Unmodified SBA-15 adsorbents for the removal and separation of Th(IV) and U(VI) ions: the role of pore channels and surface-active sites

References

• Feng, M.L.; Sarma, D.; Qi, X.H.; Du, K.Z.; Huang, X.Y.; Kanatzidis, M.G. (2016) Efficient removal and recovery of uranium by a layered organic–inorganic hybrid thiostannate. Journal of the American Chemical Society, 138: 12578–12585. doi:10.1021/jacs.6b07351.
   PubMed Web of Science ®Google Scholar
• Abd El–Magied, M.O.; Elshehy, E.A.; Manaa, E.S.A.; Tolba, A.A.; Atia, A.A. (2016) Kinetics and thermodynamics studies on the recovery of thorium ions using amino resins with magnetic properties. Industrial & Engineering Chemistry Research, 55: 11338.
   Web of Science ®Google Scholar
• Varala, S.; Kumari, A.; Dharanija, B.; Bhargava, S.K.; Parthasarathy, R.; Satyavathi, B. (2016) Removal of thorium (IV) from aqueous solutions by deoiledkaranja seed cake: Optimization using Taguchi method, equilibrium, kinetic and thermodynamic studies. Journal of Environmental Chemical Engineering, 4: 405–417. doi:10.1016/j.jece.2015.11.035.
   Web of Science ®Google Scholar
• Karimi, M.; Alamdar Milani, S.; Abolgashemi, H. (2016) Kinetic and isotherm analyses for thorium (IV) adsorptive removal from aqueous solutions by modified magnetite nanoparticle using response surface methodology (RSM). Journal of Nuclear Materials, 479: 174–183. doi:10.1016/j.jnucmat.2016.07.020.
   Web of Science ®Google Scholar
• Salem, N.A.; Ebrahim Yakoot, S.M. (2016) Adsorption kinetic and mechanism studies of thorium on nitric acid oxidized activated carbon. Desalination and Water Treatment, 57: 28313.
   Web of Science ®Google Scholar
• Hosseini–Bandegharaei, A.; Allahabadi, A.; Rahmani–Sani, A.; Rastegar, A.; Khamirchi, A.; Mehrpouyan, M.; Hekmat–Shoar, R.; Pajohankia, Z. (2016) Thorium removal from weakly acidic solutions using titan yellow–impregnated XAD–7 resin beads: kinetics, equilibrium and thermodynamic studies. The Journal of Radioanalytical and Nuclear Chemistry, 309: 761.
   Web of Science ®Google Scholar
• Anirudhan, T.S.; Suchithra, P.S.; Senan, P.; Tharun, A.R. (2012) Kinetic and equilibrium profiles of adsorptive recovery of thorium(IV) from aqueous solutions using poly (methacrylic acid) grafted cellulose/bentonite super absorbent composite. Industrial & Engineering Chemistry Research, 51: 4825.
   Web of Science ®Google Scholar
• Elsalamouny, A.R.; Desouky, O.A.; Mohamed, S.A.; Galhoum, A.A. (2017) Evaluation of adsorption behavior for U(VI) and Th(IV) ions onto solidified mannich type material. Journal of Dispersion Science and Technology, 38: 860.
   Web of Science ®Google Scholar
• Bayramoglu, G.; Arica, M.Y. (2016) MCM–41 silica particles grafted with polyacrylonitrile: Modification in to amidoxime and carboxyl groups for enhanced uranium removal from aqueous medium. Microporous and Mesoporous Materials, 226: 117–124. doi:10.1016/j.micromeso.2015.12.040.
   Web of Science ®Google Scholar
• Srivastava, S.; Bhainsa, K.C. (2016) Evaluation of uranium removal by Hydrillaverticillata (L.f.) Royle from low level nuclear waste under laboratory conditions. Journal of Environmental Management, 167: 124–129. doi:10.1016/j.jenvman.2015.11.018.
