180
Views
10
CrossRef citations to date
0
Altmetric
Original Articles

VOLUMETRIC AND THERMODYNAMIC STUDIES OF MOLECULAR INTERACTIONS IN BINARY LIQUID MIXTURES OF N-ALKANES WITH HEPTAN-2-OL AT 298.15 K: COMPARISON WITH PRIGOGINE-FLORY-PATTERSON THEORY

&
Pages 1666-1682 | Published online: 01 Jul 2013

References

  • Abe , A. , and Flory , P. J. ( 1965 ). The thermodynamic properties of mixtures of small, nonpolar molecules , J. Am. Chem. Soc. , 87 , 1838 – 1846 .
  • Aicart , E. , Tardajos , G. , and Diaz Pena , M. (1980). Isothermal compressibility of cyclohexane +n-hexane, cyclohexane +n-heptane, cyclohexane +n-octane, and cyclohexane +n-nonane, J. Chem. Eng. Data , 25, 140–145.
  • Ali , A. , Nain , A. , Sharma , V. , and Ahmed , S. ( 2004 ). Molecular interaction in binary mixtures of THF with alkanols (C6,C8,C10): An ultrasonic and volumetric study , Indian J. Pure Appl. Phys. , 42 , 666 – 673 .
  • Aminabhavi , T. M. , Banerjee , K. , and Balundgi , R. H. ( 1999 ). Thermodynamic interactions in binary mixtures of 1-chloronapthalene and monocyclic aromatics , Indian J. Chem. , 38 , 768 – 777 .
  • Baragi , J. G. , Aralaguppi , M. I. , Kariduraganavar , M. Y. , Kulkarni , S. S. , Kittur , A. S. , and Aminabhavi , T. M. ( 2006 ). Excess properties of the binary mixtures of methylcyclohexane +alkanes (C6 to C12) at T = 298.15 K to T = 308.15 K , J. Chem. Thermodyn. , 38 , 75 – 83 .
  • Bloomfield , V. A. , and Dewan , R. K. ( 1971 ). Viscosity of liquid mixtures , J. Phys. Chem. , 75 , 3113 – 3119 .
  • Douhéret , G. , Pal , A. , and Davis , M. I. ( 1990 ). Ultrasonic speeds and isentropic functions of (a 2-alkoxyethanol +water) at 298.15 K , J. Chem. Thermodyn. , 22 , 99 – 108 .
  • Flory , P. J. ( 1965 ). Statistical thermodynamics of liquid mixtures , J. Am. Chem. Soc. , 87 , 1833 – 1838 .
  • George , J. , and Sastry , N. V. ( 2004 ). Densities, excess molar volumes at T = (298.15 to 313.15) K, speeds of sound, excess isentropic compressibilities, relative permittivities, and deviations in molar polarizations at T = (298.15 and 308.15) K for methyl methacrylate +2-butoxyethanol or dibutyl ether +benzene, toluene, or p-xylene , J. Chem. Eng. Data. , 49 , 1116 – 1126 .
  • Glasstone , S. , Laidler , K. J. , and Eyring , H. ( 1941 ). The Theory of Rate Processes: The Kinetics of Chemical Reactions, Viscosity, Diffusion and Electrochemical Phenomena , 514 – 516 , McGraw-Hill , New York .
  • Gonzalez , B. , Dominguez , J. , and Tojo , J. ( 2004 ). Dynamic viscosities of 2-butanol with alkanes (C8, C10 and C12) at several temperatures , J. Chem. Thermodyn. , 36 , 267 – 275 .
  • Hasan , M. , Shirude , D. F. , Hiray , A. P. , Sawant , A. B. , and Kadam , U. B. ( 2007 ). Densities, viscosities and ultrasonic velocities of binary mixtures of methylbenzene with hexan-2-ol, heptan-2-ol and octan-2-ol at T = 298.15 and 308.15 K , Fluid Phase Equilib. , 252 , 88 – 95 .
  • Iloukhani , H. , and Almasi , M. ( 2009 ). Densities, viscosities, excess molar volumes, and refractive indices of acetonitrile and 2-alkanols binary mixtures at different temperatures: Experimental results and application of the Prigogine Flory Patterson theory , Thermochim. Acta , 495 , 139 – 148 .
  • Iloukhani , H. , and Almasi , M. ( 2010 ). Densities, viscosities, and refractive indices of binary mixtures of acetophenone and 2-alkanols , J. Chem. Eng. Data , 55 , 1416 – 1420 .
  • Iloukhani , H. , Samiey , B. , and Moghaddasi , M. A. ( 2006 ). Speeds of sound, isentropic compressibilities, viscosities and excess molar volumes of binary mixtures of methylcyclohexane +2-alkanols or ethanol at T = 298.15 K , J. Chem. Thermodyn. , 38 , 190 – 200 .
