274
Views
3
CrossRef citations to date
0
Altmetric
POLYMER BLEND DEMIXING

PC-SAFT Equation: A Predictive Tool to Determine Experimental Conditions for Polymer Blend Demixing

, , &
Pages 2661-2680 | Received 15 Oct 2008, Accepted 09 Mar 2009, Published online: 06 Aug 2009

REFERENCES

  • Kirby , C.F. ; Mc Hugh , M.A. ( 1999 ) Phase behavior of polymers in supercritical fluid solvents . Chem. Rev. , 99 : 565 – 602 .
  • Xiong , Y. ; Kiran , E. ( 1994 ) Prediction of high-pressure phase behaviour in polyethylene/n-pentane/carbon dioxide ternary system with the Sanchez-Lacombe model . Polymer , 35 : 4408 – 4415 .
  • Wei , Y.S. ; Sadus , R.J. ( 2000 ) Equations of state for the calculations of fluid phase equilibria . AIChE J. , 46 : 169 – 196 .
  • Müller , E.A. ; Gubbins , K.E. ( 2001 ) Molecular-based equations of state for associating fluids: A review of SAFT and related approaches . Ind. End. Chem. Res. , 40 : 2193 – 2211 .
  • Sanchez , I.C. ; Lacombe , R.H. ( 1976 ) Elementary molecular theory of classical fluids-pure fluids . J. Phys. Chem. , 80 : 2352 – 2362 .
  • Gross , J. ; Sadowski , G. ( 2001 ) Perturbed-chain SAFT: An equation of state based on a perturbation theory for chain molecules . Ind. Eng. Chem. Res. , 40 : 1244 – 1260 .
  • Lipatov , Y. ; Nesterov , A. ( 1997 ) Thermodynamics of Polymer Blends ; Technomic Publishing Company : Pennsylvania .
  • Martin , T.M. ; Lateef , A.A. ; Roberts , C.B. (1999) Measurements and modeling of cloud point behavior for polypropylene/n-pentane and polypropylene/n-pentane/carbon dioxide mixtures at high pressure. Fluid Phase Equilib. , 154: 241–259.
  • Gauter , K. ; Heidemann , R.A. ( 2001 ) Modeling polyethylene-solvent mixtures with the Sanchez–Lacombe equation . Fluid Phase Equilib. , 183–184 : 87 – 97 .
  • Chen , X. ; Yasuda , K. ; Sato , Y. ; Takishima , S. ; Masuoka , H. ( 2004 ) Measurement and correlation of phase equilibria of ethylene + n-hexane + metallocene polyethylene at temperatures between 373 and 473 K and at pressures up to 20 MPa . Fluid Phase Equilib. , 215 : 105 – 115 .
  • Nagy , I. ; de Loos , Th.W. ; Krenz , R.A. ; Heidemann , R.A. ( 2006 ) High pressure phase equilibria in the systems linear low density polyethylene + n-hexane and linear low density polyethylene + n-hexane + ethylene: Experimental results and modelling with the Sanchez-Lacombe equation of state . J. Supercrit. Fluids , 37 : 115 – 124 .
  • Chapman , W.G. ; E.Gubbins , K. ; Jackson , G. ; Radosz , M. ( 1990 ) New reference equation of state for associating liquids . Ind. Eng. Chem. Res. , 29 : 1709 – 1721 .
  • Wertheim , M.S. ( 1984 ) Fluids with highly directional attractive forces: I. Statistical thermodynamics . J. Stat. Phys. , 35 : 19 – 34 .
  • Wertheim , M.S. ( 1984 ) Fluids with highly directional attractive forces: II. Thermodynamic perturbation theory and integral equations . J. Stat. Phys. , 35 : 35 – 47 .
  • Wertheim , M.S. ( 1986 ) Fluids with highly directional attractive forces: III. Multiple attraction sites . J. Stat. Phys. , 42 : 459 – 476 .
  • Wertheim , M.S. ( 1986 ) Fluids with highly directional attractive forces: IV. Equilibrium polymerization . J. Stat. Phys. , 42 : 477 – 492 .
  • Huang , S.H. ; Radosz , M. ( 1990 ) Equation of state for small, large, polydisperse and associating molecules . Ind. Eng. Chem. Res. , 29 : 2284 – 2294 .
  • Huang , S.H. ; Radosz , M. ( 1991 ) Equation of state for small, large, polydisperse and associating molecules: Extensions to fluid mixtures . Ind. Eng. Chem. Res. , 30 : 1994 – 2005 .
  • Barker , J.A. ; Henderson , D. ( 1967 ) Perturbation theory and equation of state for fluids. II. A successful theory of liquids . J. Chem. Phys. , 47 : 4714 – 4721 .
  • Gross , J. ; Sadowski , G. ( 2002 ) Modeling polymer systems using the perturbed-chain statistical associating fluid theory equation of state. Ind . Eng. Chem. Res. , 41 : 1084 – 1093 .
  • Arce , P.F. ; Aznar , M. ( 2005 ) Phase behavior of polypropylene + n-pentane and polypropylene + n-pentane + carbon dioxide: modeling with cubic and non-cubic equations of state . J Supercrit. Fluids , 34 : 177 – 182 .
  • Utracki , L. ( 1990 ) Polymer Alloys and Blends ; Hanser : Munich .
  • Utracki , L. ( 1998 ) Commercial Polymer Blends ; Chapman & Hall : London .
