comprehensive Organic Synthesis , Edited by: Trost , B. M. 3 Oxford : Pergamon Press . chap 1.1.
  • D'Angelo , J. 1976 . Tetrahedron , 32 : 2979 – 2990 .
  • Stork , G. and Hudrlik , P. F. 1968 . J. Am. Chem. Soc. , 90 : 4462 – 4464 . and 4464–4465.
  • Binkley , E. S. and Heathcock , C. H. 1975 . J. Org. Chem. , 40 : 2156 – 2160 .
  • Kuwajima , I. , Nakamura , E. and Shimizu , M. 1982 . J. Am. Chem. Soc. , 104 : 1025 – 1030 .
  • Tardella , P. A. 1969 . Tetrahedron Lett. , : 1117 – 1120 .
  • Jackman , L. M. and Lange , B. C. 1977 . Tetrahedron , 33 : 2737 – 2746 .
  • House , H. O. , Gall , M. and Olmstead , H. D. 1971 . J. Org. Chem. , 36 : 2361 – 2371 .
  • Morita , Y. , Suzuki , M. and Noyori , R. 1989 . J. Org. Chem. , 54 : 1785 – 1787 .
  • Coates , R. M. and Sowerby , R. L. 1971 . J. Am. Chem. Soc. , 93 : 1027 – 1029 .
  • Fairlie , D. P. and Bosnich , B. 1988 . Organometallics , 7 : 936 – 945 .
  • Larchevêque , M. , Debal , A. and Cuvigny , T. 1975 . J. Organomet. Chem , 87 : 25 – 31 .
  • Bonafoux , D. , Bordeau , M. , Biran , C. and Dunoguès , J. 1995 . J. Organomet. Chem , 493 : 27 – 32 .
  • GC/MS analyses were carried out with a HP 5890 chromatograph (25 m CP-Sil capillary WCOTT Crompack column) and a VG Micromass 16F spectrometer. MS for 1: 112 (M+), 56 (100%), 42; for 3: 112 (55, M+), 97 (17), 69 (73), 56 (45) 55 (43), 42 (100%); for 4: 112 (14, M+), 97 (7), 69 (71), 55 (34), 42 (100%); for 5: 126 (M+), 69, 56 (100%), 41, in complete accordance with the NIST/EPA/NIH mass spectral database.
  • Bonafoux , D. , Bordeau , M. , Biran , C. , Cazeau , P. and Dunoguès , J. 1996 . J. Org. Chem. , 61 : 5532 – 5536 .
  • Tafel , J. and Wassmuth , O. 1907 . Ber. Deut. Chem. Gesell. , 40 : 2831 – 2833 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.