   PubMed Web of Science ®Google Scholar
• Li, F.; Li, D.; Li, X.; Liao, J.; Li, S.; Yang, J.; Yang, Y.; Tang, J.; Liu, N. (2016) Microorganism-derived carbon microspheres for uranium removal from aqueous solution. The Chemical Engineering Journal, 284: 630–639. doi:10.1016/j.cej.2015.09.015.
   Google Scholar
• Chipmen, N.A.;. (1996) Wai CM. Separation Techniques in Nuclear Waste Management. CRC Press: Boca Raton.
   Google Scholar
• Zhao, C.; Liu, J.; Li, X.; Li, F.; Tu, H.; Sun, Q.; Liao, J.; Yang, J.; Yang, Y.; Liu, N. (2016) Biosorption and bioaccumulation behavior of uranium on Bacillus sp. dwc–2: Investigation by Box–behenken design method. Journal of Molecular Liquids, 221: 156–165. doi:10.1016/j.molliq.2016.05.085.
   Web of Science ®Google Scholar
• Chen, C.; Wang, J. (2016) Uranium removal by novel graphene oxide–immobilized Saccharomyces cerevisiae gel beads. Journal of Environmental Radioactivity, 162–163: 134–145. doi:10.1016/j.jenvrad.2016.05.012.
   PubMed Web of Science ®Google Scholar
• Schulte–Herbruggen, H.M.A.; Semiäo, A.J.C.; Chaurand, P.; Graham, M.C. (2016) Effect of pH and pressure on uranium removal from drinking water using NF/RO membranes. Environmental Science & Technology, 50: 5817.
   PubMed Web of Science ®Google Scholar
• Gado, M.; Zaki, S. (2016) Studies on thorium adsorption characteristics upon activated titanium hydroxide prepared from rosetta ilmenite concentrate. International Journal of Waste Resources, 6: 1.
   Google Scholar
• Shao, L.; Wang, X.; Ren, Y.; Wang, S.; Zhong, J.; Chu, M.; Tang, H.; Luo, L.; Xie, D. (2016) Facile fabrication of magnetic cucurbit [6] uril/graphene oxide composite and application for uranium removal. The Chemical Engineering Journal, 286: 311. doi:10.1016/j.cej.2015.10.062.
   Google Scholar
• Alipour, D.; Keshtkar, A.R.; Moosavian, M.A. (2016) Adsorption of thorium(IV) from simulated radioactive solutions using a novel electrospun PVA/TiO2/ZnO nanofiber adsorbent functionalized with mercapto groups: Study in single and multi–component systems. Applied Surface Science, 366: 19–29. doi:10.1016/j.apsusc.2016.01.049.
   Web of Science ®Google Scholar
• Yuan, D.; Long, C.; Xin, X.; Yuan, L.; Liao, S.; Wang, Y. (2016) Removal of uranium (VI) from aqueous solution by amidoxime functionalized superparamagnetic polymer microspheres prepared by a controlled radical polymerization in the presence of DPE. The Chemical Engineering Journal, 285: 358–367. doi:10.1016/j.cej.2015.10.014.
   Google Scholar
• Srivastava, B.; Barman, M.K.; Chatterjee, M.; Roy, D.; Mandal, B. (2016) Solid phase extraction, separation and preconcentration of rare elements thorium(IV), uranium(VI), zirconium(IV), cerium(IV) and chromium(III) amid several other foreign ions with eriochrome black T anchored to 3–D networking silica gel. Journal of Chromatography A, 17: 1–14. doi:10.1016/j.chroma.2016.04.079.
   Web of Science ®Google Scholar
• Oyewo, O.A.; Onyango, M.S.; Wolkersdorfer, C. (2016) Application of banana peels nanosorbent for the removal of radioactive minerals from real mine water. Journal of Environmental Radioactivity, 164: 369.
   PubMed Web of Science ®Google Scholar
• Liu, W.; Zhao, X.; Wang, T.; Zhao, D.; Ni, J. (2016) Adsorption of U(VI) by multilayer titanate nanotubes: Effects of inorganic cations, carbonate and natural organic matter. The Chemical Engineering Journal, 286: 427–435. doi:10.1016/j.cej.2015.10.094.