  • Jouyban , A. , Khoubnasabjafari , M. , Vaez-Gharamaleki , Z. , Fekari , Z. , and Acree , Jr. , W. E. ( 2005a ). Calculation of the viscosity of binary liquids at various temperatures using Jouyban–Acree model , J. Chem. Pharm. Bull. , 53 , 519 – 523 .
  • Jouyban , A. , Fathi-Azarbayjani , A. , Khoubnasabjafari , M. , and Acree , Jr. , W. E. ( 2005b ). Mathematical representation of the density of liquid mixtures at various temperatures using Jouyban-Acree model , Indian J. Chem. , 44 , 1553 – 1560 .
  • Kannappan , A. N. , Thirumaran , S. , and Palani , R. ( 2009 ). Volumetric and thermodynamic studies of molecular interactions in ternary liquid mixtures at 303, 308 and 313 K , J. Phys. Sci. , 20 ( 2 ), 97 – 108 .
  • Kiyohara , O. , and Benson , G. C. ( 1979 ). Ultrasonic speeds and isentropic compressibilities of n-alkanol +n-heptane mixtures at 298.15 K , J. Chem. Thermodyn. , 11 , 861 – 873 .
  • Mahajan , A. R. , Mirgane , S. R. , and Deshmukh , S. B. ( 2007a ). Volumetric, viscometric and ultrasonic studies of some amino acids in aqueous 0.02 M LiCIO4 · 3H20 solutions at 298.15 K , Mater. Sci. Res. India , 4 ( 2 ), 345 – 552 .
  • Mahajan , A. R. , Mirgane , S. R. , and Deshmukh , S. B. (2007b). Ultrasonic studies of some amino acids in aqueous 0.02 M. LiCIO4 · 3H2O solutions at 298.15 K., Mater. Sci. Res. India , 4(2), 373–378.
  • Mahajan , A. R. , Mirgane , S. R. , and Deshmukh , S. B. ( 2012 ). Thermo-acoustical studies of binary mixture n-octane, n-decane, n-dodecane and n-tetradecane with octan-2-ol and application of theories of sound speed , J. Mol. Liq. , 175 , 44 – 50 .
  • McAllister , R. A. ( 1960 ). The viscosity of liquid mixtures , AIChE J. , 6 , 427 – 431 .
  • Mehra , R. , and Pancholi , M. ( 2006 ). Temperature dependent studies of thermo-acoustical parameters in hexane +1-dodecanols and application of various theories of sound speed , Indian J. Phys. , 80 , 253 – 263 .
  • Patterson , D. , and Delmas , G. ( 1970 ). Corresponding states theories and liquid models , Discuss. Faraday Soc. , 49 , 98 – 105 .
  • Prigogine , I. ( 1957 ). Molecular Theories of Solutions , North-Holland Publishing , Amsterdam .
  • Rai , R. D. , Shukla , R. K. , Shukla , A. K. , and Pandey , J. D. ( 1989 ). Ultrasonic speeds and isentropic compressibilities of ternary liquid mixtures at (298.15 ± 0.01) K , J. Chem. Thermodyn. , 21 , 125 – 129 .
  • Redlich , O. , and Kister , A. T. ( 1948 ). Thermodynamics of nonelectrolyte solutions. Algebraic representation of thermodynamic properties and the classification of solutions , Ind. Eng. Chem. , 40 , 345 – 348 .
  • Riddick , J. A. , Bunger , W. B. , and Sakano , T. K. ( 1986 ). Organic Solvents: Physical Properties and Methods of Purification, , 4th ed. , John Wiley , New York .
  • Trancrede , P. , Bothorel , P. , Romain , P. St. , and Patterson , D. ( 1977 ). Interactions in alkane systems by depolarized Rayleigh scattering and calorimetry. Part 1.—Orientational order and condensation effects in n-hexadecane +hexane and nonane isomers , J. Chem. Soc. Faraday Trans. , 2 ( 73 ), 15 – 28 .
  • Treszczanowicz , A. J. , and Benson , G. C. ( 1978 ). Excess volumes for n-alkanols +n-alkanes II. Binary mixtures of n-pentanol, n-hexanol, n-octanol, and n-decanol +n-heptane , J. Chem. Thermodyn. 10 , 967 – 974 .
  • Yang , C. , Xu , W. , and Ma , P. ( 2004 ). Thermodynamic properties of binary mixtures of p-xylene with cyclohexane, heptane, octane, and N-methyl-2-pyrrolidone at several temperatures , J. Chem. Eng. Data , 49 , 1794 – 1801 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.