EXPERIMENTAL STUDY OF THE SELECTIVE HYDROGENATION OF STEAM CRACKING C₂CUT. FRONT END AND TAIL END VARIANTS

References

• Cabanes , A. L. , Vfllora , G. and Bodalo , A. ( 1986 ). Pirolisis de hidrocarburos: El proceso de pirolisis con vapor. Modelos cineticos. , Secretariado de Publicaciones e lntercambio Cientifico . Universidad de Murcia, pp. 13 – 89 .
   Google Scholar
• Leprince , P. , Chauvel , A. , Catry , J. P. and Catex , L. ( 1971 ). Procedes de Petrochimie. , Technip , Paris , pp . 69 – 98 .
   Google Scholar
• Derrien . M. L. ( 1986 ). Selective Hydrogenation applied to the refining of petrochemical raw materials produced by steam-cracking, in L. Cerveny , (ed.), Catalytic Hydrogenalion. , Elsevier Amsterdam . pg 613 .
   Google Scholar
• Livingston , J. Y. ( 1973 ). Performance of selective hydrogenation catalysts. Chem. Eng. Progress , 5 ( 69 ), 65 – 68 .
   Google Scholar
• Zdonik , S. D. ( 1983 ). Production and Economics in the Recovery of Ethylene, Other Olefins, and Aromatics from Pyrolysis Systems, in L. F , Albright , B. L. Crynes and W. H. Corcoran , (eds.) Pyrolysis. Theory and Industrial Practice, , Academic Press , New York , pg. 377 .
   Google Scholar
• Boitiaux , J. P. , Cosyns , J. , Derrien , M. and Leger , G. ( 1985 ). Newest hydrogenation catalysts , Hydrocarbon Processing , 64 ( 3 ), 5 59 .
   Google Scholar
• Glombik , A. , Grasshoff , E. , Koler , J. and Schubert , R. ( 1988 ). The selective hydrogenation of alkynes and alkadienes in alkene-rich hydrocarbon fractions , Chem Ing. Tech. , 60 ( 5 ), 375 – 377 .
   Google Scholar
• Anderson , J. , McAllister , S. H. , Derr , E. L. and Peterson , W. H. ( 1948 ). Diolefins in alkylation feedstocks conversion to monolefins by selective hydrogenation , Ind. Eng. Chem. , 40 , 2295 – 2301 .
   Web of Science ®Google Scholar
• Hoffmann , E. J. , Lewis , E. W. and Wadley , E. F. ( 1957 ). Set conditions for hydrogen testing , Petrol. Refiner. , 36 ( 6 ), 179 – 186 .
   Google Scholar
• Mullcr , M. , Deller , K. , Volheim , G. and Kuhn , W. ( 1987 ). Selective hydrogenation of acetylene in the manufacture of vinylchloryde , Chem. Ing. Tech. , 59 ( 8 ), 645 – 647 .
   Web of Science ®Google Scholar
• Kummerow , I. , Trimm , D. L. and Wainwright , M. S. ( 1983 ). Studies of the catalytic hydrogenation of acetylenic impurities in a butadiene stream , Chemeca 83, Chem. Eng. Today , 103 – 109 .
   Google Scholar
• Weisang , E. and Engelhard , P. A. ( 1970 ). Nouveaux catalyseurs d'hydrogenation selective , Chim. Ind. Genie Chim. , 103 ( 3 ), 287 – 296 .
   Google Scholar
• Taghavi , M. B. , Pajonk , G. and Teicher , S. J. ( 1978 ). Hydrogenation selective en phase gazeuse de l'acetylene en ethylene en presence de catalyseurs au cuivre, depose sur l'alumine, de magnesie et la silice , Bull. Soc. Chim. France , 77ndash;8 1302 – 1308 .
   Google Scholar
• Carturan , G. , Navazzio , G. , Barreter , E. and Dal Maschio , R. ( 1984 ). Pd Pt and Pd/Pt alloy catalysts highly dispersed on glass/TiO2, Catalytic behaviour in the hydrogenations of olefins and acetylene, Proc. of the 9th. Iberoamerican Symposium on Catalysis , 39 – 48 .
   Google Scholar
• Al-Ammar , A. S. and Webb , G. ( 1979 ). Hydrogenation of acetylene over supported metal catalysts. J. Chem. Soc. Faraday Trans. 1 , 75 , 657 – 664 .
   Google Scholar
• Bertolini , J. C. , Massardier , J. and Dalmai-Imelik , G. ( 1978 ). Evolution of absorbed species during C2H2 adsorption on Ni(III). in relation of their vibration espectra , J. Chem. Soc. Faraday Trans. 1 , 74 ( 7 ), 1720 – 1725 .
   Google Scholar
• Bond , G. C. ( 1962 ). Catalysis by metals, , Academic Press , New York .
   Google Scholar
• Godinez , C. , Vfllora , G. and Cabanes , A. L. ( 1994 ). Hidrogenacion selectiva defracciones C2 y C2-C3 de pirolisis con vapor. Variantes tail end y front end. , Secretariado de Publicaciones e Intercambio Cientifico . Universidad de Murcia, pp. 183 – 246 .
