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EXTRACTION

Solvent Extraction of Ti(IV) from Acidic Sulphate Medium by Cyanex 301 Dissolved in Kerosene

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Pages 278-289 | Received 11 Nov 2012, Accepted 20 Aug 2013, Published online: 17 Jan 2014

REFERENCES

  • Sole , K.C. ( 1999 ) Recovery of titanium from the leach liquors of titaniferous magnetites by solvent extraction. II. Laboratory scale studies . Hydrometallurgy , 51 : 263 – 274 .
  • Sole , K.C. ( 1999 ) Recovery of titanium from the leach liquors of titaniferous magnetites by solvent extraction. Part I. Review of the literature and aqueous thermodynamics . Hydrometallurgy , 51 : 239 – 253 .
  • Reddy , M.L.P. ; Saji , J. ( 2002 ) Solvent extraction of tetravalent titanium with organophosphorus extractants . Miner. Process. Extr. Metall. Rev. , 23 : 199 – 227 .
  • Zhu , Z. ; Zhang , W. ; Cheng , C.Y. ( 2011 ) A literature review of titanium solvent extraction in chloride media . Hydrometallurgy , 105 : 304 – 313 .
  • Lakshmanan , V.I. ; Sridhar , R. ; Rishea , M.M. ; Joseph , D.E. ; Laat , R. ( 2001 ) Production of titanium metal from titanium bearing ores involving leaching and selective removal of iron values by solvent extraction. US Patent 2001/007646 A1.
  • Lakshmanan , V.I. ; Sridhar , R. ; Rishea , M.N. ; Joseph , D.E. ; Laat , R. ( 2002 ) Separation of titanium halides from aqueous solutions. US Patent, 2002, 6: 500.3960.
  • Lakshmanan , V.I. ; Sridhar , R. ; Risha , M.N. ; Joseph , D.E. ; Laat , R. ( 2004 ) Methods for separation of titanium from ore. US Patent, 2004, 6699446-B2.
  • Lakshmanan , V.I. ; Sridhar , R. ; Hains , D.H. ( 2004 ) A novel hydrometallurgical process for very high purity TiO2 production. 17th Industrial Minerals International Congress. Cambrian Printer, Aberystwyth, UK; pp. 92–95.
  • Lakshmanan , V.I. ; Sridhar , R. ; Harris , B.G. ; Pawada , G. ( 2005 ) Process for the recovery of titanium in mixed chloride media. WO Patent 2005, 2005/049872.
  • Willem , P.C.D. ; Bruce , J.S. ; Dirk , E.V.V. ; Paul , G.W. ; Timothy , M.S. ; Andrew , V. ; James , R.B. ; Bernardus , J.P.M.H. ( 2002 ) Processing titaniferrous ore to titanium dioxide pigment. US Patent 2002, 6375923.
  • Duyvesteyn , W. ; Sabachy , B. ; Edmund , V. ; Verhulst , D. ; West-sells , P.G. ; Spitler , T.M. ; Vince , A. ; Burkholder , J.R. ; Paulus , B.J. ; Huls , M. ( 2002 ) Processing titaniferous ore to titanium dioxide pigment. US Patent 2002, 6375923 B1.
  • Verhulst , D. ; Sabachy , B. ; Spitler , J. ; Duyvesteyn , W. ( 2002 ) New development in the altair hydrochloride TiO2 pigment process In: Young, C.A.; Alfantazi, A.M.; Dreisinger, D.B.; Harris, B.; James, A. (Eds.), Hydrometallurgy 2003 5th International Conference in Honor of Professor Ian Ritchie. Vol: Leaching and Purification. 2002, pp. 565–575. TMS 2003.
  • Wang , B.Z. ; Sabacky , B.J. ; Verhulst , D.E. ; Ward , J. ( 2008 ) Solvent extraction of titanium using an aromatic diluent. WO Patent 2008/157275.
  • Biswas , R.K. ; Karmakar , A.K. ( 2013 ) Solvent extraction of Ti(IV) in the Ti(IV)- (H+, Na+) – Cyanex 302-kerosene-5% (v/v) hexan-1-ol system. Hydrometallurgy, 134–135: 1–10.
  • Deep , A. ; Malik , P. ; Gupta , B. ( 2001 ) Extraction and separation of Ti(IV) using thiophosphic acids and its recovery from ilmenite and red mud . Sep. Sci. Technol. , 36 : 671 – 685 .
