133
Views
15
CrossRef citations to date
0
Altmetric
Original Articles

ON THE EFFECTS OF SYNGAS COMPOSITION AND WATER-GAS-SHIFT REACTION RATE ON FT SYNTHESIS OVER IRON BASED CATALYST IN A SLURRY REACTOR

Pages 143-158 | Received 10 Aug 1993, Accepted 11 Jan 1994, Published online: 06 Apr 2007

REFERENCES

  • Anderson , R.B. , “ Catalysts for the Fischer-Tropsch Synthesis ”, in Catalysis , Emmett, P.H., Ed. ; Van Nosirand Rheinhold New York , Vol. IV p. 257 – 371 ( 1956 ).
  • Arakawa , H. , and Bell , A.T. , “ Effects of Potassium Promotion on the Activity and Selectivity of Iron Fischer-Tropsch Catalysts ”, Ind. Eng. Process. Des. Dev. , 22 , 97 ( 1983 ).
  • Ascher , U. , Christiansen , J. , and RusscI , R.D. , “ Algorithm 569 COLSYS Collocation Software for Boundary Value ODEs ”, ACM Trans. Math. Softw. , 7 , 223 ( 1981 ).
  • Bukur , D.B. , Patel , S.A. , and Daly , J.G. , “ Hydrodynamic Studies with Fischer-Tropsch Waxes in Three-Phase Bubble Columns ”, Indirect Liquefaction Proceedings, DOE Contractors Review Meeting , p. 329 , Nov. 13 – 15 ( 1989 ).
  • Bukur , D.B. , Daly , J.G. , and Patel , S.A. , “ Hydrodynamics of Three-Phase Slurry Fischer-Tropsch Bubble Column Reactors ”, Final Report to the Department of Energy for contract No. DE-AC22-87PC90012 ( 1990 ).
  • Calderbank , P.H. , Evans , F. , Farley , R. , Jepson, G,, and Poll , A. , “ Rate Processes in the Catalysis-Slurry Fischer-Tropsch Reaction ”, Catalysis in Practice ( Inst. Chem. Engrs. ), p. 66 ( 1963 ).
  • Chao , K.C. , and Lin , H.M. , “ Synthesis Gas Solubility in Fischer-Tropsch Slurry ”, Final Report for DOE contract No. DE-AC22-84PC70024 ( 1987 ).
  • Cova , D.R. , “ Catalyst Suspension in Gas-Agitated Tubular Reactors ”, Ind. Eng. Chem. Process. Des. Dev. , 5 , 20 ( 1966 ).
  • Deckwer , W.D. , Burckhart , R. , and Zoll , G. , “ Mixing and Mass Transfer in Tall Bubble Columns ”, Chem. Eng. Sci. , 29 , 2177 ( 1974 ).
  • Deckwer , W.D. , Serpemen , Y. , Ralek , M. , and Schmidt , B. , “ Modeling the Fischer-Tropsch Synthesis in the Slurry Phase ”, Ind. Eng. Chem., Process. Des. Dev. , 21 , 231 ( 1982 ).
  • Deckwer , W.D. , Nguyen-tien , K. , Kelkar , B.G. , and Shah , Y.T. , “ Applicability of Axial Dispersion Model to Analyze Mass Transfer Measurements in Bubble Columns ”, AlChE J. , 29 , 915 ( 1983 ).
  • Field , R.W. , and Davidson , J.F. , “ Axial Dispersion in Bubble Columns ” Trans. Inst. Chem. Engrs. , 58 , 228 ( 1980 ).
  • Graff , G.H. , Winkelman , J.G.M. , Stamhuis , E.J. ,Beenackers, A.A.C.M., “ Kinetics of the Three-Phase Methanol Synthesis ”, Chem. Eng. Sci. , 43 , 8 , 2161 – 68 ( 1988 ).
  • Huff , G.A. Jr. , “ Fischer-Tropsch Synthesis in a Slurry Reactor ”, ScD. Thesis , M.I.T. , Cambridge , Mass . ( 1982 ).
  • Huff , G.A. Jr. , and Satterfield , C.N. , “ Intrinsic Kinetics of the Fischer-Tropsch Synthesis on a Reduced Fused-Magnetite Catalyst ”, Ind. Eng. Chem. Process Des. Dev. , 23 , 696 – 705 ( 1984a ).
  • Huff , G.A. Jr. , and Satterfield , C.N. , “ Some Kinetic Design Considerations in the Fischer-Tropsch Synthesis on a Reduced Fused-Magnetite Catalyst ”, Ind. Eng. Chem. Process Des. Dev. , 23 , 851 – 954 ( 1984b ).
  • Hughmark , G.A. , “ Holdup and Mass Transfer in Bubble Columns ”, Ind. Eng. Chem. Process Des. Dev. , 6 , 218 ( 1967 ).
  • Kato , Y. , Nishiwaki , A. , Fukuda , T. ,Tanaka, S-, “ The Behavior of Suspended Solid Particles and Liquid in Bubble Column ”, J. Chem. Eng. Jpn. 5 , 112 – 18 ( 1972 ).
  • Kawagoe , M. , Otake , T. , and Robinson , C.W. , “ Gas Phase Mixing in Bubble Columns ”, J. Chem. Eng. Jpn. , 22 , 136 ( 1989 ).
