90
Views
0
CrossRef citations to date
0
Altmetric
Original Articles

Determination of N, N’, N’’-tris(3,7-dimethyloctyl)guanidine (TiDG) in Cesium Extraction Solvent

, , &
Pages 2866-2872 | Received 13 Nov 2014, Accepted 18 Aug 2015, Published online: 08 Jan 2016

REFERENCES

  • Savannah River Site Strategic Plan (2010) U. S. Department of Energy, Savannah River Site, Aiken, SC.
  • Wilmarth, W. R.; Johnson, M. E.; Lumetta, G.; Poirier, M. R.; Thompson, M. C.; Machara, M. (2008) The Role of Liquid Waste Treatment Technologies in Solving DOE Clean-up Mission. Technical Report SRNL-STI-2008-00426, Savannah River National Laboratory, Aiken, SC, October 2008.
  • Linking Legacies: Connecting the Cold War Nuclear Weapons Production Processes to Their Environmental Consequences (1997) U. S. Department of Energy, Office of Environmental Management, Washington, DC.
  • Delmau, L.H.; Birdwell, J. F., Jr.; McFarlane, J.; Moyer, B. A. (2010) Robustness of the CSSX Process to feed variation: Efficient cesium removal from the high potassium wastes at Hanford. Solvent Extr. Ion Exc., 28 (1): 19–48.
  • Moyer, B. A.; Birdwell, J. F, Jr..; Bonnesen, P. V.; Delmau, L. H. (2005) Use of Macrocycles in Nuclear-Waste Cleanup: A Realworld Application of a Calixcrown in Cesium Separation Technology. in Gloe, K., Ed.; Macrocyclic Chemistry – Current Trends and Future Perspectives; Springer: Dordrecht.
  • Bonnesen, P. V.; Delmau, L. H.; Moyer, B. A.; Leonard, R. A. (2001) A robust alkaline-side CSEX solvent suitable for removing cesium from Savannah River High Level waste. Solvent Extr. Ion Exc., 18 (6): 1079–1107.
  • White, T. L.; Herman, C. C.; Crump, S. L.; Marinik, A. R.; Lambert, D. P.; Eibling, R. E. (2007) Analysis of cesium extracting solvent using GCMS and HPLC. J. Radioanal. Nucl. Chem., 274 (3): 609–620.
  • Moyer, B. A.; Bonnesen, P. V.; Delmau, L. H.; Sloop, F. V., Jr.; Williams, N. J.; Birdwell, J. F., Jr.; Lee, D. L.; Leonard, R. L.; Fink, S. D.; Peters, T. B.; Geeting, M. W. (2011) Development of Next-Generation Caustic-Side Solvent Extration (NG-CSSX) process for cesium removal from high-level tank waste, Waste Management Conference, Phoenix, Arizona.
  • Moyer, B. A.; Delmau, L. H.; Duncan, N. C.; Ensor, D. D.; Hill, T. G.; Lee, D. L.; Roach, B. D.; Sloop, F.V., Jr.; Williams, N. J. (2012) Recommended Guanidine Suppressor for the Next-Generation Caustic-Side Solvent Extaction Process, Report ORNL/TM-2012/625, Oak Ridge National Laboratory, Oak Ridge, Tennessee.
  • Herman, D. T.; Duignan, M. R.; Williams, M. R.; Peters, T. B.; Poirier, M. R.; Fondeur, F. F. (2013) Mass Transfer and Hydraulic Testing of the V-05 and V-10 Contactors with the Next Generation Solvent, SRNL-STI-2013-00413, Rev. 0, July 2013.
  • Moyer, B. A.; Delmau, L. H.; Roach, B. D.; Williams, N. J. (2013) Thermal Degradation of Next Generation Solvent using Triisodecylguanidine Suppressor: Impacts on Solvent Performance and Organic Content of Aqueous Effluents, ORNL-LTR-NGCSSX-020, Rev. 1, July 2013.
  • Hall, H. K., Jr. (1957) Correlation of the base strengths of amines. J. Am. Chem. Soc., 79: 5441.
  • Peters, T. B.; Washington, A. L., II (2013) Sample Results from the Next Generation Solvent Program Real Waste Extraction-Scrub-Strip Testing, SRNL-STI-2013-00256, Rev. 0, June 2013.
  • Olah, G. A.; Burrichter, A.; Rasul, G.; Hachoumy, M.; and Prakash, G. K. S. (1997) 1H, 13C, 15N NMR and Ab Initio/IGLO/GIAO-MP2 Study of Mono-, Di-, Tri-, and tetraprotonated guanidine, J. Am. Chem. Soc., 119: 12929.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.