  • Sole , K.C. ; Hiskey , J.B. ( 1992 ) Solvent extraction characteristics of thiosubstituted organophosphinic acid extractants . Hydrometallurgy , 30 : 345 – 365 .
  • Bassette , J. ; Denny , R.C. ; Jeffery , G.H. ; Mendham , J. (1979) Vogel's Textbook of Quantitative Inorganic Analysis, , 4th ed.; ELBS : London, pp. (a) 750 (b) 752 (c) 741.
  • Biswas , R.K. ; Begum , D.A. ( 1998 ) Solvent extraction of Fe(III) from chloride solution by D2EHPA in kerosene . Hydrometallurgy , 50 : 153 – 168 .
  • Zhengshui , H. ; Ying , P. ; Wanwu , M. ; Xun , F. ( 1995 ) Purification of organophosphorus acid extractants . Solvent Extr. Ion Exch. , 13 : 965 – 976 .
  • Zhu , Y. ; Chen , J. ; Jiao , R. ( 1996 ) Extraction of Am(III) and Eu(III) from nitrate solution with purified Cyanex 301 . Solvent Extr. Ion Exch. , 14 : 61 – 68 .
  • Paatero , E. ; Lantto , T. ; Ernola , P. ( 1990 ) The effect of trioctylphosphine oxide on phase and extraction equilibria in systems containing bis(2,4,4-trimethylpentyl) phosphinic acid . Solvent Extr. Ion Exch. , 8 : 371 – 388 .
  • Ulewicz , M. ; Walkowiak , W. ( 2005 ) Selective removal of transition metal ions in transport through polymer inclusion memberances with organophosphorus acid . Environ. Prot. Eng. , 31 : 74 – 81 .
  • Saji , J. ; Reddy , M.L.P. ( 2003 ) Selective extraction and separation of titanium(IV) from multivalent metal chloride solutions using 2-ethylhexyl phosphonic acid mono 2-ethylhexyl ester . Sep. Sci. Technol. , 38 : 427 – 441 .
  • Saji , J. ; Saji , J.K. ; Reddy , M.L.P. ( 2000 ) Liquid-liquid extraction of tetravalent titanium from acidic chloride solutions by bis(2,4,4-trimethylpentyl)phosphinic acid . Solvent Extr. Ion Exch. , 18 : 877 – 894 .
  • Cotton , F.A. ; Wilkinson , G. ( 1980 ) Advanced Inorganic Chemistry-A Comprehensive Text, , 4th ed. ; Wiley : New York , pp. 692 – 704 .
  • Pourbaix , M. ( 1966 ) Atlas of Electrochemical Equilibria in Aqueous Solutions ; Pergamon : Oxford , pp. 213 – 222 .
  • Biswas , R.K. ; Begum , D.A. ( 1998 ) Solvent extraction of tetravalent titanium from chloride solution by D2EHPA in kerosene . Hydrometallurgy , 49 : 263 – 274 .
  • Sato , T. ; Sato , K. ( 1991 ) Solvent extraction of titanium(IV) from hydrochloric and sulphuric acid solution by acid organo-phosphorus compounds. Recent Advances in Science and Engineering of Light Metals (RASELM ‘91). Tokyo, Japan, pp. 597–602.
  • Islam , F. ; Biswas , R.K. ( 1981 ) The solvent extraction of Ti(IV), Fe(III) and Mn(II) from acidic sulfate-acetato media with HDEHP in benzene . J. Inorg. Nucl. Chem. , 43 : 1929 – 1933 .
  • Biswas , R.K. ; Zaman , M.R. ; Islam , M.N. ( 2002 ) Extraction of TiO2+ from 1 M (Na+, H+) by D2EHPA . Hydrometallurgy , 63 : 159 – 169 .
  • Fontana , D. ; Kulkarni , P. ; Pietrelli , L. ( 2005 ) Extraction of titanium (IV) from acidic media by 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester . Hydrometallurgy , 77 : 219 – 225 .
  • Biswas , R.K. ; Ali , M.R. ( 1987 ) Solvent extraction of Ti(IV) from acidic sulfate solutions by HDTP-benzene-i-butanol system. Rajshahi University Studies (Press & Publication Department of Rajshahi University) , 15B : 51 – 63 .
  • Karmakar , A.K. ( 2012 ) Solvent extraction of Ti(IV) and V(IV) by Cyanex 301 and Cyanex 302 and application of Yates experimental design. Ph.D thesis, Rajshahi University, Rajshahi, Bangladesh.
