Water and Mean Ionic Activities of Aqueous HNO₃ Solutions Calculated from an Extension of the Brunauer-Emmett-Teller (BET) Model

REFERENCES

• Rains , W.O. ; Counce , R.M. ; Spencer , B.B. ( 1999 ) Application of the Brunauer-Emmett-Teller Isotherm to the water-nitric acid system for the determination of mean ionic activity coefficients . Chem. Eng. Comm. , 171 : 169 – 180 .
   Web of Science ®Google Scholar
• Rains , W.O. ; Counce , R.M. ; Spencer , B.B. ( 2000 ) Analysis of the variability of parameters in the Brunauer-Emmett-Teller solution model for the nitric acid-water system . Ind. Eng. Chem. Res. , 39 : 236 – 239 .
   Google Scholar
• Davis , W. ; DeBruin , H.J. ( 1964 ). New activity coefficients of 0–100 per cent aqueous nitric acid . J. Inorg. Nucl. Chem. , 26 : 1069 – 1084 .
   Web of Science ®Google Scholar
• Clavelin , J.-L. ; Mirabel , P. ( 1979 ) No. 83-determination des pressions partielles du melange eau-acide nitrique . J. Chim. Phys. Phys.-Chim. Biol. , 76 : 533 – 537 .
   Google Scholar
• Taylor , G.B. ( 1928 ) Partial vapor pressures of aqueous solutions of HNO3, mmHg . In: International Critical Tables of Numerical Data, Physics, Chemistry and Technology , III , McGraw Hill : New York , 304 – 305 .
   Google Scholar
• Stokes , R.H. ; Robinson , R.A. ( 1948 ) Ionic hydration and activity in electrolyte solutions . J. Am. Chem. Soc. , 70 : 1870 – 1978 .
   PubMed Web of Science ®Google Scholar
• Brunauer , S. ; Emmett , P.H. ; Teller , E. ( 1938 ) Adsorption of gases in multimolecular layers . J. Am. Chem. Soc. , 60 : 309 – 319 .
   Web of Science ®Google Scholar
• Abraham , M. ( 1981 ) L'Activite d'un sel a hautes concentrations dan s L'Eau Pure . J. Chim. Phys. , 78 : 57 – 59 .
   Google Scholar
• Ally , M.R.; Braunstein, J. ( 1993 ) BET model for calculating activities of salts and water, molal enthalpies, molar volumes and liquid-solid phase behavior in concentrated electrolyte solutions . Fluid Phase Equilibria , 87 : 213 – 236 .
   Google Scholar
• Ally , M.R. ; Braunstein , J. ( 1998 ) Statistical mechanics of multilayer adsorption: Electrolyte and water activities in concentrated solutions . J. Chem. Thermodyn. , 30 : 49 – 58 .
   Google Scholar
• Tripp , T.B. ; Braunstein , J. ( 1969 ) Vapor pressures of aqueous melts lithium nitrate-potassium nitrate-water at 119–150 deg . J. Phys. Chem. , 73 : 1984 – 1990 .
   Google Scholar
• Braunstein , H. ; Braunstein , J. ( 1971 ) Isopiestic studies of very concentrated aqueous solutions of LiCl, LiBr, LiNO3, Ca(NO3)2, LiNO3 + KNO3, LiNO3 + Cs(NO3)2 and Ca(NO3)2 + CsNO3 at 100 to 150°C . J. Chem. Thermodyn. , 3 : 419 – 431 .
   Google Scholar
• Trudelle , M.C. ; Abraham , M. ; Sangster , J. ( 1977 ) Vapour pressures of aqueous solutions of AgNO3 + TlNO3 by the static method at 98.5°C . Can. J. Chem. , 55 : 1713 – 1719 .
   Google Scholar
• Sangster , J. ; Abraham , M.C. ; Abraham , M. ( 1979 ) Vapour pressures of aqueous solutions of (Ag,Tl, Ca)NO3 at 371.7 K . J. Chem. Thermodyn. , 11 : 619 – 625 .
   Google Scholar
• Richardson , C.B. ; Kurtz , C.A. ( 1984 ) Novel isopiestic measurement of water activity in concentrated and supersaturated lithium halide solution . J. Am. Chem. Soc. , 106 : 6615 – 6618 .
   Web of Science ®Google Scholar
• Emmons , H.H. ; Voigt , W. ; Wollny , W.F. (1979) On the calculation of activity coefficients of electrolyte solutions from vapour pressure data up to high temperatures and concentrations: The system MgCl2 + H2 . J. Electroanal. Chem. , 180: 57–65.
