148
Views
7
CrossRef citations to date
0
Altmetric
EXTRACTION

Liquid-Liquid Extractions of Microamounts of 137Cs and 85Sr with Chlorinated Dicarbollide and Crown Ethers into Mixed Dodecanenitrile/n-dodecane Nonpolar Diluent

, , , &
Pages 2174-2182 | Received 15 Feb 2011, Accepted 03 Jun 2011, Published online: 21 Sep 2011

REFERENCES

  • Rais , J. ; Selucký , P. ; Kyrš , M. ( 1976 ) Extraction of alkali metals into nitrobenzene in the presence of univalent polyhedral borate anions . J. Inorg. Nucl. Chem. , 38 : 1376 .
  • Rais , J. ; Šebestová , E. ; Selucký , P. ; Kyrš , M. ( 1976 ) Synergistic effect of polyethylene glycols on the extraction of alkaline earth cations by nitrobenzene . J. Inorg. Nucl. Chem. , 38 : 1742 .
  • Kyrš , M. ; Heřmánek , S. ; Rais , J. ; Plešek , J. The Method of Extraction Isolation of Cesium Cations from their Aqueous Solutions. Czech. Patent 182,913, July 29, 1980; Rais, J.; Kyrš, M.; Heřmánek, S. The Method of Sr Isolation from Aqueous Solutions, Czech. Patent 153,933, June 15,1974.
  • Kyrš , M. ; Heřmánek , S. ; Rais , J. ; Plešek , J. The Method of Cs and Sr Separation from Aqueous Solutions. USSR Patent 508,476, March 30, 1976.
  • Lazarev , L.N. ; Lyubtsev , R.I. ; Galkin , B.Y. ; Romanovskii , V.N. ; Shishkin , D.N. ; Kyrš , M. ; Selucký , P. ; Rais , J. ; Heřmánek , S. ; Plešek , J. The Method of Isolation of Cs and Sr from Acid Waste Solutions. USSR Patent 1,031,088, June 6, 1981.
  • Herbst , R.S.; Law J.D. ; Todd , T.A. ; Romanovskii , V.N. ; Babain , V.A. Esimantovski , V.M. ; Smirnov , I.V. ; Zaitsev , B.N. (2002) Universal solvent extraction (UNEX) flowsheet testing for the removal of cesium, strontium, and actinide elements from radioactive, acidic dissolved calcine waste. Solvent Extr. Ion Exch. , 20: 429–445.
  • Pereira , C. ; Vandegrift , G.F. ; Regalbuto , M.C. ; Bakel , A. ; Bowers , D. ; Byrnes , J.P. ; Clark , M.A. ; Emery , J.W. ; Falkenberg , J.R. ; Hafenrichter , L. ; Krebs , J.F. ; Leonard , R. ; Maggos , L.E. ; Quigley , K.J. ; Laidler , J.J. Lab-Scale Demonstration of the UREX + 1a Process Using Spent Nuclear Fuel. AIChE National Meeting, San Francisco, USA, November 12–17, 2006.
  • Lazarev , L.N. ; Pushlenkov , M.F. ; Babain , V.A. ; Esimantovski , V.M. ; Starchenko , V.A. ; Dzekun , E.G. ; Gladyshev , M.V. ; Shidlovskiy , V.M. ; Prokopchuk , Yu.Z. Method of treatment of liquid radioactive wastes. USSR Patent 1,603,552 A1, July 30, 1994.
  • Herbst , R.S. ; Law , J.D. ; Todd , T.A. ; Romanovskii , V.N. , Babain , V.A. ; Esimantovski , V.M. ; Zaitsev , B.N.; Smirnov I.V. ( 2002 ) Development and testing of a cobalt dicarbollide based solvent extraction process for the separation of cesium and strontium from acidic tank waste . Sep. Sci. Technol. , 37 : 1807 .
  • Koprda , V. ; Ščasnár , V. ( 1980 ) Separation of 137Cs and 90Sr from biomaterials by using dicarbollide compounds . Chem. Zvesti ., 34 : 480 .
  • Blasius , E. ; Nilles , K.H. Process for the extraction of cesium ions from aqueous solutions using an adduct compound containing a macrocyclical polyether and an inorganic heteropoly acid. U.S. Patent 4,452,702, June 5, 1984.
  • Blasius , E. ; Nilles , K.H. Process for the extraction of cesium ions from aqueous solutions U.S. Patent 4,647,440, March 3, 1987.
  • McDowell , W.J. , Case , G.N. , McDonough , J.A. , Bartsch , R.A. ( 1992 ) Selective extraction of cesium from acidic nitrate solutions with didodecylnaphthalenesulfonic acid synergized with bis(tert-butylbenszo)-21-crown-7 . Anal. Chem. , 64 : 3013 – 3017 .
