References
- Piscataway, New Jersey 08854 : 4 Marvin Lane . Address for Correspondence
- Malaska , M. J. , Fauq , A. H. , Kozikowski , A. P. , Aagaard , P. J. and McKinney , M. 1995 . Bioorg. Med. Chem. Lett. , 5 : 61
- Chackalamannil , S. , Davies , R. J. , Asberom , T. , Doller , D. and Leone , D. 1996 . J. Am. Chem. Soc. , 118 : 9812
- Tanikaga , R. , Nozaki , Y. , Tamura , T. and Kaji , A. 1983 . Synthesis , : 134
- Tanikaga , R. , Nozaki , Y. , Nishida , M. and Kaji , A. 1984 . Bull. Chem. Soc. Jpn. , 57 : 729
- Huh , K. ‐T. , Orita , A. and Alper , H. 1993 . J. Org. Chem. , 58 : 6956
- Derien , S. , Clinet , J. C. , Dunach , E. and Perichon , J. 1992 . J. Organomet. Chem. , 424 : 213
- Tamura , R. , Shimizu , H. , Ono , N. , Azuma , N. and Suzuki , H. 1992 . Organometallics , 11 : 954
- Tsuji , J. , Sugiura , T. and Minami , I. 1986 . Tetrahedron Lett. , 27 : 731
- Moriarty , R. M. , Epa , W. R. and Awasthi , A. K. 1991 . J. Am. Chem. Soc. , 113 : 6315
- Trost , B. M. , Lautens , M. and Peterson , B. 1983 . Tetrahedron Lett. , 24 : 4525
- Trost , B. M. , Weber , L. , Strege , P. , Fullerton , T. J. and Dietsche , T. J. 1978 . J. Am. Chem. Soc. , 700 : 3426
- Stang , P. J. and Treptow , W. 1980 . Synthesis , 283
- Jigajinni , V. B. and Wightman , R. H. 1982 . Tetrahedron Lett. , 23 : 117
- Cacchi , S. , Morera , E. and Ortar , G. 1993 . Org. Synth. Coll. , Vol. VIII : 126
- Stang , P. J. , Hanack , M. and Subramanian , L. R. 1982 . Synthesis , : 85
- Crisp , G. T. , Scott , W. T. J. and Stille , J. K. 1984 . J. Am. Chem. Soc. , 106 : 7500
- This yield was determined by 'H NMR analysis
- The price of 2,6‐dHerf‐butyl‐4‐methylpyridine (Aldrich): $273.65 per 25g
- Scott , W. J. , Pena , M. R. , Sward , K. , Stoessel , S. J. and Stille , J. K. 1985 . J. Org. Chem. , 50 : 2302
- Bandodakar , B. S. and Nagendrappa , G. 1990 . Synthesis , : 843 1‐Bromocyclohexene was supplied from Allied‐Signal, Inc., Morristown, New Jersey 07962. For its preparation, see
- Ndebeka , G. , Raynal , S. and Caubere , P. 1980 . J. Org. Chem. , 45 : 5394 For its Heck reaction with methyl acrylate, see: Kim, J. I. Taehan Hwahakhoe Chi 1983, 27, 441; CA 1984, 100, 156199
- Lee , K. and Wiemer , D. 1993 . Tetrahedron Lett. , 34 : 2433 1‐Iodocyclohexene was prepared in two steps from cyclohexanone via the corresponding vinyl phosphate. See
- For these Heck reactions, we examined the following palladium catalysts: Pd(PPh3)2CI2, Pd(PPh3)4, and Pd(OAc)2/PPh3; bases: triethylamine and sodium carbonate; and solvents: DMF and acetonitrile, however, 'H NMR analysis showed that there existed 12–25% of the byproduct methyl cinnamate in the reaction mixture in all the experiments
- HPLC conditions: column, Symmetry C18 (3.9 mm x 150 mm, Waters); mobile phase, CH3CN/H20 (40:60); flow rate, 1.5 mL/min; detector, 230 ran; room temperature
- Wenkert , E. and Rego de , Sousa J. 1977 . Synth. Commun. , 7 : 457