   Google Scholar
• Mokhtari, M.; Keshtkar, A.R. (2016) Removal of Th(IV), Ni(II)and Fe(II) from aqueous solutions by a novel PAN–tiO2 nanofiber adsorbent modified with amino propyl triethoxysilane. Research on Chemical Intermediates, 42: 4055–4076. doi:10.1007/s11164-015-2258-0.
   Web of Science ®Google Scholar
• Crespi, J.; Quici, N.; Halac, E.B.; Leyva, A.G.; Ramos, C.P.; Mizrahi, M.; Requejo, F.G.; Litter, M. (2016) Removal of uranium (VI) with iron nanoparticles. Chemical Engineering Transactions, 47: 265.
   Google Scholar
• Qiao, W.J.; Zhai, S.R.; Zhang, F.; Xiao, Z.Y.; An, Q.D.; Song, X.W. (2014) Correlation between pore-expanding and dye adsorption of platelet C/SBA-15 prepared by carbonization and oxidation of P123-TMB/SBA-15 composites. Journal of Sol-Gel Science and Technology, 70 (3): 451–463. doi:10.1007/s10971-014-3305-9.
   Web of Science ®Google Scholar
• Qiao, W.J.; Wang, Z.Z.; Zhai, S.R.; Xiao, Z.Y.; Zhang, F.; An, Q.D. (2015) Oxygen-containing/amino groups bifunctionalized SBA-15 toward efficient removal of methylene blue: kinetics, isotherm and mechanism analysis. Journal of Sol-Gel Science and Technology, 76 (2): 320–331. doi:10.1007/s10971-015-3779-0.
   Web of Science ®Google Scholar
• Bruzzoniti, M.C.; Prelle, A.; Sarzanini, C.; Onida, B.; Fiorilli, S.; Garrone, E. (2017) Retention of heavy metal ions on SBA-15 mesoporous silica functionalised with carboxylic groups. Journal of Separation Science, 30: 2414. doi:10.1002/jssc.200700182.
   Web of Science ®Google Scholar
• Hulea, V.; Mureseanu, M.; Reiss, A.; Cioatera, N.; Trandafir, I. (2010) Mesoporous silica functionalized with 1–furoyl thiourea urea for Hg (II) adsorption from aqueous media. Journal of Hazardous Materials, 82: 197.
   Google Scholar
• Park Jeong, E.Y.; Ansari, M.B.; Mo, Y.H. (2011) Removal of Cu (II) from water by tetrakis (4–carboxyphenyl) porphyrin–functionalized mesoporous silica. Journal of Hazardous Materials, 185: 1311–1317. doi:10.1016/j.jhazmat.2010.10.047.
   PubMed Web of Science ®Google Scholar
• Silva, N.D.; Da’na, E.; Silva, N.D. (2011) Adsorption of copper on amine–functionalized SBA-15 prepared by co–condensation: kinetics properties. The Chemical Engineering Journal, 166: 454–459. doi:10.1016/j.cej.2010.11.017.
   Google Scholar
• Ren, Y.M.; Yang, R.; Shao, L.; Tang, H.; Wang, S.; Zhao, J.; Zhong, J.R.; Kong, C. (2016) Removal of aqueous uranium by SBA-15 modified with 2 phosphoramide: A combined experimental and DFT study. RSC Advances, 6: 68695–68704. doi:10.1039/C6RA12269H.
   Web of Science ®Google Scholar
• Ji, G.; Zhu, G.; Wang, X.; Wei, Y.; Yuan, J.; Gao, C. (2017) Preparation of amidoxime functionalized SBA-15 with platelet shape and adsorption property of U(VI). Separation and Purification Technology, 74: 455–465. doi:10.1016/j.seppur.2016.10.048.
