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Original Articles

Zirconium and Hafnium Separation, Part 1. Liquid/Liquid Extraction in Hydrochloric Acid Aqueous Solution with Aliquat 336

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Pages 1927-1940 | Received 26 Oct 2005, Accepted 07 Mar 2006, Published online: 20 Aug 2006

References

  • Da Silva , A. B.V. and Distin , P. A. 1998 . Zirconium and hafnium separation without waste generation . CIM Bull. , 91 : 221 – 224 .
  • Sathiyamoorthy , D. , Shetty , S. M. , Bose , D. K. and Gupta , C. K. 1999 . Pyrochemical separation of zirconium and hafnium tetrachlorides using fused salt extractive distillation process . High Temp. Mater. Process. , 18 : 213 – 226 .
  • Moulin , L. , Thouvenin , P. and Brun , P. 1984 . New process for zirconium and hafnium separation . ASTM Spec. Tech. Publ. , 824 : 37 – 44 .
  • Nandi , B. , Das , N. R. and Bhattacharyya , S. N. 1983 . Solvent extraction of zirconium and hafnium . Solvent Extr. Ion Exch. , 1 : 141 – 202 .
  • Vinarov , I. V. 1967 . Modern methods of separating zirconium and hafnium . Russ. Chem. Rev. , 36 : 522 – 536 .
  • Da Silva , A. , El‐Ammouri , E. and Distin , P. A. 2000 . Hafnium/zirconium separation using Cyanex 925 . Can. Metal. Quart. , 39 : 37 – 42 .
  • Das , N. R. and Lahiri , S. 1991 . Liquid ion exchangers and their uses in the separation of zirconium, niobium, molybdenum, hafnium, tantalum and tungsten . Solvent Extr. Ion Exch. , 9 : 337 – 381 .
  • Hubicki , Z. 1988 . Separation of zirconium(IV) from hafnium(IV) on various types of selective ion‐exchangers . Solvent Extr. Ion Exch. , 6 : 183 – 205 .
  • Trubert , D. , Monroy Guzman , F. , Le Naour , C. , Brillard , L. , Hussonnois , M. and Constantinescu , O. 1998 . Behavior of Zr, Hf, Nb, Ta and Pa on macroporous anion exchanger in chloride‐fluoride media . Anal. Chim. Acta , 374 : 149 – 158 .
  • Pin , C. and Joannon , S. 2002 . Combined cation‐exchange and extraction chromatography for the concomitant separation of Zr, Hf, Th, and the lanthanides from geological materials . Talanta , 57 : 393 – 403 .
  • Poriel , L. , Favre‐Réguillon , A. , Pellet‐Rostaing , S. and Lemaire , M. 2005 . Zirconium and hafnium separation, part 2 Solid/liquid extraction in hydrochloric acid aqueous solution with anion exchange resins . Submitted to Sep. Sci. Technol. ,
  • Skaggs , R. L. , Rogers , D. T. and Hunter , D. B. 1984 . Review of anhydrous zirconium‐hafnium separation techniques . Boulder City Eng. Lab., Bur. Mines ,
  • Kabili , M. A. , Akl , M. A. , Abdallah , A. M. and Ismail , D. S. 2000 . Selective separation‐flotation of hafnium from zirconium and their determination in real samples . Anal. Sci. , 16 : 713 – 718 .
  • Pickles , C. A. and Flengas , S. N. 1997 . Separation of HfCl4 from ZrCl4 by reaction with solid and liquid alkali chlorides under non‐equilibrium conditions . Can. Metall. Q. , 36 : 131 – 136 .
  • Poriel , L. , Favre‐Réguillon , A. , Pellet‐Rostaing , S. , Chitry , F. and Lemaire , M. 2005 . Zirconium and hafnium separation, part 3. Ligand‐enhanced separation of zirconium and hafnium from aqueous solution using nanofiltration . (Submitted to Sep. Sci. Technol) ,
  • Veyland , A. , Dupont , L. , Pierrard , J.‐C. , Rimbault , J. and Aplincourt , M. 1998 . Thermodynamic stability of zirconium(IV) complexes with hydroxy ions . Eur. J. Inorg. Chem. , 11 : 1765 – 1770 .
  • Reddy , B. R. , Kumar , J. R. , Reddy , A. V. and Priya , D. N. 2004 . Solvent extraction of zirconium(IV) from acidic chloride solutions using 2‐ethyl hexyl phosphonic acid mono‐2‐ethyl hexyl ester (PC‐88A) . Hydrometallurgy , 72 : 303 – 307 .
  • Abdel‐Fattah , A. A. , Ali , S. M. and El‐Sweify , F. H. 2002 . Thermodynamics of the solvent extraction of Zr(IV) by Amberlite LA‐2, TBP and HDEHP from different aqueous media . J. Radioanal. Nucl. Chem. , 253 : 465 – 475 .
  • Singhal , A. , Toth , L. M. , Beaucage , G. , Lin , J.‐s. and Peterson , J. 1997 . Growth and structure of zirconium hydrous polymers in aqueous solutions . J. Colloid Interface Sci. , 194 : 470 – 481 .
  • Singhal , A. , Toth , L. M. , Lin , J. S. and Affholter , K. 1996 . Zirconium(IV) Tetramer/Octamer Hydrolysis Equilibrium in Aqueous Hydrochloric Acid Solution . J. Am. Chem. Soc. , 118 : 11529 – 11534 .
  • Mit'kina , T. V. , Gerasko , O. A. , Sokolov , M. N. , Naumov , D. Y. and Fedin , V. P. 2004 . Syntheses and crystal structures of supramolecular compounds of tetranuclear ZrIV and HfIV aqua hydroxo complexes with macrocyclic cavitand cucurbituril . Russ. Chem. Bull., Int. Ed. , 53 : 80 – 85 .
