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Articles

Improved mechanical properties of ATBN-toughened epoxy networks by controlling the phase separation scale

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Pages 642-652 | Received 25 Jul 2015, Accepted 29 Oct 2015, Published online: 30 Nov 2015

References

  • Williams RJJ, Rozenberg BA, Pascault JP. Reaction-induced phase separation in modified thermosetting polymers. Adv. Polym. Sci. 1997;128:95–156.10.1007/3-540-61218-1
  • Vale’ria DR, Helson MDC, Vera LPS. Modification of epoxy resin: a comparison of different types of elastomer. Polym. Test. 2005;24:387–394.
  • Takahiro O, Masahiko K, Hideaki H, et al. Effect of modified silicone elastomer particles on the toughening of epoxy resin. J. Adhes. Sci. Technol. 1998;12:813–830.
  • Bagheri R, Marouf BT, Pearson RA. Rubber-toughened epoxies: a critical review. Polym. Rev. 2009;49:201–225.10.1080/15583720903048227
  • Thomas R, Abraham J, Thomas S, et al. Influence of carboxyl-terminated (butadiene-co-acrylonitrile) loading on the mechanical and thermal properties of cured epoxy blends. J. Polym. Sci., Part B: Polym. Phys. 2004;42:2531–2544.10.1002/(ISSN)1099-0488
  • Raju T, Ding YM, He YL. Miscibility, morphology, thermal, and mechanical properties of a DGEBA based epoxy resin toughened with a liquid rubber. Polymer. 2008;49:278–304.
  • Farajpour T, Bayat Y, Keshavarz M, et al. Viscoelastic and thermal properties of polysulfide modified epoxy resin: the effect of modifier molecular weight. Materwiss. Werkstofftech. 2013;44:991–996.10.1002/mawe.v44.12
  • Ratna D, Banthia AK. Toughened epoxy adhesive modified with acrylate based liquid rubber. Polym. Int. 2000;49:281–287.10.1002/(ISSN)1097-0126
  • Sobhani S, Jannesari A, Bastani S. Effect of molecular weight and content of PDMS on morphology and properties of silicone-modified epoxy resin. J. Appl. Polym. Sci. 2012;123:162–178.10.1002/app.34435
  • Garima T, Deepak S. Effect of carboxyl-terminated poly(butadiene-co-acrylonitrile) (CTBN) concentration on thermal and mechanical properties of binary blends of diglycidyl ether of bisphenol-A (DGEBA) epoxy resin. Mater. Sci. Eng. A Struct. Mater. 2007;443:262–269.
  • Raju T, Ding YM, He YL. Miscibility, morphology, thermal, and mechanical properties of a DGEBA based epoxy resin toughened with a liquid rubber. Polymer. 2008;49:278–304.
  • Chikhi N, Fellahi S, Bakar M. Modification of epoxy resin using reactive liquid (ATBN) rubber. Eur. Polym. J. 2002;38:251–264.10.1016/S0014-3057(01)00194-X
  • Wang HH, Chen JC. Modification and compatibility of epoxy resin with hydroxyl -terminated or amine-terminated polyurethanes. Polym. Eng. Sci. 1995;35:1468–1475.10.1002/(ISSN)1548-2634
  • Chen SB, Wang QH, Wang TM. Hydroxy-terminated liquid nitrile rubber modified castor oil based polyurethane/epoxy IPN composites: damping, thermal and mechanical properties. Polym. Test. 2011;30:726–731.10.1016/j.polymertesting.2011.06.011
  • Verchere D, Pascault JP, Sautereau H, et al. Rubber-modified epoxies. IV. Influence of morphology on mechanical properties. J. Appl. Polym. Sci. 1991;43:293–304.10.1002/app.1991.070430208
  • Klug JH, Seferis JC. Phase separation influence on the performance of CTBN-toughened epoxy adhesives. Polym. Eng. Sci. 1999;39:1837–1848.10.1002/(ISSN)1548-2634
  • Chen TK, Jan YH. Fracture mechanism of toughened epoxy resin with bimodal rubber-particle size distribution. J. Mater. Sci. 1992;27:111–121.10.1007/BF02403652
  • Mathew VS, George SC, Parameswaranpillai J, et al. Epoxidized natural rubber/epoxy blends: phase morphology and thermomechanical properties. J. Appl. Polym. Sci. 2014;131:1–9.
  • Chen D, Pascault JP, Sautereau H, et al. Rubber-modified epoxies: III. Influence of the rubber molecular weight on the phase separation process. Polym. Int. 1994;33:253–261.10.1002/(ISSN)1097-0126
  • Ratna D. Phase separation in liquid rubber modified epoxy mixture. Relationship between curing conditions, morphology and ultimate behavior. Polymer. 2001;42:4209–4218.10.1016/S0032-3861(00)00798-9
  • He D, Ding XD, Chang PS, et al. Effect of annealing on phase separation and mechanical properties of epoxy/ATBN adhesive. Int. J. Adhes. Adhes. 2012;38:11–16.10.1016/j.ijadhadh.2012.04.006
  • Kozii VV, Rozenberg BA. Mechanisms of energy dissipation in elastomer-modified thermosetting polymer matrics and composites based on such polymers. Polym. Sci. 1992;34:919–951.
  • Frigione ME, Mascia L, Acierno D. Oligomeric and polymeric modifiers for toughening of epoxy resins. Eur. Polym. J. 1995;31:1021–1029.10.1016/0014-3057(95)00091-7
  • Frounchi M, Mehrabzadeh M, Parvary M. Toughening epoxy resins with solid acrylonitrile–butadiene rubber. Polym. Int. 2000;49:163–169.10.1002/(ISSN)1097-0126

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