   Google Scholar
• Kodejs , Z. ; Spalkova , H. ; Sacchetto , G.A. ( 1988 ) Vapour pressures of very concentrated electrolyte solutions IV. Measurements on {(1 − x)(CH3)2SO + xKSCN} by a dew-point apparatus . J. Chem. Thermodyn. , 20 : 363 – 371 .
   Google Scholar
• Sacchetto , G.A. ; Kodejs , Z. ( 1989 ) Vapour pressures of very concentrated electrolyte solutions V. Measurements on {(1 − x)H2O + xKSCN} by a dew-point apparatus . J. Chem. Thermodyn. , 21 : 585 – 593 .
   Google Scholar
• Brendler , V. ; Voight , W. ( 1995 ) Isopiestic measurements at high temperature: II. The ternary system LiCl-MgCl2-H2O at 155°C . J. Solution Chem. , 24 : 917 – 924 .
   Google Scholar
• Ally , M.R. ( 2000 ) Liquidus curves of NaNO3(aq) calculated from the modified adsorption isotherm model for aqueous electrolytes . Monatshefte fur Chemie. , 131 : 341 – 344 .
   Google Scholar
• Voigt , W. ; Zeng , D. ( 2002 ) Solid-liquid equilibria in mixtures of molten salt hydrates for the design of heat storage materials . Pure Appl. Chem. , 74 : 1909 – 1920 .
   Google Scholar
• Rains , W.O. ; Counce , R.M. ( 2003 ) Liquidus curves of AgNO3(aq) calculated from the modified adsorption isotherm model for aqueous electrolytes . Monatshefte fur Chemie. , 134 : 1541 – 1544 .
   Google Scholar
• Rains , W.O. ; Counce , R.M. ( 2006 ) Liquidus Curves of NH4NO3(aq) calculated from the modified adsorption isotherm model for aqueous electrolytes . J. Sepn. Sci. Tech. , 41 : 2629 – 2634 .
   Web of Science ®Google Scholar
• Rains , W.O. ; Counce , R.M. ( 2007 ) Liquidus curves of LiNO3(aq) calculated from the modified adsorption isotherm model for aqueous electrolytes . J. Sepn. Sci. Tech. , 42 : 253 – 259 .
   Web of Science ®Google Scholar
• Marcus , Y. ( 2005 ) BET modeling of solid-liquid phase diagrams of common-ion binary salt hydrate mixtures. II. Calculation of liquidus temperatures . J. Soln. Chem. , 34 : 297 – 306 .
   Google Scholar
• Anderson , R.B. ( 1946 ) Modification of the Brunauer, Emmett and Teller equation . J. Am. Chem. Soc. , 68 : 686 – 691 .
   Web of Science ®Google Scholar
• Stokes , R.H. ; Robinson , R.A. ( 1973 ) Solvation equilibria in very concentrated electrolyte solutions . J. Soln. Chem. , 2 : 173 – 191 .
   Web of Science ®Google Scholar
• Nesbitt , W.H. ( 1982 ) The stokes and robinson hydration theory: A modification with application to concentrated electrolyte solutions . J. Soln. Chem. , 11 : 415 – 422 .
   Web of Science ®Google Scholar
• Zeng , D. ; Voigt , W. ( 2003 ) Phase diagram calculation of molten salt hydrates using the Modified BET equation . Comp. Coupling. Phase. Diag. Thermochem. , 27 : 243 – 251 .
   Google Scholar
• Clegg , S.L. ; Simonson , J.M. ( 2001 ) A BET model of the thermodynamics of aqueous multicomponent solutions at extreme condition . J. Chem. Thermodynamics. , 33 : 1457 – 1472 .
   Google Scholar
• Clegg , S.L. ; Brimblecombe , P. ( 1990 ) Equilibrium partial pressures and mean activity and osmotic coefficients of 0–100% nitric acid as a function of temperature . J. Phys. Chem. , 94 : 5369 – 5380 .
   Web of Science ®Google Scholar
• Brandani , S. ; Brandani , V. ( 1996 ) Vapor-liquid calculation of the system water-nitric acid over the entire concentration range . Fluid Phase Euilibria , 114 : 37 – 45 .
   Google Scholar
• Thermodynamic Research Center, Texas, TRC Thermodynamic Tables IV, Texas A&M University System, College Station, 500 , 1987 .
   Google Scholar
• Weast , R.C. ( 1975 ) Handbook of Chemistry and Physics ; CRC Press Inc. : Cleveland , D159 .
   Google Scholar
• Mason , D.O. ( 1929 ) Solute molecular volumes in relation to solvation and ionization . Phil. Mag. , 1 ( 8 ): 218 .
   Google Scholar