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Original Articles

THE PREPARATION AND CRYSTAL STRUCTURE OF DIMOLYBDENUM TETRAFORMATE; PHOTOELECTRON SPECTRA OF THIS AND SEVERAL OTHER DIMOLYBDENUM TETRACARBOXYLATES

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Pages 217-223 | Received 19 Jan 1976, Published online: 13 Dec 2006

References

  • Stevenson , T. A. , Bannister , E. and Wilkinson , G. 1964 . J. Chem. Soc. , : 2538 and several earlier preliminary notes cited therein
  • Cotton , F. A. 1975 . Chem. Soc. Revs. , 4 : 27
  • Brignole , A. B. and Cotton , F. A. 1972 . Inorg. Svn. , 13 : 87
  • Abbot , E. H. , Schoenewolf , F. Jr. and Backstrom , T. 1974 . J. Coord. Chem. , 3 : 255
  • Hochberg , E. , Walks , P. and Abbot , E. H. 1974 . Inorg. Chem. , 13 : 1824
  • Green , J. C. and Hayes , A. J. 1975 . Chem. Phys. Letters , 31 : 306
  • Dr. Abbot has sent us samples of the compound made by this method in his laboratory. The X-ray powder pattern is similar to but not identical to that of our product
  • It should be pointed out that the structural solution from the first crystal, refined to R 1 = 0.078, would not refine with the second data set. In fact, the structure had to be completely re-solved using the second data set and there is no crystallography allowed transformation for the atomic positions from crystal one to crystal two. There also appears to be no common scale factor relating the equivalent reflections between the two data sets. The problem, be it twinning or something else, results in two different crystals giving virtually identical unit cells, identical space groups, yet, two different structural solutions
  • Cotton , F. A. , Frenz , B. A. , Deganello , G. and Shaver , A. 1973 . J. Organometal. Chem. , 50 : 227
  • Computer programs used in the structural solution and refinement were those of the Enraf Nonius Structure Determination Package on a PDP 11/45 computer at the Molecular Structure Corporation, College Station, Texas
  • Cromer , D. T. and Waber , J. T. 1974 . International Tables for X-ray Crystallography , Vol. IV , Birmingham, , England : Kynoch Press . Table 2.3.1
  • Cromer , D. T. and Liberman , D. 1971 . J. Chem. Phys. , 53 : 1891
  • Cotton , F. A. , Mester , Z. C. and Webb , T. R. 1974 . Acta Crystallogr. , 30B : 2768
  • Cotton , F. A. and Norman , J. G. Jr. 1971 . J. Coord. Chem. , 1 : 161
  • Cotton , F. A. and Webb , T. R. 1976 . Inorg. Chem. , 15 : xxx
  • Dubicki , L. and Martin , R. L. 1969 . Austral. J. Chem. , 22 : 1571
  • Cotton , F. A. , Martin , D. S. and Webb , T. R. 1976 . Inorg. Chem. , 15 : 1199
  • Norman , J. G. Jr. and Kolari , H. G. 1975 . J. Chem. Soc. Chem. Comm. , : 649
  • Price , W. C. , Potts , A. W. and Streets , D. G. 1972 . Electron Spectroscopy , Edited by: Shirley , D. A. 187 – 197 . New York : Elsevier .

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