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Phase Transitions
A Multinational Journal
Volume 77, 2004 - Issue 4
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Original Articles

Studying of the critical exponents around the glass transition in bulk polymerization of ethyl methacrylate by using fluorescence techniques

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Pages 359-373 | Received 27 Jan 2004, Published online: 21 Aug 2006

References

References

  • Abuin , E and Lissi , EA . 1977 . Methyl-methacrylate polymerization at high conversion. 2. Factors determining onset of gel effect . J. Macromol. Sci. , A11 : 287
  • Balke , ST and Hamielec , AE . 1973 . Bulk polymerization of methyl-methacrylate . J. Polym. Sci. , 17 : 905
  • Birks JB 1971 Photophysics of Aromatic Molecules, J. Wiley-Interscience New York
  • Birks , JB , Lumb , MD and Munro , IH . 1964 . Excimer fluorescence. V. Influence of solvent viscosity and temperature . Proc. R. Soc. London, Ser. A , 280 : 289
  • Bixon , M and Jortner , J . 1968 . Intramolecular Radiationless Transitions . Chem. Phys. , 48 : 715
  • Cardenas , JN and O’Driscoll , KF . 1976 . High-conversion polymerization. 2. Influence of chain transfer on gel effect . J. Polym. Chem. Ed. , 14 : 883
  • Cheng , S and Thomas , JK . 1974 . Dynamics of pyrene fluorescence in phospholipid dispensions . Radiat. Res. , 60 : 268
  • De Gennes PG 1988 Scaling Concepts in Polymer Physics p. 54 Cornell University Press Ithaca
  • Dorrance , RC and Hunter , TF . 1972 . Absorption and emission studies of solubilization in micelles: pyrene in long-chain cationic micelles . J. Chem. Soc. Fraday Trans. , 68 : 1312
  • Durand , D and Bruneau , C-M . 1979 . Reactivity and gelation: intrinsic reactivity . J. Polym. Sci. Polym. Phys. Ed. , 17 : 273
  • Flory , PJ . 1941 . Molecular size distribution in three dimension polymers . J. Am. Chem. Soc. , 63 : 3083
  • Goetze W 1989 Aspects of structural glass transition In: J.-P. Hansen and Zinn-Justin, J. (Eds.) Les Houches,Session LI., (1991). Liquids, Freezing and Glass Transition, Elsevier Amsterdam
  • Ito K 1975 Initiator concentration-dependence of autoacceleration of polymerization rate J. Polym. Sci. Part A 13 401
  • Kamioka , K , Weber , SE and Morishima , Y . 1988 . Solvent dependence of energy trapping in methacylic acid-vinylphenanthrene block copolymers . Macromolecules , 21 : 972
  • Kaya D Pekcan Ö. Yilmaz Y 2003 Fast transient fluorescence technique to study critical exponents at the glass transition Phase Transitions 76 6 543
  • Kropp LJ Dawson RW 1969 Fluorescence and phosphorescence of aromatic hydrocarbons in polymethylmethacrylate In: Lim, E.C. (Ed.) International Conference on Molecular Luminescence New York
  • Macosko , CW and Miller , DR . 1976 . New derivation of average molecular-weights on non-linear polymers, post gel properties of network polymers . Macromolecules , 9 : 199
  • Matheson , MS , Auer , EE , Bevilacqua , EB and Hart , EJ . 1951 . Rate constant in free radical polymerization (III) styrene . J. Am. Chem. Soc. , 73 : 1700
  • Norrish , RGW and Brookman , EF . 1939 . The mechanism of polymerization reactions I. The polymerization of styrene and methylmethacrylate . Proc. R. Soc. London. Ser. A. , 171 : 147
  • Norrish , RGW and Smith , RR . 1942 . Catalyzed polymerization of methylmethacrylate in the liquid phase . Nature , 150 : 336
  • North AM 1974 The influence of chain structure on the free radical termination reaction Chap. 5 In: Jenkins, A.D. and Ledwith, A. (Eds.) Reactivity, Mechanism and Structure in Polymer Chemistry, Wiley-Interscience New York
  • Okay , O , Kaya , D and Pekcan , Ö. 1999 . Free radical crosslinking copolymerization of styrene and divinylbenzene: real time monitoring of the gel effect using fluorescence probe . Polymer , 40 : 6179
  • O'Neil , GA and Wisdual , MB . 1998 . Gel effect in free radical polymerization: model discrimination of its cause . AIChE J. , 44 : 1226
  • Panxviel , JC , Dunn , B and Zink , JJ . 1989 . Fluorescence study of aluminosilicate sols and gels doped with hydroxy trisulfonated pyrene . J. Phys. Chem. , 93 : 2134
  • Pearson , DS and Graessley , WW . 1978 . Structure of rubber networks with multifunctional junctions . Macromolecules , 11 : 528
  • Pekcan , Ö. 1992 . Inverted Kalfter-Blumen equation for fractal analysis in polymer particles . Chem. Phys. Lett. , 20 : 198
  • Pekcan , Ö. , Egan , LS , Winnik , MA and Croucher , MD . 1990 . Energy transfer in restricted dimensions; a new Approach to latex morphology . Macromolecules , 23 : 2210
  • Pekcan , Ö. , Winnik , MA and Croucher , MD . 1988 . Direct energy transfer studies on dopped and labelled polymer latex particles . Phys. Rev. Lett. , 61 : 641
  • Qin , J , Guo , W and Zhang , Z . 2002 . Modeling of the bulk free radical polymerization up to high conversion – three stage polymerization model. II. Number-average molecular weight and apparent initiator efficiency . Polymer , 43 : 1163
  • Serrano , B , Levenfeld , B , Bravo , J and Baselga , J . 1996 . Studies of polymerization of acrylic monomers using luminescence probes and differential scanning calorimetry . Polymer Engineering and Science , 36 ( 2 ) : 175
  • Schultz , GV and Harbort , G . 1947 . On the mechanism of explosive polymerization process of methacrylicacidethylester . Macromol. Chem. and Physc. , 1 : 106
  • Stauffer D 1985 Introduction to Percolation Theory, Taylor and Francis London
  • Stauffer D Aharony A 1992 Introduction to Percolation Theory, Taylor and Francis London
  • Stauffer , D , Coniglio , A and Adam , M . 1982 . Gelation and critical phenomena . Adv. Polym. Sci. , 44 : 103
  • Stockmayer , WH . 1943 . Theory of molecular size distribution and gel formation in branched-chain polymers . J. Chem. Phys. , 11 : 45
  • Turner , DT . 1977 . Autoacceleration of free-radical polymerization. 1. Critical concentration . Macromolecules , 10 : 221
  • Winnik MA 1983 In: Feast, J. and Munro, H. (Eds.) Polymer Surfaces and Interfaces Ch. 1. Wiley London
  • Winnik , MA , Pekcan , Ö. , Chen , L and Croucher , MD . 1988 . Morphology changes and volume deformation of individual phases of polymer blends fluorescence studies of polymer colloids . Macromolecules , 21 : 55
  • Yilmaz , Y , Erzan , A and Pekcan , Ö. 1998 . Critical exponents and fractal dimension at the sol-gel phase transition via in situ fluorescence experiments . Phy. Rev. E. , 58 : 6
  • Zhu , S and Hamielec , AE . 1991 . Heat-effects for free-radical polymerization in glass ampoule reactors . Polymer , 32 : 3021

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