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Separation Science and Technology Volume 47, 2012 - Issue 9
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ION-EXCHANGE (MATERIALS AND METHODS)

The Effect of Foreign Ions on Separation of Hafnium from Zirconium on Diphonix® Resin

Marek Smolik Department of Chemistry, Inorganic Technology and Fuels, Faculty of Chemistry, Silesian University of Technology, Gliwice, PolandCorrespondence[email protected]
,
Zbigniew Hubicki Department of Inorganic Chemistry, Faculty of Chemistry, Marie Curie-Skłodowska University, Lublin, Poland
,
Agata Jakóbik-Kolon Department of Chemistry, Inorganic Technology and Fuels, Faculty of Chemistry, Silesian University of Technology, Gliwice, Poland
,
Teofil Korolewicz Department of Chemistry, Inorganic Technology and Fuels, Faculty of Chemistry, Silesian University of Technology, Gliwice, Poland
&
Łukasz Siepietowski Department of Chemistry, Inorganic Technology and Fuels, Faculty of Chemistry, Silesian University of Technology, Gliwice, Poland
Pages 1341-1344 | Received 15 Oct 2011, Accepted 20 Feb 2012, Published online: 15 Jun 2012

REFERENCES

  • Smolik , M. ; Jakóbik-Kolon , A. ( 2009 ) Determination of microamounts of hafnium in zirconium using inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry during their separation by ion exchange on Diphonix® chelating resin . Analytical Chemistry , 81 ( 7 ): 2685 .
  • Smolik , M. ; Jakóbik-Kolon , A. ( 2009 ) Separation of zirconium and hafnium using Diphonix® chelating ion-exchange resin . Hydrometallurgy , 95 : 350 .
  • Hubicki , Z. ( 1988 ) Separation of zirconium(IV) from hafnium(IV) on various types of selective ion-exchangers . Solvent Extraction and Ion Exchange , 6 ( 1 ): 183 .
  • Hurst , F.J. ( 1983 ) Separation of hafnium and zirconium in sulfuric acid solutions using pressurized ion exchange . Hydrometallurgy , 10 ( 1 ): 1 .
  • Poriel , L. ; Pellet-Rostaing , S. ; Lamotte , V. ; Lemaire , M. ( 2006 ) Zirconium and hafnium separation, Part 2. Solid/liquid extraction in hydrochloric acid aqueous solution with anion exchange resins . Separation Science and Techology , 41 : 2711 .
  • Byers , C. H. ; Sisson , W. G. ; Snyder , T. S. ; Beleski , R. G. ; Francis , T. L. ; Nayak , Umesh . Separation of zirconium and hafnium from crude oxychloride solutions by continuous ion-exchange chromatography to obtain nuclear-grade metals . Patent WO9704141 1997 .
  • Smolik , M. ; Hubicki , Z. ; Jakóbik-Kolon , A. ; Korolewicz , T. ; Siepietowski , Ł. ( 2011 ) Determination of trace amounts of chosen elements in zirconium salts by means of ICP-OES and ICP-MS . Science and industry – spectroscopic methods in practice. New challenges and scopes . Lublin , 367 – 370 (in Polish)
  • Chiarizia , R. ; Horwitz , E.P. ; Gatrone , R.C. ; Alexandratos , S.D. ; Trochimczuk , A.Q. ; Crick , D.W. ( 1993 ) Uptake of metal ions by a new chelating ion-exchange resin. Part 2: Acid dependencies of transition and post-transition metal ions . Solvent Extraction and Ion Exchange , 11 ( 5 ): 967 .
  • Chiarizia , R. ; Horwitz , E.P. ; Alexandratos , S.D. ; Gula , M.J. ( 1997 ) Diphonix® resin: a review of its properties and applications . Separation Science and Technology , 32 : 1 .
  • Lee , M.S. ; Nicol , M.J. ( 2007 ) Removal of iron from cobalt sulfate solutions by ion exchange with Diphonix resin and enhancement of iron elution with titanium(III) . Hydrometallurgy , 86 : 6 .

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