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Original Articles

THE CRYSTAL AND MOLECULAR STRUCTURE OF TRICYCLOPENTADIENYLETHYNYLURANIUM(IV)

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Pages 209-215 | Received 17 Nov 1975, Published online: 13 Dec 2006

References

  • Department of Chemistry, University of Alabama .
  • Department of Chemistry, Texas A & M University .
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  • Atwood , J. L. and Smith , K. D. 1973 . J. Amer. Chem. Soc. , 95 : 1488 The important features of the three-dimensional structure of Sm(C5H5)3 were confirmed by the structure of Sc(C5H5)3. See
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  • Using the relation [sgrave](difference) = ([sgrave]2 1 + [sgrave]2 2)1/2
  • A similar, although not so pronounced, contraction is noted for the Lu-C bonds in lithium tetrakis(2,6-dimethylphenyl)lutetiate: the observed values are approximately 0.2 Å shorter than that calculated for a Lu-C(5) bond length
  • Other crystallographic programs used on either an RCA 70/6 or a UNIVAC 1110 include ORFFE (distance and angles with esd's, by W. R. Busing, K. O. Martin, and H. A. Levy), ALFF (Fourier synthesis, by C. R. Hubbard, C. O. Quicksall, and R. A. Jacobson), ORABS (absorption corrections, by D. J. Wehe, W. R. Busing, and H. A. Levy), ORTEP (thermal ellipsoid drawings, by C. K. Johnson), and BPL (least-squares planes, by W. E. Hunter)
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  • 1962 . International Tables for X-ray Crystallography , Vol. III , 202 Birmingham, , England : Kynoch Press .
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  • The term “poorer structure” means that the derived bond distances and angles made poorer chemical sense than the structure reported herein
  • The final values of the observed and calculated structure factor amplitudes are given in a table which may be obtained from the Editor's office
  • Although there are two crystallographically independent molecules in the asymmetric unit, it was not possible to refine the carbon atom (2C16) bonded in sigma fashion to U2. Therefore, all subsequent discussion of the U-C sigma bond will refer to the parameters obtained for the molecule containing U1. It may be noted in Tables IV and V that the less accurately determined sigma bond parameters for U2 are nevertheless in good agreement with those for U1
  • Zalkin , A. and Raymond , K. N. 1969 . J. Amer. Chem. Soc. , 91 : 5667
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  • Wong , C. H. , Yen , T. and Lee , T. 1965 . Acta Crystallogr. , 18 : 340
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  • Churchill , M. R. and Kalra , K. L. 1973 . Inorg. Chem. , 12 : 1650
  • Epstein , E. F. , Bernal , I. and Köpf , H. 1971 . J. Organometal. Chem. , 26 : 229
  • Atwood , J. L. and Smith , K. D. 1974 . J. Amer. Chem. Soc. , 96 : 994
  • Atwood , J. L. , Hunter , W. E. , Hrncir , D. C. , Samuel , E. , Alt , H. and Rausch , M. D. 1975 . Inorg. Chem. , 14 : 1757
  • Atwood , J. L. , Hunter , W. E. , Alt , H. G. and Rausch , M. D. 1976 . J. Amer. Chem. Soc. , 98 : 2454

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