   Web of Science ®Google Scholar
• Dolatyari, L.; Yaftian, M.R.; Rostamnia, S. (2016) Removal of uranium(VI) ions from aqueous solutions using Schiff base functionalized SBA-15 mesoporous silica materials. Journal of Environmental Management, 169: 8–17. doi:10.1016/j.jenvman.2015.12.005.
   PubMed Web of Science ®Google Scholar
• Dolatyari, L.; Yaftian, M.R.; Rostamnia, S. (2016) Adsorption characteristics of Eu(III) and Th(IV) ions onto modified mesoporous silica SBA-15 materials. Journal of the Taiwan Institute of Chemical Engineers, 60: 174–184. doi:10.1016/j.jtice.2015.11.004.
   Web of Science ®Google Scholar
• Hami Dindar, M.; Yaftian, M.R.; Hajihasani, M.; Rostamnia, S. (2016) Refinement of contaminated water by Cr(VI), As(V) and Hg(II) using N–donor ligands arranged on SBA-15 platform; batch and fixed–bed column methods. Journal of the Taiwan Institute of Chemical Engineers, 67: 325–337. doi:10.1016/j.jtice.2016.07.042.
   Web of Science ®Google Scholar
• Hami Dindar, M.; Yaftian, M.R.; Pilehvari, M.; Rostamnia, S. (2015) SBA-15 mesoporous materials decorated with organic ligands: Use as adsorbents for heavy metal ions. Journal of the Iranian Chemical Society, 12: 561–572. doi:10.1007/s13738-014-0513-8.
   Web of Science ®Google Scholar
• Hami Dindar, M.; Yaftian, M.R.; Rostamnia, S. (2015) Potential of functionalized SBA-15 mesoporous materials for decontamination of water solutions from Cr(VI), As(V) and Hg(II) ions. Journal of Environmental Chemical Engineering, 3: 986–995. doi:10.1016/j.jece.2015.03.006.
   Web of Science ®Google Scholar
• Marczenko, Z. (1976) Spectrophotometric Determination of Elements, Holsted Press – John Wiley & Sons: New York.
   Google Scholar
• Haleem Khan, M.; Warwick, P.; Evans, N. (2006) Spectrophotometric determination of uranium with arsenazo–III in perchloric acid. Chemosphere, 63: 1165–1169. doi:10.1016/j.chemosphere.2005.09.060.
   PubMed Web of Science ®Google Scholar
• Liu, Y.; Li, Q.; Cao, X.; Wang, Y.; Jiang, X.; Li, M.; Hua, M.; Zhang, Z. (2013) Removal of uranium(VI) from aqueous solutions by CMK–3 and its polymer composite. Applied Surface Science, 285: 258–266. doi:10.1016/j.apsusc.2013.08.048.
   Web of Science ®Google Scholar
• Dong, Y.; Liu, Z.; Li, Y. (2011) Effect of pH, ionic strength, foreign ions and humic substances on Th(IV) sorption to GMZ bentonite studied by batch experiments. The Journal of Radioanalytical and Nuclear Chemistry, 289: 257–265. doi:10.1007/s10967-011-1072-4.
   Web of Science ®Google Scholar
• Abbasizadeh, S.; Keshtkar, A.R.; Mousavian, M.A. (2013) Preparation of a novel electrospun polyvinyl alcohol/titanium oxide nanofiber adsorbent modified with mercapto groups for uranium(VI) and thorium(IV) removal from aqueous solution. The Chemical Engineering Journal, 220: 161–171. doi:10.1016/j.cej.2013.01.029.
   Google Scholar
• Foo, K.Y.; Hameed, B.H. (2010) Insights into the modeling of adsorption isotherm systems. The Chemical Engineering Journal, 156: 2–10. doi:10.1016/j.cej.2009.09.013.
   Google Scholar
• Zhang, X.; Zhu, G.; Guo, F. (2013) Removal of uranium (VI) ion from aqueous solution by SBA-15. Annals of Nuclear Energy, 56: 151–157. doi:10.1016/j.anucene.2013.01.041.
