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Original Articles

The Effect of Solvent Casting Condition on the Electrochemical Properties of Nafion/Polyvinylidene Fluoride Copolymer Blends for Direct Methanol Fuel Cell

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References

  • Cho, K. Y., Eom, J. Y., Jung, H. Y., Choi, N. S., Lee, Y. M., Park, J. K., Choi, J. H., Park, K. W., and Sung, Y. E. (2004). Characteristics of PVdF copolymer/Nafion blend membrane for direct methanol fuel cell (DMFC), Electrochim. Acta, 50, 583–588.
  • Cho, K. Y., Jung, H. Y., Choi, N. S., Sung, S. J., Park, J. K., Choi, J. H., and Sung, Y. E. (2005). A coated Nafion membrane with a PVdF copolymer/Nafion blend for direct methanol fuel cells (DMFCs), Solid State Ionics, 176, 3027–3030.
  • Cho, K. Y., Jung, H. Y., Sung, K. A., Kim, W. K., Sung, S. J., Park, J. K., Choi, J. H., and Sung, Y. E. (2006). Preparation and characteristics of Nafion membrane coated with a PVdF copolymer/recast Nafion blend for direct methanol fuel cell, J. Power Sources, 159, 524–528.
  • Eisenberg, A. (1970). Clustering of ions in organic polymers. A theoretical approach, Macromolecules, 3, 147–154.
  • Fujimura, M., Hashimoto, T., and Kawai, H. (1981). Small-angle x-ray scattering study of perfluorinated ionomer membranes. 1. Origin of two scattering maxima, Macromolecules, 14, 1309–1315.
  • Gierke, T. D. Munn G. E., and Wilson, F. C. (1981). Morphology of Nafion perfluorosulfonated membrane products as determined by wide- and small-angle X-ray studies, J. Polym. Sci. Polym. Phys., 19, 1687–1704.
  • Hobson, L. J., Ozu, H., Yamaguchi, M., and Hayase, S. (2001). Modified Nafion 117 as an improved polymer electrolyte membrane for direct methanol fuel cell, J. Electrochem. Soc., 148, A1185–A1190.
  • Jia, N., Lefebvre, M. C., Halfyard, J., Qi, Z., and Pickup, P. G. (2000). Modification of Nafion proton exchange membranes to reduce methanol crossover in PEM fuel cells, Electrochem. Solid-State Lett., 3, 529–531.
  • Lee, K. H., and Park, J. K. (1998). Effect of ion content in ionomer on the ion conductivity of polymer electrolytes based on the P(MMA-co-LiMA)/PEG/LiCF3SO3 blend, J. Polym. Sci. Part B Polym. Phys., 36, 991–997.
  • MacCallum, J. R., and Vincent, C. A. (1987). Polymer Electrolyte Reviews, Elsevier Applied Science, London.
  • Mauritz, K. A., and Fu, R. M. (1988). Dielectric relaxation studies of ion motions in electrolyte-containing perfluorosulfonaed ionomers. 1. NaOH and NaCl Systems, Macromolecules, 21, 1324–1333.
  • Mauritz, K. A. (1989). Dielectric relaxation studies of ion motions in electrolyte-containing perfluorosulfonate ionomers. 4. Long-range ion transport, Macromolecules, 22, 4483–4488.
  • O'Hayre, R., Cha, S. W., Colella, W., and Prinz, F. B. (2006). Fuel Cell Fundamentals, John Wiley & Sons Inc., New York.
  • Pu, C., Huang, W., Ley, K. L., and Smotkin, E. S. (1995). A methanol impermeable proton conducting composite electrolyte system, J. Electrochem. Soc., 142, L119–L120.
  • Shao, Z. G., Wing, X., and Hsing, I. M. (2002). Composite Nafion/polyvinyl alcohol membranes for the direct methanol fuel cell, J. Membrane Sci., 210, 147–153.
  • Yeo, S. C., and Eisenberg, A. (1977). Physical properties and supermolecular structure of perfluorinated ion-containing (nafion) polymers, J. Appl. Polym. Sci., 21, 875–897.

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