Liquid-liquid equilibrium of a ternary system of water+ ethanol+ benzene or furfural in a micro-extractor: experimental investigation and thermodynamic modeling

References

• Benz, K.; Jäckel, K. P.; Regenauer, K. J.; Schiewe, J.; Drese, K.; Ehrfeld, W.; … Löwe, H. Utilization of Micromixers for Extraction Processes. Chem. Eng. Technol. 2001, 24(1), 11–17. DOI: 10.1002/1521-4125(200101)24:1<11::AID-CEAT11>3.0.CO;2-Q.
   Web of Science ®Google Scholar
• Lee, J. Y.; Kumar, J. R.; Kim, J. S.; Park, H. K.; Yoon, H. S. Liquid–Liquid extraction/separation of Platinum (IV) and Rhodium (III) from Acidic Chloride Solutions Using Tri-iso-octylamine. J. Hazard. Mater. 2009, 168(1), 424–429. DOI: 10.1016/j.jhazmat.2009.02.056.
   PubMed Web of Science ®Google Scholar
• Okubo, Y.; Maki, T.; Aoki, N.; Khoo, T. H.; Ohmukai, Y.; Mae, K. Liquid–Liquid Extraction for Efficient Synthesis and Separation by Utilizing Micro Spaces. Chem. Eng. Sci. 2008, 63(16), 4070–4077. DOI: 10.1016/j.ces.2008.05.017.
   Web of Science ®Google Scholar
• Kikutani, Y.; Mawatari, K.; Hibara, A.; Kitamori, T. Circulation Microchannel for Liquid–Liquid Microextraction. Microchim. Acta. 2009, 164(3–4), 241. DOI: 10.1007/s00604-008-0065-7.
   Web of Science ®Google Scholar
• Chasanis, P.; Brass, M.; Kenig, E. Y. Investigation of Multicomponent Mass Transfer in Liquid–Liquid Extraction Systems at Microscale. Int. J. Heat Mass Transfer. 2010, 53(19–20), 3758–3763. DOI: 10.1016/j.ijheatmasstransfer.2010.04.026.
   Web of Science ®Google Scholar
• Jovanović, J.; Rebrov, E. V.; Nijhuis, T. A.; Kreutzer, M. T.; Hessel, V.; Schouten, J. C. Liquid–Liquid Flow in a Capillary Microreactor: Hydrodynamic Flow Patterns and Extraction Performance. Ind. Eng. Chem. Res. 2011, 51(2), 1015–1026. DOI: 10.1021/ie200715m.
   Web of Science ®Google Scholar
• Darekar, M.; Sen, N.; Singh, K. K.; Mukhopadhyay, S.; Shenoy, K. T.; Ghosh, S. K. Liquid–Liquid Extraction in Microchannels with Zinc–D2EHPA System. Hydrometallurgy. 2014, 144, 54–62. DOI: 10.1016/j.hydromet.2014.01.010.
   Web of Science ®Google Scholar
• Yin, S.; Zhang, L.; Peng, J.; Li, S.; Ju, S.; Zhang, L. Microfluidic Solvent Extraction of La (III) with 2-ethylhexyl Phosphoric Acid-2-ethylhexyl Ester (P507) by a Microreactor. Chem. Eng. Process. 2015, 91, 1–6. DOI: 10.1016/j.cep.2015.03.003.
   Web of Science ®Google Scholar
• Singh, K. K.; Renjith, A. U.; Shenoy, K. T. Liquid–Liquid Extraction in Microchannels and Conventional Stage-wise Extractors: A Comparative Study. Chem. Eng. Process. 2015, 98, 95–105. DOI: 10.1016/j.cep.2015.10.013.
   Web of Science ®Google Scholar
• John, J. J.; Kuhn, S.; Braeken, L.; Van Gerven, T. Ultrasound Assisted Liquid–Liquid Extraction in microchannels—A Direct Contact Method. Chem. Eng. Process. 2016, 102, 37–46. DOI: 10.1016/j.cep.2016.01.003.
