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Original Articles

Synthesis and Magnetic Properties of the First (μ-End-To-End-Azido)Gadolinium(III) Compound: Gd2(phen)4(N3)6(H2O)

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Pages 405-414 | Received 16 Oct 1998, Accepted 28 Oct 1997, Published online: 14 Apr 2008

References

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  • Cortes , R. , Lezama , L. , Pizarro , J. L. , Arriortua , M. I. , Solans , X. and Rojo , T. 1994 . Angew. Chem. Int. Ed Fngl. , 33 : 2488
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  • Although the analytical and spectroscopic data unambiguously showed the presence of a dinuclear complex Gd2(phen)4(N3)6(H2O), an X-ray analysis was undertaken to remove the doubts regarding connectivity. Unfortunately, because the crystal is sensitive to X-ray, the intensity of standard reflections strongly declined and the data collection had to be halted when the measured intensity of a control reflection dropped below 60% of the initial intensity. Consequently, the high R and Rw factors (R = 0.118 and Ru = 0.137 based on F) and its unacceptable quality prevent us from publishing the crystal data in detail
  • Sakamoto , M. , Takagi , M. , Ishimori , T. and Okawa , H. 1988 . Bull. Chem. Soc. Jpn. , 61 : 1613

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