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Original Articles

Influence of the Steric Hindrance, Ligand Hydrophobicity, and DN of solvents on Structure and Extraction of Cu(II) Complexes of 1‐Alkyl‐2‐Ethylimidazoles

Pages 794-814 | Received 05 Jun 2007, Accepted 04 Nov 2007, Published online: 26 Mar 2008

References

  • Lenarcik , B. , Kulig , J. and Laidler , P. 1974 . Stability and structure of transition metal complexes with azoles in aqueous solutions. Part II. 2‐methylimidazole complexes of Co(II), Cu(II), and Zn(II) . Roczniki Chemii , 48 : 1151
  • Lenarcik , B. and Kurdziel , K. 1981 . Stability and structure of transition metal complexes of azoles in aqueous solutions. Part XXIII. Effect of the position of methyl substituents on the complex‐forming capacity of imidazoles . Polish J. Chem. , 55 : 737
  • du Preez , J. G.H. , Sumter , N. , Mattheüs , Ch. , Ravindran , S. and van Brecht , B. J. 1997 . Nitrogen reagents in metal ion separation. Part VII. The development of a novel copper(II) extractant . Solv. Ext. Ion Exch. , 15 ( 6 ) : 1007
  • du Preez , J. G.H. , Mattheüs , Ch. , Sumter , N. , Ravindran , S. , Poptgieter , C. and van Brecht , B. J. 1998 . Nitrogen reagents in metal ion separation. Part VIII. Substituted imidazoles as extractants for Cu2+ . Solv. Ext. Ion Exch. , 16 ( 2 ) : 565
  • Lenarcik , B. , Adach , A. and Radzyminska‐Lenarcik , E. 1999 . The influence of steric effect and alkyl chain length on the extraction of the complexes of Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with 1‐alkyl‐2‐methylimidazoles . Polish J. Chem. , 73 : 1273
  • Kulig , J. , Kurdziel , K. , Barszcz , B. and Lenarcik , B. 1991 . Hydroxyalkylimidazole complexes of transition metal ions in aqueous solutions. Part I. effect of the hydroxymethyl substituent on the stability and structure of the 4(5)‐hydroxymethylimidazole and 1‐methyl‐2‐hydroxymethylimidazole complexes . Polish J. Chem. , 65 : 2159
  • Kulig , J. , Barszcz , B. and Lenarcik , B. 1992 . Hydroxyalkylimidazole complexes of transition metal ions in aqueous solutions. Part II. The chelate effect in the complexes of 1‐ethyl‐2‐hydroxymethylimidazole and 1‐propyl‐2‐hydroxymethyl‐imidazole . Polish J. Chem. , 66 : 79
  • du Preez , J. G.H. , Gerber , T. I.A. , Edge , W. , Mtotywa , V. L.V. and van Brecht , B. J.A.M. 2001 . Nitrogen reagents in metal ion separation. XI. The synthesis and extraction behavior of a new NS imidazole derivative . Solv. Ext. Ion Exch. , 19 ( 1 ) : 143
  • Lenarcik , B. and Kierzkowska , A. 2006 . The influence of alkyl chain length and steric effect on extraction of zinc(II) complexes with 1‐alkyl‐2‐methylimidazoles . Solv. Ext. Ion Exch. , 24 : 433
  • Radzyminska‐Lenarcik , E. 2007 . Effect of alkyl chain length on the extraction of copper(II) complexes with 1‐alkyl‐2‐methylimidazoles . Sep. Sci. Technol. , 42 : 2661
  • Lenarcik , B. and Kurdziel , K. 1982 . Stability and structure of transition metal complexes of azoles in aqueous solutions. Part XXV. The effect of the size and position of an alkyl substituent on the stability and structure of alkylimidazole complexes . Polish J. Chem. , 56 : 3
  • Pernak , J. , Krysinski , J. and Skrzypczak , A. 1987 . Bakterizide wirkung von iminiumverbindun‐gen. A. Tenside . Surfactants Deter. , 24 ( 5 ) : 276
  • Radzyminska‐Lenarcik , E. 2007 . The influence of the alkyl chain length on the extraction equilibrium of Cu(II) complexes with 1‐alkylimidazoles in aqueous solution ‐ organic solvent systems . Solv. Ext. Ion Exch. , 25 : 53
  • Braibanti , A. , Ostacoli , G. , Paoletti , P. , Pettit , L. D. and Sammartano , S. 1987 . Potentiometric apparatus and technique for the pH‐metric measurement of metal‐complex equilibrium constants . Pure Appl. Chem. , 59 : 1721
  • Lenarcik , B. and Ojczenasz , P. 2004 . Investigation of the stability constants of Co(II) complexes with a homologous series of 1‐alkylimidazoles in aqueous solution by using a partition method with several solvents . Sep. Sci. Technol. , 39 : 199
  • Lenarcik , B. and Kierzkowska , A. 2004 . The influence of alkyl length on stability constants of Zn(II) complexes with 1‐alkylimidazoles in aqueous solutions and their partition between aqueous phase and organic solvent . Sol. Extr. Ion Exch. , 22 : 449
  • Lenarcik , B. and Rauckyte , T. 2004 . The influence of alkyl length on extraction equilibria of Ni(II) complexes with 1‐alkylimidazoles in aqueous solution/organic solvent systems . Sep. Sci. Technol. , 39 : 3353
  • Lenarcik , B. and Kierzkowska , A. 2004 . The influence of alkyl chain length and steric effect on stability constants and extractability of Zn(II) complexes with 1‐alkyl‐4(5)‐methylimidazoles . Solv. Ext. Ion Exch. , 39 : 3485
  • Marcus , Y. 1993 . The properties of organic liquids that are relevant to their use as solvating solvents . Chem. Soc. Rev. , : 409
  • Rydberg , J. , Musakis , C. and Chopin , G. R. 1992 . Principles and Practices of Solvent Extraction Vol. 1 , 22 – 24 . New York : M. Dekker, Inc. .
  • Rydberg , J. 1950 . On the complex formation between thorium and acetylacetone . Acta Chem. Scand. , 4 : 1503
  • Rossotti , F. J.C. and Rossotti , H. 1961 . The Determination of Stability Constants New York : McGraw‐Hill .
  • Lenarcik , B. and Ojczenasz , P. 2002 . The influence of the size and position of the alkyl groups in alkylimidazole molecules on their acid – base properties . J. Heterocycl. Chem. , 39 : 287

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