   Web of Science ®Google Scholar
• Kurt, S. K.; Gürsel, I. V.; Hessel, V.; Nigam, K. D.; Kockmann, N. Liquid–Liquid Extraction System with Microstructured Coiled Flow Inverter and Other Capillary Setups for Single-stage Extraction Applications. Chem. Eng. J. 2016, 284, 764–777. DOI: 10.1016/j.cej.2015.08.099.
   Web of Science ®Google Scholar
• Su, Y.; Zhao, Y.; Chen, G.; Yuan, Q. Liquid–Liquid Two-phase Flow and Mass Transfer Characteristics in Packed Microchannels. Chem. Eng. Sci. 2010, 65(13), 3947–3956. DOI: 10.1016/j.ces.2010.03.034.
   Web of Science ®Google Scholar
• Sato, K.; Tokeshi, M.; Sawada, T.; Kitamori, T. Molecular Transport between Two Phases in a Microchannel. Anal. Sci. 2000, 16(5), 455–456. DOI: 10.2116/analsci.16.455.
   Web of Science ®Google Scholar
• Okubo, Y.; Toma, M.; Ueda, H.; Maki, T.; Mae, K. Microchannel Devices for the Coalescence of Dispersed Droplets Produced for Use in Rapid Extraction Processes. Chem. Eng. J. 2004, 101(1–3), 39–48. DOI: 10.1016/j.cej.2003.10.025.
   Web of Science ®Google Scholar
• Hotokezaka, H.; Tokeshi, M.; Harada, M.; Kitamori, T.; Ikeda, Y. Development of the Innovative Nuclide Separation System for High-level Radioactive Waste Using Microchannel Chip-extraction Behavior of Metal Ions from Aqueous Phase to Organic Phase in Microchannel. Prog. Nucl. Energy. 2005, 47, 439–447. DOI: 10.1016/j.pnucene.2005.05.045.
   Web of Science ®Google Scholar
• Zhao, Y.; Chen, G.; Yuan, Q. Liquid‐liquid Two‐phase Flow Patterns in a Rectangular Microchannel. AIChE J. 2006, 52(12), 4052–4060. DOI: 10.1002/(ISSN)1547-5905.
   Web of Science ®Google Scholar
• Zhao, Y.; Chen, G.; Yuan, Q. Liquid–Liquid Two‐phase Mass Transfer in the T‐junction Microchannels. AIChE J. 2007, 53(12), 3042–3053. DOI: 10.1002/(ISSN)1547-5905.
   Web of Science ®Google Scholar
• Zhao, Y.; Su, Y.; Chen, G.; Yuan, Q. Effect of Surface Properties on the Flow Characteristics and Mass Transfer Performance in Microchannels. Chem. Eng. Sci. 2010, 65(5), 1563–1570. DOI: 10.1016/j.ces.2009.10.027.
   Web of Science ®Google Scholar
• Su, Y.; Chen, G.; Zhao, Y.; Yuan, Q. Intensification of Liquid–Liquid Two‐phase Mass Transfer by Gas Agitation in a Microchannel. AIChE J. 2009, 55(8), 1948–1958. DOI: 10.1002/aic.v55:8.
   Web of Science ®Google Scholar
• Rajesh, V. M.; Buwa, V. V. Experimental Characterization of Gas–Liquid–Liquid Flows in T-junction Microchannels. Chem. Eng. J. 2012, 207, 832–844. DOI: 10.1016/j.cej.2012.07.082.
   Web of Science ®Google Scholar
• Xu, B.; Cai, W.; Liu, X.; Zhang, X. Mass Transfer Behavior of Liquid–Liquid Slug Flow in Circular Cross-section Microchannel. Chemical Engineering Research and Design. 2013, 91(7), 1203–1211. DOI: 10.1016/j.cherd.2013.01.014.
