Misinterpretation of Dubinin–Radushkevich isotherm and its implications on adsorption parameter estimates

References

• Srivastava, A.; Gupta, B.; Majumder, A.; Gupta, A. K.; Nimbhorkar, S. K. A Comprehensive Review on the Synthesis, Performance, Modifications, and Regeneration of Activated Carbon for the Adsorptive Removal of Various Water Pollutants. J. Environ. Chem. Eng. 2021, 9, 106177. DOI: 10.1016/j.jece.2021.106177.
   Web of Science ®Google Scholar
• Saxena, R.; Saxena, M.; Lochab, A. Recent Progress in Nanomaterials for Adsorptive Removal of Organic Contaminants from Wastewater. ChemistrySelect. 2020, 5, 335–353. DOI: 10.1002/slct.201903542.
   Web of Science ®Google Scholar
• Jayakumar, V.; Govindaradjane, S.; Rajasimman, M. Efficient Adsorptive Removal of Zinc by Green Marine Macro Alga Caulerpa Scalpelliformis –Characterization, Optimization, Modeling, Isotherm, Kinetic, Thermodynamic, Desorption and Regeneration Studies. Surf. Interfaces. 2021, 22, 100798. DOI: 10.1016/j.surfin.2020.100798.
   Web of Science ®Google Scholar
• Ayawei, N.; Ebelegi, A. N.; Wankasi, D. Modelling and Interpretation of Adsorption Isotherms. J. Chem. 2017, 2017, 1–11. DOI: 10.1155/2017/3039817.
   Web of Science ®Google Scholar
• Chen, S. G.; Yang, R. T. Theoretical Basis for the Potential Theory Adsorption Isotherms. The Dubinin-Radushkevich and Dubinin-Astakhov Equations. Langmuir. 1994, 10, 4244–4249. DOI: 10.1021/la00023a054.
   Web of Science ®Google Scholar
• Itodo, A. U.; Itodo, H. U. Sorption Energies Estimation Using Dubinin-Radushkevich and Temkin Adsorption Isotherms. Life Sci. J. 2010, 7, 31–39.
   Web of Science ®Google Scholar
• Inyinbor, A. A.; Adekola, F. A.; Olatunji, G. A. Kinetics, Isotherms and Thermodynamic Modeling of Liquid Phase Adsorption of Rhodamine B Dye Onto Raphia Hookerie Fruit Epicarp. Water Resour. Ind. 2016, 15, 14–27. DOI: 10.1016/j.wri.2016.06.001.
   Web of Science ®Google Scholar
• Hu, Q.; Zhang, Z. Application of Dubinin–Radushkevich Isotherm Model at the Solid/Solution Interface: A Theoretical Analysis. J. Mol. Liq. 2019, 277, 646–648. DOI: 10.1016/j.molliq.2019.01.005.
   Web of Science ®Google Scholar
• Nishikawa, E.; da Silva, M. G. C.; Vieira, M. G. A. Cadmium Biosorption by Alginate Extraction Waste and Process Overview in Life Cycle Assessment Context. J. Clean. Prod. 2018, 178, 166–175. DOI: 10.1016/j.jclepro.2018.01.025.
   Web of Science ®Google Scholar
• Geszke-Moritz, M.; Moritz, M. Modeling of Boldine Alkaloid Adsorption Onto Pure and Propyl-Sulfonic Acid-Modified Mesoporous Silicas. A Comparative Study. Mater. Sci. Eng. C. 2016, 69, 815–830. DOI: 10.1016/j.msec.2016.07.055.
   PubMed Web of Science ®Google Scholar
• Inglezakis, V. J. Solubility-Normalized Dubinin–Astakhov Adsorption Isotherm for Ion-Exchange Systems. Microporous. Mesoporous. Mater. 2007, 103, 72–81. DOI: 10.1016/j.micromeso.2007.01.039.
   Web of Science ®Google Scholar
• Lo, H. M.; Lin, K. C.; Liu, M. H.; Pai, T. Z.; Lin, C. Y.; Liu, W. F.; Fang, G. C.; Lu, C.; Chiang, C. F.; Wang, S. C., et al. Solubility of Heavy Metals Added to MSW. J. Hazard. Mater. 2009, 161, 294–299. DOI: 10.1016/j.jhazmat.2008.03.119.
