Investigation of the Impacts of Gamma Radiolysis on an Advanced TALSPEAK Separation

REFERENCES

• Hudson, M. J.; Harwood, L. M.; Laventine, D. M.; Lewis, F. W. (2013) Use of soft heterocyclic N- donor ligands to separate actinides and lanthanides. Inorganic Chemistry, 52(7): 3414–3428.
   PubMed Web of Science ®Google Scholar
• Todd, T. A. (2010) Separation Research for Advanced Nuclear Fuel Cycles in Wai, C. M., Mincher, B. J. (Eds.) Nuclear Energy and the Environment; American Chemical Society: Washington, D.C.
   Google Scholar
• Horwitz, E. P.; Kalina, D. G.; Diamond, H.; Vandegrift, G. F.; Schulz, W. W. (1985) The TRUEX process: A process for the extraction of the transuranic elements from nitric acid wastes utilizing modified PUREX solvent. Solvent Extraction and Ion Exchange, 3: 75–109.
   Web of Science ®Google Scholar
• Nilsson, M.; Nash, K. L. (2007) Review article: A review of the development and operational characteristics of the TALSPEAK process. Solvent Extraction and Ion Exchange, 25(6): 665- 701.
   Web of Science ®Google Scholar
• Nash, K. L. (2015) The Chemistry of TALSPEAK: A review of the science. Solvent Extraction and Ion Exchange, 33(1): 1–55.
   Web of Science ®Google Scholar
• Weaver, B.; Kappelmann, F. A. (1964) TALSPEAK: A New Method of Separating Americium and Curium from the Lanthanides by Extraction from an Aqueous Solution of an Aminopolyacetic Acid Complex with a Monoacidic Organophosphate or Phosphonate. In Oak Ridge National Laboratory: Oak Ridge, TN, 1964.
   Google Scholar
• Weaver, B.; Kappelmann, F. A. (1968) Preferential extraction of lanthanides over trivalent actinides by monoacidic organophosphates from carboxylic acids and from mixtures of carboxylic and aminopolyacetic acids. Journal of Inorganic and Nuclear Chemistry, 30: 263–272.
   Web of Science ®Google Scholar
• Regalbuto, M. C. (2011) 7 - Alternative separation and extraction: UREX+ processes for actinide and targeted fission product recovery in Nash, K.L., Lumetta, G.J. (Eds) Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment; Woodhead Publishing
   Google Scholar
• Nilsson, M.; Nash, K. L. (2009) Trans-lanthanide extraction studies in the TALSPEAK system; Investigating the effect of acidity and temperature. Solvent Extraction and Ion Exchange, 27: 354–377.
   Web of Science ®Google Scholar
• Braley, J. C.; Grimes, T. S.; Nash, K. L. (2011) Alternatives to HDEHP and DTPA for Simplified TALSPEAK Separations. Industrial & Engineering Chemistry Research, 51(2): 629–638.
   Web of Science ®Google Scholar
• Del Cul, G. D.; Toth, L. M.; Bond, W. D.; Davis, G. D.; Dai, S. (1997) Citrate-based “TALSPEAK” actinide-lanthanide separation process. Separation Science and Technology, 32: 431–446.
   Web of Science ®Google Scholar
• Lumetta, G. J.; Casella, A. J.; Rapko, B. M.; Levitskaia, T. G.; Pence, N. K.; Carter, J. C.; Niver, C. M.; Smoot, M. R. (2014) An advanced TALSPEAK concept using 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester as the extractant. Solvent Extraction and Ion Exchange: 1–13.
   Google Scholar
• Tachimori, S.; Nakamura, H. (1979) Radiation effects on the separation of lanthanides and transplutonides by the TALSPEAK-type extraction. J. Radioanal. Chem., 52(2): 343–354.
   Web of Science ®Google Scholar
• Zhengshui, H.; Ying, P.; Wanwu, M.; Xun, F. (1995) Purification of organophosphorus acid extractants. Solvent Extraction and Ion Exchange, 13(5): 965- 976.
   Web of Science ®Google Scholar
• Klassen, N. V.; Shortt, K. R.; Seuntjens, J.; Ross, C. K. (1999) Fricke dosimetry: the difference between G(Fe3+) for 60Co gamma-rays and high-energy x-rays. Phys. Med. Biol., 44: 1609- 1624.
   PubMed Web of Science ®Google Scholar
• Black, T. H. (1983) The preparation and reactions of diazomethane. Aldrichimica Acta, 16(1): 3- 10.
   Google Scholar
• Dodi, A.; Verda, G. (2001) Improved determination of tributyl phosphate degradation products (mono- and dibutyl phosphates) by ion chromatography Journal of Chromatography A, 920: 275- 281.
   Google Scholar
• Laine, P.; Matilainen, R. (2005) Simultaneous determination of DTPA, EDTA, and NTA by UV-Visible spectrometry and HPLC. Anal Bioanal Chem, 382: 1601- 1609.
   PubMed Web of Science ®Google Scholar
• Dodi, A.; Monnier, V. (2004) Determination of ethylenediaminetetraacetic acid at very low concentrations by high-performance liquid chromatography coupled with electrospray mass spectrometry. Journal of Chromatography A, 1032(1–2): 87–92.
   PubMed Web of Science ®Google Scholar
• Bergers, P. J. M.; Groot, A. C. d. (1994) The analysis of EDTA in water by HPLC. Water Research, 28(3): 639- 642.
   Web of Science ®Google Scholar
• Buxton, G. V.; Greenstock, C. L.; Helman, W. P.; Ross, A. B. (1988) Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (·OH/·O-) in aqueous solution. Journal of Physical and Chemical Reference Data, 17(2): 513–886.
   Web of Science ®Google Scholar
• Mincher, B. J.; Mezyk, S. P. (2009) Radiation chemcial effects on radiochemistry: A review of examples important to nuclear power. Radiochimica Acta, 97: 519- 534.
   Web of Science ®Google Scholar
• Mincher, B. J.; Curry, R. D. (2000) Considerations for choice of a kinetic fig. of merit in process radiation chemistry for waste treatment. Applied Radiation and Isotopes, 52: 189–193.
   PubMed Web of Science ®Google Scholar