   Google Scholar
• Cabanes , A. L. , Vfllora , G. and Fajardo , J. C. ( 1990 ). Analisis termodinamico de la hidrogenacion de la fraction C3 de steam cracking , Ing. Quim. , 22 ( 254 ), 131 – 134 .
   Google Scholar
• Park , Y. H. and Price , G. L. ( 1991 ). Deuterium tracer study on the effect of CO on the selective hydrogenation of acetylene over Pd/Al2O3 , Ind. Eng. Chem. Res. , 30 ( 8 ), 1693 – 1699 .
   Web of Science ®Google Scholar
• McGown , W. T. , Kemball , C. , Whan , D. A. and Scurrell , M. S. ( 1977 ). Hydrogenation of acetylene in excess ethylene on an alumina supported palladium catalyst in a static system , J. Chem. Soc. Faraday Trans., 1 , 73 ( 4 ), 632 – 647 .
   Google Scholar
• LeViness , S. C. (1990). Polymer formation, deactivation and ethylene selectivity decline in Pl/A12O3 catalyzed selective acetylene hydrogenation, Diss. Abstr. Int. B. , 50(12, Ptl), 5766–5767.
   Google Scholar
• Weiss , A. H. , LeViness , S. , Nair , V. , Guczi , L. , Sarkany , A. and Schay , Z. ( 1984 ). The effect of palladium dispersion in acetylene selective hydrogenation , Int. Congr. Catal. , [Proc], 8th 591-V600.
   Google Scholar
• Fajardo , J. C. , Vfllora , G. and Cabanes , A. L. ( 1994 ). Analisis cinetico de la hidrogenacion selectiva de la fraction C₃ de pirolisis con vapor. , Secretariado de Publicationes e Intercambio Cientifico . Universidad de Murcia, pp. 71 – 186 .
   Google Scholar
• Schuit , G. C. and van Reijen , L. L. ( 1958 ). Structure and activity of metal-on silica catalysts , Advances in Catalysis , 10 , 242 – 317 .
   Google Scholar
• Kowaka , M. and Joncich , M. I. , ( 1959 ). Catalytic reaction on palladium and the effect of hydrogen, Mem. Inst. Sci. Ind. Res, , Osaka Univ , 16 , 107 – 111 .
   Google Scholar
• Apel'baum , L. O. and Temkin , M. I. ( 1961 ). The mechanism of catalytic hydrogenation of ethylene on palladium , Zhur. Fiz. Khim. , 35 , 2060 – 2070 .
   Google Scholar
• Margitfalvi , J. L. , Gobolos , S. , Hegediis , M. and Talas , E. ( 1988 ). Modification of Ni/Al2O3 hydrogenation catalysts with lead by using controlled surface reactions , in M. Guisnet et al (ed.), Heterogeneous Catalysis and Fine Chemicals, , Elsevier , Amsterdam , pg . 145 .
   Google Scholar
• Moses , J. M. , Weiss , A. H. , Matusek , K. and Guczi , L. ( 1984 ). The effect of catalyst treatment on the selective hydrogenation of acetylene over palladium/alumina , J. Catal. , 86 ( 2 ), 417 – 426 .
   Web of Science ®Google Scholar
• Beebe , T. P. Jr. and Yates , J. T. Jr. ( 1986 ). An in situ infrared spectroscopic investigation of the role of ethylidyne in the ethylene hydrogenation reaction on Pd/Al2O3 , J. Am. Chem. Soc. , 108 ( 4 ), 663 – 671 .
   Web of Science ®Google Scholar
• Bond , G. C. and Wells , P. B. ( 1965 ). The hydrogenation of acetylene (I). The reaction of acetylene with hydrogen catalyzed by alumina-supported platinum , J. Catal. , 4 , 211 – 219 .
   Google Scholar
• Bond , G. C. and Wells , P. B. ( 1965 ). The hydrogenation of acetylene (11). The reaction of acetylene with hydrogen catalyzed by alumina-supported platinum , J. Catal. , 5 , 65 – 73 .
   Web of Science ®Google Scholar
• Kittrell , J. R. , Hunter , W. G. and Watson , C. C. ( 1965 ). Nonlinear least squares analysis of catalytic rate models , AlChE J. , 11 ( 6 ), 1051 – 1057 .
   Web of Science ®Google Scholar
• Marquardt , D. W. ( 1963 ). Least squares estimation of nonlinear parameters. Soc. Ind. Appl. Math. , 11 , 431 – 437 .
   Google Scholar
• Bos , A. N. R. , Bootsma , E. S. , Foeth , F. , Sleyster , H. W. J. and Westerterp , K. R. ( 1993 ). A kinetic study of the hydrogenation of ethyne and ethene on a commercial palladium/alumina catalyst , Chem. Eng. Process. , 32 ( 1 ), 53 – 63 .
   Web of Science ®Google Scholar