   PubMed Web of Science ®Google Scholar
• Ratkova, E. L.; Abramov, Y. A.; Baskin, I. I.; Livingstone, D. J.; Fedorov, M. V.; Withnall, M.; Tetko, I. V. Comprehensive Medicinal Chemistry III, Volume 3: “IN SILICO DRUG DISCOVERY TOOLS”, Chapter title: Empirical and Physics-Based Calculations of Physical–Chemical Properties. Elsevier. 2017, 393–428. DOI: 10.1016/B978-0-12-409547-2.12341-8.
   Google Scholar
• Ran, Y.; Jain, N.; Yalkowsky, S. H. Prediction of Aqueous Solubility of Organic Compounds by the General Solubility Equation (GSE). J. Chem. Inf. Comput. Sci. 2001, 41, 1208–1217. DOI: 10.1021/ci010287z.
   PubMedGoogle Scholar
• Klopman, G.; Zhu, H. Estimation of the Aqueous Solubility of Organic Molecules by the Group Contribution Approach. J. Chem. Inf. Comput. Sci. 2001, 41, 439–445. DOI: 10.1021/ci000152d.
   PubMedGoogle Scholar
• Meftahi, N.; Walker, M. L.; Smith, B. J. Predicting Aqueous Solubility by QSPR Modeling. J. Mol. Graph. Modell. 2021, 106, 107901. DOI: 10.1016/j.jmgm.2021.107901.
   PubMed Web of Science ®Google Scholar
• Nematollahzadeh, A.; Babapoor, A.; Mousavi, S. M.; Nuri, A. Nitrobenzene Adsorption from Aqueous Solution Onto Polythiophene-Modified Magnetite Nanoparticles. Mater. Chem. Phys. 2021, 262, 124266. DOI: 10.1016/j.matchemphys.2021.124266.
   Web of Science ®Google Scholar
• Liu, Q.; Zang, G. -L.; Zhao, Q. Removal of Copper Ions by Functionalized Biochar Based on a Multicomponent Ugi Reaction. R.S.C. Adv. 2021, 11, 25880–25891. DOI: 10.1039/D1RA04156H.
   PubMed Web of Science ®Google Scholar
• Tang, Y.; Liao, X.; Zhang, X.; Peng, G.; Gao, J.; Chen, L. Enhanced Adsorption of Hexavalent Chromium and the Microbial Effect on Quartz Sand Modified with Al-Layered Double Hydroxides. Sci. Total Environ. 2021, 762, 143094. DOI: 10.1016/j.scitotenv.2020.143094.
   PubMed Web of Science ®Google Scholar
• Paluri, P.; Ahmad, K. A.; Durbha, K. S. Importance of Estimation of Optimum Isotherm Model Parameters for Adsorption of Methylene Blue Onto Biomass Derived Activated Carbons: Comparison Between Linear and Non-Linear Methods. Biomass Convers. Biorefinery. 2020, 12, 4031–4048. DOI: 10.1007/s13399-020-00867-y.
   Web of Science ®Google Scholar
• Jakobek, L.; Matić, P.; Kraljević, Š.; Ukić, Š.; Benšić, M.; Barron, A. R. Adsorption Between Quercetin Derivatives and β-Glucan Studied with a Novel Approach to Modeling Adsorption Isotherms. Appl. Sci. 2020, 10, 1637. DOI: 10.3390/app10051637.
   Google Scholar
• Osmari, T. A.; Gallon, R.; Schwaab, M.; Barbosa-Coutinho, E.; Severo, J. B.; Pinto, J. C. Statistical Analysis of Linear and Non-Linear Regression for the Estimation of Adsorption Isotherm Parameters. Adsorpt. Sci. Technol. 2013, 31, 433–458. DOI: 10.1260/0263-6174.31.5.433.
   Web of Science ®Google Scholar
• Chu, K. H.; Hashim, M. A. Protein Adsorption on Ion Exchange Resin: Estimation of Equilibrium Isotherm Parameters from Batch Kinetic Data. Biotechnol. Bioprocess Eng. 2006, 11, 61–66. DOI: 10.1007/BF02931870.
   Web of Science ®Google Scholar