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Original Articles

ON THE SIMULTANEOUS REPRESENTATION OF VAPOR-LIQUID EQUILIBRIA AND EXCESS ENTHALPIES OF 1-ALKANOL + n-ALKANE MIXTURES

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Pages 1-15 | Received 26 Jan 1996, Accepted 19 Jul 1996, Published online: 19 Apr 2007

References

  • Alessi , P. , Fermeglia , M. and Kikie , I. , ( 1989 ). Liquid-liquid equilibrium of cyclohexane-n-hexane-methanol mixtures effect of water . J. Chem. Eng. Data , 34 , 236 – 240 .
  • Aristovich , V. Yu. , Morachevskii , A. G. and Sabylin , I.I. , ( 1965 ). Experimental study and the equilibrium calculations in the ternary system methyl ethyl ketone-butanol-heptane . Zh, Prikl, Khim. , 38 , 2694 – 2700 .
  • Boublikova , L. and Lu , B.C.-Y. , ( 1969 ). Vapor-liquid phase equilibria for the ethanol-n-octane system . J, Appl. Chem. (London) , 19 , 89 – 92 .
  • Brown , I. , Fock , W. and Smith , F. , ( 1964 ). Aust. J. Chem. , 17 , 1106 – 1118 , Quoted from Christensen, J. J., Hanks, R. W. and Izatt, R. W., (1982). Handbook of Heats of Mixing, p. 1012, John Wiley & Sons .
  • Collins , S. G. , Christensen , J. J. , Izatt , R. M. and Hanks , R. W. , ( 1980 ). The excess enthalpies of 10 (n-Pentane + an n-alkanol) mixtures at 298.15 K. J. Chem. Thermodyn. , 12 , 609 – 614 .
  • Demirel , Y. and Gecegörmez , H. , ( 1991 ). Simultaneous representation of excess enthalpy and Vapor-liquid equilibrium data by the NRTL and UNIQUAC models . Fluids phase Equllib. , 65 , 111 – 133 .
  • Diaz Pena , M. , Rodriguez Cheda , D. An Quim ., ( 1970 ). Quoted from Maczynski, A., Bilinski, A., Oracz, P. and Treszczanowicz, T . Verified Vapor-liquid Equilibrium Data , 6 , Binary Systems of C4 + Hydrocarbons and Alcohols, p. 68, PWA. Warsaw, 66, 721 .
  • Ferguson , J. B. , Freed , M. and Morris , A C. , ( 1970 ). J. Phys. Chem. , 37 , 87 . Quoted from Hirata, M., Ohe, S. and Nagahawa, K., Computer Aided Data Book of Vapor-liquid Equilibria, Elsevier Scientific Publishing Company, p. 268, (1975) .
  • Fu , S. J. and Lu , B. C.-Y. , ( 1966 ). Binary Vapor-liquid equilibria . J, Appl. Client. (London) , 16 , 324 – 32 .
  • Gmehling , J. , Li , J. and Schiller , M. , ( 1993 ) A modified UNIFAC model 2. Present parameter matrix and results for different thermodynamic properties , lnd. Eng. Chem. Res. , 32 , 178 – 193 .
  • Gmehling , J. and Onken , U. , ( 1977 , 1982 ) Vapor-liquid Equilibrium Data Collection Organic Hydroxy Compounds Alcohols. DECHEMA Chemistry Data Series, 1 .
  • Hanks , R. W. and Christensen , J.J. , ( 1979 ). The prediction of multicomponent vapor-liquid equilibria from binary heats of mixing . Inst. Chem. Engrs. (London). Symp. Ser. No. 56(1) , p1/29–1/49 p.
  • Jones , H. K. , de Q. and Lu , B. C.-Y. , ( 1966 ). Heats of mixing of liquids System ethanol-benzene-n-hexane . J. Chem. Eng. Data , 11 , 488 – 492 .
  • Larsen , B. L. , Rasmussen , P. and Fredenslund , Aa. , ( 1987 ). A modified UNIFAC groups-contribution model for the prediction of phase equilibri and heats of mixings , lnd. Eng. Chem. Res. , 26 , 2274 – 2286 .
  • Lee , L. A. and Scheller , W. A. , ( 1967 ). Isothermal Vapor-liquid equilibrium for the systems heptane-1-propanol at 75°C and decane-1-butanol at 100°C . J. Chem. Eng. Data , 12 , 497 – 499 .