  • Peralta‐Zamora , P. and Martins , J. W. 1999 . Anomalies in the spectrophotometric and extractive behavior of zirconium and hafnium: evidence of a synergistic effect . Talanta , 49 : 937 – 941 .
  • Biswas , R. K. and Hayat , M. A. 2002 . Solvent extraction of zirconium(IV) from chloride media by D2EHPA in kerosene . Hydrometallurgy , 63 : 149 – 158 .
  • Biswas , R. K. and Hayat , M. A. 2002 . Kinetics of solvent extraction of zirconium(IV) from chloride medium by D2EHPA in kerosene using the single drop technique . Hydrometallurgy , 65 : 205 – 216 .
  • Johnson , J. S. and Kraus , K. A. 1956 . Hydrolytic behavior of metal ionsVI. Ultracentrifugation of zirconium(IV) and hafnium(IV); effect of acidity on the degree of polymerization . J. Am. Chem. Soc. , 78 : 3937 – 43 .
  • El‐Ammouri , E. and Distin , P. A. 1996 . Hafnium extraction from acidic chloride solutions by Cyanex 923 . Solvent Extr. Ion Exch. , 14 : 871 – 887 .
  • Mishra , P. K. , Chakravortty , V. , Dash , K. C. , Das , N. R. and Bhattacharyya , S. N. 1989 . Extraction of zirconium(IV) from hydrochloric acid solutions by mixtures of Aliquat‐336 and Alamine‐336 with TBP . J. Radioanal. Nucl. Chem. , 134 : 259 – 264 .
  • Das , N. R. and Lahiri , S. 1994 . Liquid‐liquid extraction of trace level zirconium and hafnium with trioctylamine . J. Radioanal. Nucl. Chem. , 181 : 157 – 164 .
  • Wang , Q. , Tsunoda , K.‐I. and Akaiwa , H. 1997 . Separation of zirconium(IV) and hafnium(IV) by extraction chromatography using di(1‐methylheptyl) methylphosphonate as a stationary phase . Anal. Sci. , 13 : 27 – 31 .
  • Yang , X. J. , Pin , C. and Fane , A. G. 1999 . Separation of hafnium from zirconium by extraction chromatography with liquid anionic exchangers . J. Chromat. Sci. , 37 : 171 – 179 .
  • Wang , Q. , Tsunoda , K.‐i. and Akaiwa , H. 1995 . Extraction chromatographic behaviors of zirconium and hafnium using sulfoxides as stationary phases . Anal. Sci. , 11 : 909 – 913 .
  • Yang , X.‐J. and Pin , C. 1999 . Separation of Hafnium and Zirconium from Ti‐ and Fe‐Rich Geological Materials by Extraction Chromatography . Anal. Chem. , 71 : 1706 – 1711 .
  • Karve , M. A. and Khopkar , S. M. 1992 . Applications of liquid anion exchangers for the separation of zirconium and hafnium . Anal. Sci. , 8 : 237 – 241 .
  • Mishra , P. K. , Chakravortty , V. , Dash , K. C. and Bhattacharyya , S. N. 1992 . Extraction and separation of zirconium, niobium, and hafnium by Aliquat 336 and its mixtures with tri‐n‐octyl phosphine oxide (TOPO) from acidic thiocyanate media . J. Radioanal. Nucl. Chem. , 162 : 289 – 298 .
  • Vibhute , C. P. and Khopkar , S. M. 1987 . Liquid/liquid extraction separation of hafnium with Amberlite LA‐1 from zirconium and other elements in citric acid solutions . Anal. Chim. Acta , 193 : 387 – 392 .
  • Cerrai , E. and Testa , C. 1959 . Extraction and separation of zirconium and hafnium by means of liquid anionic exchangers in a hydrochloric acid medium . I. Behavior of some primary, secondary, and tertiary amines. Energ. Nucl. , 6 : 707 – 716 .
  • Das , N. R. and Chattopadhyay , P. 1988 . Solvent and reversed‐phase extraction chromatographic separation of niobium, zirconium, and hafnium with Aliquat 336 . Bull. Chem. Soc. Jpn. , 61 : 4423 – 4426 .
  • Bonfanti , F. , Cerrai , E. and Ghersini , G. 1967 . Extraction and separation of zirconium and hafnium by means of liquid anion exchangers in a hydrochloric acid medium III. Extraction with tri‐caprylyl‐monomethyl‐ammonium chloride . Energ. Nucl. , 14 : 578 – 85 .
  • El‐Yamani , I. S. , Farah , M. Y. and Abd El‐Aleim , F. A. 1978 . Studies on extraction of zirconium by quaternary ammonium halides from hydrochloric acid media and its separation from hafnium . Talanta , 25 : 714 – 716 .
  • Sato , T. and Watanabe , H. 1982 . The extraction of zirconium(IV) from sulfuric acid solutions by long‐chain alkyl quaternary compound . Sep. Sci. Technol. , 17 : 625 – 634 .
  • Choppin , G. R. 1992 . Complexation of Metal Ions Edited by: Rydberg , J. , Musikas , C. and Choppin , G. R. New York, , U.S.A. : Marcel Dekker .
  • Ho , T.‐L. 1975 . The Hard Soft Acids Bases (HSAB) principle and organic chemistry . Chem. Rev. , 75 : 1 – 20 .
  • Pearson , R. G. 1988 . Absolute electronegativity and hardness: application to inorganic chemistry . Inorg. Chem. , 27 : 734 – 740 .

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