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- Here and subsequently coordinated waters on aquochromium species will be omitted for brevity of notation
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- The assumption is entirely reasonable if it is noted that at 0°C the rate constants for the CrX2+-Cr2+ exchanges differ by a factor 5.5 for X = Br and Cl2 7 and that any discrimination in rates between Br and Cl in CrClBr+ is expected to be diminished for the faster CrClBr+-Cr2+ reaction. The statistically corrected rate constant for the t-CrCl2 +-Cr2+ reaction is 200 M−1 s−1.2 6 Thus k –6 is probably ∼ 1200 M−1s−1
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