  • Kolbel , H. , and Ralek , M. , “ The Fischer-Tropsch Synthesis in the Liquid Phase ”, Catal. Rev.-Sci. Eng. , 21 , 225 ( 1980 ).
  • Kuo , J.C.W. , “ Slurry Fischer-Tropsch/Mobil Two-Stage Process of Converting Syngas to High Octane Gasoline ”, U.S. DOE Final Report No. DOE/PC/30022-10, Dec. ( 1983 ).
  • Ledakowicz , S. , Nettelhoff , H. , Kokuun , R. , and Deckwer , W.D. , “ Kinetics of the Fischer-Tropsch Synthesis in the Slurry Phase on a Potassium-Promoted Iron Catalyst ”, Ind. Eng. Chem. Process Des. Dev. , 24 , 1043 – 49 ( 1985 ).
  • Lee , S. , “ Research to Support Development of the Liquid-Phase Methanol Synthesis Process ”, EPRI AP-4429 ( 1986 ).
  • Moe , J.M. , “ Design of Water-Gas-Shift Reactors ”, Chem. Eng. Prog. , 58 , 33 ( 1962 ).
  • Nettelhoff , H. , Kokuun , R. , Ledakowicz , S. , and Deckwer , W.D. , “ Studies on the Kinetics of Fischer-Tropsch Synthesis in Slurry Phase ”, Cer. Chem. Eng. , 8 , 177 – 185 ( 1985 ).
  • Nguyen-tien , K. , Patwari , A.N. , Schumpe , A. , and Deckwer , W.D. , “ Gas-Liquid Mass Transfer in Fluidized Particle Beds ”, AIChE J. , 31 , 194 ( 1985 ).
  • Nigam , K.D.P. , and Schumpe , A. , “ Gas-Liquid Mass Transfer in a Bubble Column with Suspended Solids ”, AIChE J. , 33 , 2 , p. 328 – 30 ( 1987 ).
  • Prakash , A. , and Bendale , P.G. , “ Design of Slurry Reactor for Indirect Liquefaction Applications ”, Final Report for U.S. DOE contract No. DE-AC22-89PC89870, Dec . ( 1991 ).
  • Satterfield , C.N. , and Huff , G.A. , “ Effects of Mass Transfer on Fischer-Tropsch Synthesis in Slurry Reactors ”, Chem. Eng. Sci. , 35 , 195 ( 1980 ).
  • 156 A. PRAKASH Satterfield , C.N. ,Huff, G.A. Jr., “ Carbon Number Distribution of Fischer-Tropsch Products Formed on an Iron Catalyst in a Slurry Reactor ”, J. Catalyst , 73 , 187 ( 1982 ).
  • Shinnar , R. , and Kuo , J.C.W. , “ Gasifier Study for Mobil Coal to Gasoline Processes ”, Final Report for DOE Contract No. EF-77-C-01-2766, DOE Report FE-2766-13, Oct . ( 1976 ).
  • Smith , D.N. , Dowd , W. , Reuther , J.A. , Stiegel , G.J. , and Shah , Y.T. , “ Slurry F-T Reactor Hydrodynamics and Scale-up ” Proc. of 4th DOE Indirect Liquefaction Contractors Meeting , Washington , Oct. 30 – 31 ( 1984 ).
  • Smith , D.N. , and Ruether , J. , “ Dispersed Solid Dynamics in a Slurry Bubble Column ”, Chem. Eng. Set. , 40 , 5 , 741 – 54 ( 1985 ).
  • Stern , D. , Bell , A.T. , and Heinemann , H. , “ Effects of Mass Transfer on the Performance of Slurry Reactors Used for Fischer-Tropsch Synthesis ”, Chem. Eng. Sci. , 38 , 597 ( 1983 ).
  • Stern , D. , Bell , A.T. ,Heinemann, H-, “ A Theoretical Model for the Performance of Bubble-Column Reactors used for Fischer-Tropsch Synthesis ”, Chem. Eng. Sci , 40 , 1663 ( 1985 ).
  • Towell , G.D. , and Ackerman , G.H. , “ Axial Mixing of Liquid and Gas in Large Bubble Reactors ”, Proc. of Fifth European/Second Int. Symp. on Reaction Eng. , p. B 3 – 1 , Amsterdam ( 1972 ).
  • Wendt , R. , Steiff , A. , and Weinspach , P.M. , “ Liquid Phase Dispersion in Bubble Columns ”, Ger. Chem. Eng. , 7 ,267( 1984 ).
  • Yates , I.C. , and Satterfield , C.N. , “ Effect of Carbon Dioxide on the Kinetics of the Fischer-Tropsch Synthesis on Iron Catalysts ”, Ind. Eng. Chem. Res. , 28 , 9 – 12 ( 1989 ).
  • Zimmerman , W.H. , and Bukur , D.B. , “ Reaction Kinetics Over Iron Catalysts Used for the Fischer-Tropsch Synthesis ”, Can. J. Chem. Eng. , 68 , 292 – 301 ( 1990 ).

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.