   Web of Science ®Google Scholar
• Raimondi, N. D. M.; Prat, L.; Gourdon, C.; Tasselli, J. Experiments of Mass Transfer with Liquid–Liquid Slug Flow in Square Microchannels. Chem. Eng. Sci. 2014, 105, 169–178. DOI: 10.1016/j.ces.2013.11.009.
   Web of Science ®Google Scholar
• Liu, G.; Wang, K.; Lu, Y.; Luo, G. Liquid–Liquid Microflows and Mass Transfer Performance in Slit-like Microchannels. Chem. Eng. J. 2014, 258, 34–42. DOI: 10.1016/j.cej.2014.07.035.
   Web of Science ®Google Scholar
• Sen, N.; Darekar, M.; Singh, K. K.; Mukhopadhyay, S.; Shenoy, K. T.; Ghosh, S. K. Solvent Extraction and Stripping Studies in Microchannels with TBP Nitric Acid System. Solvent Extr. Ion Exch. 2014, 32(3), 281–300. DOI: 10.1080/07366299.2013.850290.
   Web of Science ®Google Scholar
• Chapeaux, A.; Simoni, L. D.; Ronan, T. S.; Stadtherr, M. A.; Brennecke, J. F. Extraction of Alcohols from Water with 1-hexyl-3-methylimidazolium Bis (Trifluoromethylsulfonyl) Imide. Green Chem. 2008, 10(12), 1301–1306. DOI: 10.1039/b807675h.
   Web of Science ®Google Scholar
• Neves, C. M.; Granjo, J. F.; Freire, M. G.; Robertson, A.; Oliveira, N. M.; Coutinho, J. A. Separation of Ethanol–Water Mixtures by Liquid–Liquid Extraction Using Phosphonium-based Ionic Liquids. Green Chem. 2011, 13(6), 1517–1526. DOI: 10.1039/c1gc15079k.
   Web of Science ®Google Scholar
• Renon, H.; Prausnitz, J. M. Local Compositions in Thermodynamic Excess Functions for Liquid Mixtures. AIChE J. 1968, 14(1), 135–144. DOI: 10.1002/(ISSN)1547-5905.
   Web of Science ®Google Scholar
• Abrams, D. S.; Prausnitz, J. M. Statistical Thermodynamics of Liquid Mixtures: A New Expression for the Excess Gibbs Energy of Partly or Completely Miscible Systems. AIChE J. 1975, 21(1), 116–128. DOI: 10.1002/(ISSN)1547-5905.
   Web of Science ®Google Scholar
• Othmer, D.; Tobias, P. Liquid-liquid Extraction Data-the Line Correlation. Ind. Eng. Chem. 1942, 34(6), 693–696. DOI: 10.1021/ie50390a600.
   Google Scholar
• Hand, D. B.;. Dineric Distribution. J. Phys. Chem. 1930, 34(9), 1961–2000. DOI: 10.1021/j150315a009.
   Google Scholar
• Gokel, G. W. 2004. Dean’s handbook of organic chemistry.
   Google Scholar
• Rivelino, R.; Canuto, S.; Coutinho, K. Conformational Stability of Furfural in Aqueous Solution: The Role of Hydrogen Bonding. Braz. J. phys. 2004, 34(1), 84–89. DOI: 10.1590/S0103-97332004000100012.
   Web of Science ®Google Scholar
• Brandani, V.; Chianese, A.; Rossi, M. Ternary Liquid-liquid Equilibrium Data for the Water-ethanol-benzene System. J. Chem. Eng. Data. 1985, 30(1), 27–29. DOI: 10.1021/je00039a009.
   Web of Science ®Google Scholar
• Habaki, H.; Hu, H.; Egashira, R. Liquid–Liquid Equilibrium Extraction of Ethanol with Mixed Solvent for Bioethanol Concentration. Chin. J. Chem. Eng. 2016, 24(2), 253–258. DOI: 10.1016/j.cjche.2015.07.022.
   Web of Science ®Google Scholar