  • Kadyrova , G.I. ; Ivanenko , V.I. ; Ivanova , E.A. ( 1983 ) Polymerization of titanium(IV) in sulfate perchlorate solutions . Russ. J. Inorg. Chem. , 28 : 1075 – 1076 .
  • Kadyrova , G.I. ; Ivanenko , V.I. ( 1981 ) Potentiometric study of the polymerization of titanium(IV) in sulfate perchlorate solutions . Russ. J. Inorg. Chem. , 26 : 839 – 842 .
  • Kadyrova , G.I. ; Ivanova , E.A. ( 1979 ) Polymerization of titanium(IV) in sulfate solutions . Russ. J. Inorg. Chem. , 24 : 1645 – 1648 .
  • Islam , F. ; Biswas , R.K. ( 1978 ) Kinetics and mechanism of solvent extraction of Ti(IV) from acidic aqueous solutions with HDEHP in benzene . J. Inorg. Nucl. Chem. , 40 : 569 – 566 .
  • Sato , T. ; Nakamura , T. ( 1975 ) The extraction of titanium(IV) and aluminium(III) from sulfuric acid solutions by di-(2-ethylhexyl)-phosphoric acid . Anal. Chim. Acta. , 76 : 401 – 408 .
  • Potter , E.C. ( 1961 ) Electrochemical Principles and Applications ; Cleaver House Press : London , p. 51 .
  • Smith , R.M. ; Martell , A.E. ( 1976 ) Critical Stability Constants, Vol. 4, Inorganic Complexes, Plenum Press: New York; p. 79.
  • Singh , R.K. ; Dhadke , P.M. ( 2002 ) Extraction and separation of titanium(IV) with D2EHPA and PC-88A from aqueous perchloric acid solutions . J. Serb. Chem. Soc. , 67 : 507 – 521 .
  • El-Hefny , N.E. ( 2010 ) Kinetics and mechanism of extraction of Cu(II) by Cyanex 302 from nitrate medium and oxidative stripping of Cu(I) using Lewis Cell . Chem. Eng. Process , 49 : 84 – 90 .
  • Sole , K.C. ; Hiskey , J.B. ( 1995 ) Solvent extraction of copper by Cyanex 272, Cyanex 302, and Cyanex 301 . Hydrometallurgy , 37 : 129 – 147 .
  • Bhattacharyya , A. ; Mohapatra , P.K. ; Manchanda , V.K. ( 2006 ) Seperation of Americium(III) and Europium(III) from nitrate medium using a binary mixture of Cyanex 301 with N-donor ligands . Solvent Extr. Ion Exch. , 24 : 1 – 17 .
  • Menoya , B. ; Elizalde , M.P. ; Almela , A. ( 2002 ) Determination of the degradation compounds formed by the oxidation of thiophosphinic acids and phosphine sulphides with nitric acid . Anal. Sci. , 18 : 799 – 804 .
  • Sole , K.C. ; Hiskey , J.B. ; Ferguson , T.L. ( 1993 ) An assessment of the long term stabilities of Cyanex 302 and Cyanex 301 in sulfuric and nitric acids . Solvent Extr. Ion Exch. , 11 : 783 – 796 .
  • Demopoulos , G.P. ; Mihaylov , I.O. ; Pouskouleli , G. ( 1993 ) Synergistic extraction of Fe(III) from sulphuric acid solution with mixed Kelex100-alkylphosphorus derivatives . Solvent Extr. Ion Exch. , 11 : 67 – 89 .
  • Jayachandran , J. ; Dhadke , P.M. ( 1998 ) Solvent extraction of titanium(IV) with 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (HEHEHP) . J. Chem. Eng. Jpn. , 31 : 465 – 468 .
  • Jayachandran , J. ; Dhadke , P.M. ( 1997 ) Liquid-liquid extraction of iron(III) with 2-ethylhexyl phosphonic acid mono 2-ethylhexyl ester . Talanta. , 44 : 1285 – 1290 .
  • Islam , M.F. ; Biswas , R.K. ; Mustafa , C.M. ( 1985 ) Solvent extraction of Ti(IV), Fe(II) and Fe(III) from acidic sulphate medium with di-o-tolyl phosphoric acid-benzene-hexan-1-ol system: A separation and mechanism study . Hydrometallurgy , 13 : 365 – 376 .
  • Mohiuddin , M. ; Begum , D.A. ; Islam , F. ; Islam , M.S. ( 1998 ) The solvent extraction of titanium(IV) from aqueous acidic sulphate media with Cyanex 272 . J. Bangladesh Acad. Sci. , 22 : 247 – 253 .

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