  • Hudson , R. ( 1994 ) Commodity Plastics – As Engineering Materials? RAPRA Report. Rapro Tech. LTD : Shawbury .
  • Barbosa , S. ; Díaz , M. ; Mabe , G. ; Brignole , E. ; Capiati , N. (2005) Thermoplastic Blends demixing by high pressure high temperature process. J Polym. Sci. Polym. Phys. , 43: 2361–2369.
  • Martini , R. ; Barbosa , S. ; Brignole , E. ( 2006 ) Demixing of PP/PS blends by near critical selective solubilization . Ind. Eng. Chem. Res. , 45 : 3393 – 3399 .
  • Martini , R. ( 2007 ) Ph.D. Thesis. Universidad Nacional del Sur (UNS), Argentine, 2007 .
  • Chapman , W.G. ; Jackson , G. ; Gubbins , K.E. ( 1988 ) Phase equilibria of associating fluids. Chain molecules with multiple bonding sites . Mol. Phys. , 65 : 1057 – 1079 .
  • Liu , H. ; Hu , Y. ( 1996 ) Molecular thermodynamic theory for polymer systems. II equation of state for chain fluids . Fluid Phase Equilib. , 122 : 75 – 97 .
  • Kiran , E. ; Zhuang , W. ( 1992 ) Solubility of polyethylene in n-pentane at high pressures . Polymer , 33 : 5259 – 5263 .
  • Trumpi , H. ; de Loos , Th.W. ; Krenz , R.A. ; Heidemann , R.A. ( 2003 ) High pressure phase equilibria in the system linear low density polyethylene + ethylene: Experimental results and modelling . J. Supercrit. Fluids , 2 : 205 – 214 .
  • Cismondi , M. ; Nuñez , D.N. ; Zabaloy , M.S. ; Brignole , E.A. ; Michelsen , M.L. ; Mollerup , J.M. ( 2006 ) “GPEC: A Program for Global Phase Equilibrium Calculations in Binary Systems” . EQUIFASE 2006: VII Iberoamerican Conference on Phase Equilibrium for Process Design . Morelia, Michoacán , México . October 21–25, 2006 .
  • www.gpec.plapiqui.edu.ar
  • Cismondi , M. ; Michelsen , M. ( 2007 ) Global phase equilibrium calculations: Critical lines, critical end points and liquid-liquid-vapour equilibrium in binary mixtures . J. Supercrit. Fluids , 39 : 287 – 295 .
  • Cismondi , M. ; Michelsen , M. ( 2007 ) Automated calculation of complete Pxy and Txy diagrams for binary systems . Fluid Phase Equilib. , 259 : 228 – 234 .
  • Van Krevelen , D.W. ( 1997 ) Properties of Polymers ; Elsevier : Amsterdam .
  • Kiran , E. ; Zhuang , W. ; Sen , Y.L. ( 1993 ) Solubility and demixing of polyethylene in supercritical binary fluid mixtures: Carbon dioxide-cyclohexane, carbon dioxide-toluene, carbon dioxide-pentane . J. Appl. Polym. Sci. , 47 : 895 – 909 .
  • Xiong , Y. ; Kiran , E. ( 1994 ) High-pressure phase behavior in polyethylene/n-butane binary and polyethylene/n-butane/CO2 ternary systems . J. Appl. Polym. Sci. , 53 : 1179 – 1190 .
  • Kiran , E. ; Gokmenoglu , Z. ( 1995 ) High-pressure viscosity and density of polyethylene solutions in n-pentane . J. Appl. Polym. Sci. , 58 : 2307 – 2324 .
  • Zhang , W. ; Dindar , C. ; Bayraktar , Z. ; Kiran , E. ( 2003 ) Phase behavior, density, and crystallization of polyethylene in n-pentane and in n-pentane/CO2 at high pressures . J. Appl. Polym. Sci. , 89 : 2201 – 2209 .
  • Kiran , E. ; Xiong , Y. ( 1998 ) Miscibility of isotactic polypropylene in n-pentane and n-pentane + carbon dioxide mixtures at high pressures . J. Supercrit. Fluids , 11 : 173 – 177 .
  • Vladimir Oliveira , J. ; Dariva , C. ; Pinto , J.C. ( 2002 ) “High-pressure phase equilibria for polypropylene-hydrocarbon systems” . Ind. Eng. Chem. Res. , 39 : 4627 – 4633 .
  • Ndiaye , P.M. ; Dariva , C. ; Vladimir Oliveira , J. ; Tavares , F.W. (2001) Phase behavior of isotactic polypropylene/C4-solvents at high pressure. Experimental data and SAFT modeling. J. Seupercrit. Fluids , 21: 93–103.
  • Saraf , V.P. ; Kiran , E. ( 1988 ) Supercritical fluid-polymer interactions: phase equilibrium data for solutions of polystyrenes in n-butane and n-pentane . Polymer , 29 : 2061 – 2065 .
  • Xiong , Y. ; Kiran , E. ( 1997 ) Miscibility, density and viscosity of polystyrene in n-hexane at high pressures . Polymer , 38 : 5185 – 5193 .
  • Chrastil , J. ( 1982 ) Solubility of solids and liquids in supercritical gases . J. Phys. Chem. , 86 : 3016 – 3021 .
  • DIPPR 801. Evaluated Process Design Data, Public Release . ( 2003 ) AIChE, Design Institute for Physical Property Data, byu-DIPPR, thermophysical properties laboratory. Provo, UTAH .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.