   Web of Science ®Google Scholar
• Ho, Y.S.; McKay, G. (2002) Application of kinetic models to the sorption of copper(II) on to peat. Adsorption Science & Technology, 20: 797–815. doi:10.1260/026361702321104282.
   Web of Science ®Google Scholar
• Da’na, E.; Silva, N.D.; Sayari, A. (2011) Adsorption of copper on amine–functionalized SBA-15 prepared by co–condensation: kinetics properties. The Chemical Engineering Journal, 166: 454–459. doi:10.1016/j.cej.2010.11.017.
   Google Scholar
• Belgacem, A.; Rebiai, R.; Hadoun, H.; Khemaissia, S.; Belmedani, M. (2013) The removal of uranium(VI) from aqueous solutions onto activated carbon developed from grinded used tire. In: Environmental Science and Pollution Research, 21: 684.
   PubMed Web of Science ®Google Scholar
• Zhang, Z.B.; Zhou, Y.D.; Liu, Y.H.; Cao, X.H.; Zhou, Z.W.; Han, B.; Liang, P.; Xiong, G.X. (2014) Removal of thorium from aqueous solution by ordered mesoporous carbon CMK–3. The Journal of Radioanalytical and Nuclear Chemistry, 302: 9–16. doi:10.1007/s10967-014-3304-x.
   Web of Science ®Google Scholar
• Yuan, L.Y.; Bai, Z.Q.; Zhao, R.; Liu, Y.L.; Li, Z.J.; Chu, S.Q.; Zheng, L.R.; Zhang, J.; Zhao, Y.L.; Chai, F.Z.; Shi, W.Q. (2014) Introduction of bifunctional groups into mesoporous silica for enhancing uptake of thorium(IV) from aqueous solution. Applied Materials & Interfaces, 6 (7): 4786–4796. doi:10.1021/am405584h.
   PubMed Web of Science ®Google Scholar
• Zuo, L.; Yu, S.; Zhou, H.; Tian, X.; Jiang, J. (2011) Th(IV) adsorption on mesoporous molecularsieves: Effects of contact time, solid content, pH, ionic strength, foreign ions and temperature. The Journal of Radioanalytical and Nuclear Chemistry, 288: 379–387. doi:10.1007/s10967-010-0930-9.
   Web of Science ®Google Scholar
• Gao, J.K.; Hou, L.A.; Zhang, G.H.; Gu, P. (2015) Facile functionalized of SBA-15 via a biomimetic coating and its application in efficient removal of uranium ions from aqueous solution. Journal of Hazardous Materials, 286: 325–333. doi:10.1016/j.jhazmat.2014.12.061.
   PubMed Web of Science ®Google Scholar
• Wang, Y.L.; Song, L.J.; Zhu, L.; Guo, B.L.; Chen, S.W.; Wu, W.S. (2014) Removal of uranium(VI) from aqueous solution using iminodiacetic acid derivative functionalized SBA-15 as adsorbents. Dalton Transactions, 43: 3739. doi:10.1039/c3dt52610k.
   PubMed Web of Science ®Google Scholar
• Lebed, P.J.; Savoie, J.D.; Florek, J.; Bilodeau, F.; Larivière, D.; Kleitz, F. (2012) Large pore mesostructured organosilica–phosphonate hybrids as highly efficient and regenerable sorbents for uranium sequestration. Chemistry of Materials, 24: 4166–4176. doi:10.1021/cm3023709.
   Web of Science ®Google Scholar
• Yuan, L.Y.; Liu, Y.L.; Shi, W.Q.; Li, Z.; Lan, J.H.; Feng, Y.X.; Zhao, Y.L.; Yuan, Y.L.; Chai, Z.F. (2012) A novel mesoporous material for uranium extraction, dihydroimidazole functionalized SBA-15. Journal of Materials Chemistry, 22: 17019. doi:10.1039/c2jm31766d.
   Web of Science ®Google Scholar