  • Lichtenstein , C. , Rauzy , E. and Berro , Ch. , ( 1993 ). Simultaneous representation of vapor liquid equilibria and excess enthalpies of methanol-hydrocarbon systems using an equation of state . Fluid Phase Equilib. , 87 , 37 – 51 .
  • Lu , B. C.-Y. , Zhao , E. , Shen , S. and Wang , L. , ( 1993 ). Progress in the development of simple equation of state . Trends in Chemical Engineering , 1 , 233 – 244 .
  • Margerum , M. R. and Lu , B. C.-Y. , ( 1990 ). VLE correlation for binary 1-alkanol + n-alkane mixtures , Fluid Phase Equilib. , 56 , 105 – 118 .
  • Moorthi , K. , Gierycz , P. and Nagata , I. , ( 1991 ). “ Prediction and correlation of excess enthalpy and excess Gibbs energy of the 1-alkanol + n-alkane systems . Fluid Phase Equilib. , 64 , 13 – 32 .
  • Nguyen , T. H. and Ratcliff , G. A. , ( 1975 ). Heats of mixing of n-alcohol-n-alkane systems at 15°C and 55°C . J. Chem. Eng. Data , 20 , 252 – 255 .
  • Ragaini , V. , Santi , R. and Carra , S. , ( 1968 ). Uncei-Rend. Sc.fis. mat. e nat. , 45 , 540 – 544 . Quoted from Christensen, J. J., Hanks, R. W. and Izatt, R. M., (1982). Handbook of Heats of Mixing, p. 687. John Wiley & Sons .
  • Renon , H. and Prausnitz , J. M. , ( 1968 ). Local compositions in thermodynamic excess functions for liquid mixtures . AIChE.J , 14 , 135 – 144 .
  • Ronc , M. , and Ratcliff , G. R. , ( 1976 ). Measurement of vapor-liquid equilibria using a semi-continuous total pressure static equilibrium still . Can. J. Chem. Eng. , 54 , 326 – 332 .
  • Scheller , M. , Schuberth , H. and Koennecke , H. G. , ( 1969 ). Ergebnisse von Dampt-Fliissig-keits-phasengeichgewichtsuntersuchungen am system n-hexane-melhylcyelohexane/meth-anol bei 60°C . J. Prakt, Chem. , 311 , 974 .
  • Shen , S. , Wang , Y. and Si , J. , ( 1988 ). A new model for simultaneous representation of H E and G e . Int. Symp. Thermodynamics Chem. Eng. Ind. , pp. 313 – 318 , Beijing.
  • Shen , S. , Wang , Y. , Shi , J. , Benson , G. C. and Lu , B. C.-Y. , ( 1992 ). Excess enthalpies of the system acetone + ethyl acetate and cyclohexane + cyclohexanone . J. Chem. Eng. Data , 37 , 400 – 402 .
  • Smirnova , N. A. and Kurtynina , L. M. , ( 1969 ). Thermodynamic functions of mixing for a number of binary alcohol-hydrocarbon solutions . Russ J. Phys. Chem. , 43 , 1059 – 1060 .
  • Stryjek , R. and Vera , J. H. , ( 1986 ). PRSV an improved Peng-Robinson equation of state of pure components and mixtures . Can J. Chem. Eng. , 64 , 323 – 33 .
  • Trebble , M. A. , ( 1988 ). Correlation of VLE data for binary mixtures of 1-alkanols and normal hexane with the Trebble-Bishnoi equation of stale . Fluid Phase Equilib. , 42 , 117 – 128 .
  • Trebble , M. A. , ( 1991 ). The impact of asymmetric equation of state mixing rules on thermi dynamic property prediction for normal alkanol-hexane binaries . Fluid Phase Equilib. , 65 , 73 – 88 .
  • Wilson , G. M. , ( 1964 ). Vapor-liquid equilibrium XI. A new expression for the excess free energy of mixing . J. Am. Chem. Soc. , 86 , 127 – 130 .
  • Wong , D. S. H. , Sandler , S. I. , ( 1992 ). A theoretically correct mixing rule for cubic equations of state . AIChE J. , 38 , 671 – 680 .

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