  • Horwitz , E.P. ; Dietz , M.L. ; Fisher , D.E. ( 1991 ) SREX – A new process for the extraction and recovery of strontium from acidic nuclear waste streams . Solvent Extr. Ion Exch. , 9 : 1 .
  • Smirnov , I.V. ; Stoyanov , E.S. ; Vorob'eva , T.P. ( 2003 ) Nature of strontium extraction by synergistic mixtures of chlorinated cobalt dicarbollide and polyethers . Czech. J. Phys. , 53 : A501 – A508 .
  • Rais , J. ; Okada , T. ; Alexová , J. ( 2006 ) Gibbs energies of transfer of alkali metal cations between mutually saturated water-solvent systems determined from extraction experiments with radiotracer 137Cs . J. Phys. Chem. B , 110 : 8432 .
  • Miller , R.L. ; Pinkerton , A.B. ;, Hurlburt , P.K. ; Abney , K.D. ( 1995 ) Extraction of cesium and strontium into hydrocarbon solvents using tetra-c-alkyl cobalt dicarbollide . Solv. Extr. Ion Exch. , 13 : 813 – 827 .
  • Rais , J. ; Selucký , P. ; Šístková , N.V. ; Alexová , J. ( 1999 ) Extraction of 137Cs and 90Sr from alkaline solutions with high NaNO3 content with tetrahexyldicarbollide . Sep. Sci. Tech. , 34 : 2865 .
  • Lamb , J.D. ; Nazarenko , A.Y. ; Hansen , R.J. ( 1999 ) Novel solvent system for metal ion separation: Improved solvent extraction of strontium(II) and lead(II) as dicyclohexano-18-crown-6 Complexes . Sep. Sci. Technol. , 34 : 2583 .
  • Abboud , J.-L.M. ; Notario , R. ( 1999 ) Critical compilation of scales of solvent parameters. Part I. Pure, non-hydrogen bond donor solvents . Pure Appl. Chem. , 71 : 645 .
  • http://www.thegoodscentscompany.com/data/rw1004961.html, last accessed 11.1.2011.
  • Dietz , M.L. ; Horwitz , E.P. ; Bartsh , R.A. ; Barrans , Jr. R.E. ; Rausch , D. Composition and process for separating cesium ions from an acidic aqueous solution also containing other ions U.S. Patent No 5,888,398, March 30, 1999.
  • Flink , S. ; van Veggel , F.C. J.M. ; Reinhoudt , D.N. ( 1999 ) Recognition of cations by self-assembled monolayers of crown ethers . J. Phys. Chem. B , 103 : 6515 .
  • Beadle , J.R. ; Dishong , D.M. ; Khanna , R.K. ; Gokel , G.W. ( 1984 ) Synthesis and properties of arenediazonium and anilinium cation lariat ether complexes: An “ostrich molecule” complex and evidence for intramolecular sidearm – macroring interaction . Tetrahedron , 40 : 3935 .
  • Ikeda , I. ; Emura , H. ; Okahara , M. ( 1984 ) Hydrophilicity and complexing ability of alkyl lariat ethers . Bull. Chem. Soc. Jpn. , 57 : 1612 .
  • Matsumura , H. ; Watanabe , T. ; Furusawa , K. ; Inokuma , S. ; Kuwamura , T. ( 1987 ) Electrical double layer formed on the monolayers of crown ether compounds . Bull. Chem. Soc. Jpn. , 60 : 2747 .
  • Rais , J. ( 2004 ) Principles of Extraction of Electrolytes . In: Ion Exchange, Solvent Extraction , Marcus , Y. ; SenGupta , A.K. , eds.; Marcel Dekker : New York , USA , Vol. 17 , 335 .
  • Marcus , Y. ( 2006 ) On the activity coefficients of charge-symmetrical ion pairs . J. Mol. Liquids , 123 : 8 – 13 .
  • Marcus , Y. ( 1997 ) Ion Properties ; Marcel Dekker : New York .
  • Marcus , Y. ( 1999 ) Properties of Solvents ; Wiley : New York .
  • Gritzner , G. ( 1997 ) A critical view on the Lewis-donor (nucleophilic) properties of solvents . J. Mol. Liquids , 73,74 : 487 .
  • Vaňura , P. ; Rais , J. ; Selucký , P. ; Kyrš , M. ( 1979 ) Extraction of strontium with dicarbollide in the presence of polyethyleneglycol . Coll. Czech. Chem. Comm. , 44 : 157 .
  • Wright , M.R. ( 2007 ) An Introduction to Aqueous Electrolyte Solutions ; John Wiley & Sons Ltd : Chichester .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.