Publication Cover
Ozone: Science & Engineering
The Journal of the International Ozone Association
Volume 29, 2007 - Issue 2
157
Views
9
CrossRef citations to date
0
Altmetric
Original Articles

A Multi-Channel Stopped-Flow Reactor for Measuring Ozone Decay Rate: Instrument Development and Application

, &
Pages 121-129 | Received 07 Apr 2006, Accepted 12 Sep 2006, Published online: 17 Apr 2007

REFERENCES

  • American Public Health Association (APHA), American Water Works Association (AWWA), and Water Environment Federation (WEF) . 1998 . Standard Methods for the Examination of Water and Wastewater , 20th , Washington, DC : American Public Health Association .
  • Bader , H. and Hoigné , J. 1981 . Determination of Ozone in Water by the Indigo Method . Water Research , 15 ( 4 ) : 449 – 456 .
  • Bahnemann , D. and Hart , E.J. 1982 . Rate Constants of the Reaction of the Hydrated Electron and Hydroxyl Radical with Ozone in Aqueous-Solution . Journal of Physical Chemistry , 86 ( 2 ) : 252 – 255 .
  • Bühler , R.E. , Staehelin , J. and Hoigné , J. 1984 . Ozone Decomposition in Water Studied by Pulse-Radiolysis.1. HO2/O2 − and HO3/O3 − as Intermediates . Journal of Physical Chemistry , 88 ( 12 ) : 2560 – 2564 .
  • Burguera , J.L. 1989 . Flow Injection Atomic Spectroscopy , New York, NY : Marcel Dekker, Inc. .
  • Buxton , G.V. and Elliot , A.J. 1986 . Rate Constant for Reactions of Hydroxyl Radicals with Bicarbonate Ions . Radiation Physics and Chemistry , 27 : 241 – 243 .
  • Buxton , G.V. , Greenstock , C.L. , Helman , W.P. and Ross , A.B. 1988 . Critical Review of Rate Constants for Reactions of Hydrated Electrons, Hydrogen Atoms, and Hydroxyl Radicals in Aqueous Solution . Journal of Physical and Chemical Reference Data , 17 ( 2 ) : 513 – 886 .
  • Chiou , C.F. , Mariñas , B.J. and Adams , J.Q. 1995 . Modified Indigo Method for Gaseous and Aqueous Ozone Analysis . Ozone: Science and Engineering , 17 ( 3 ) : 329 – 344 .
  • Cho , M. , Kim , H. , Cho , S. H. and Yoon , J. 2003 . Investigation of Ozone Reaction in River Waters Causing Instantaneous Ozone Demand . Ozone: Science & Engineering , 25 ( 4 ) : 251 – 259 .
  • Christensen , H. , Sehested , K. and Corfitzen , H. 1982 . Reactions of Hydroxyl Radicals with Hydrogen Peroxide at Ambient and Elevated Temperatures . Journal of Physical Chemistry , 86 ( 9 ) : 1588 – 1590 .
  • Czapski , G. , Lymar , S.V. and Schwarz , H.A. 1999 . Acidity of Carbonate Radical . Journal of Physical Chemistry , 103 ( 18 ) : 3447 – 3450 .
  • Elovitz , M.S. and von Gunten , U. 1999 . Hydroxyl Radical Ozone Ratios During Ozonation Processes. I-The R-ct Concept . Ozone: Science & Engineering , 21 ( 3 ) : 239 – 260 .
  • Forni , L. , Bahnemann , D. and Hart , E.J. 1982 . Mechanism of the Hydroxide Ion Initiated Decomposition of Ozone in Aqueous-Solution . Journal of Physical Chemistry , 86 ( 2 ) : 255 – 259 .
  • Hoigné , J. and Bader , H. 1983a . Rate Constants of Reactions of Ozone with Organic and Inorganic-Compounds in Water. 1. Non-Dissociating Organic-Compounds . Water Research , 17 ( 2 ) : 173 – 183 .
  • Hoigné , J. and Bader , H. 1983b . Rate Constants of Reactions of Ozone with Organic and Inorganic-Compounds in Water. 2. Dissociating Organic-Compounds . Water Research , 17 ( 2 ) : 185 – 194 .
  • Hoigné , J. , Bader , H. , Haag , W. R. and Staehelin , J. 1985 . Rate Constants of Reactions of Ozone with Organic and Inorganic-Compounds in Water.3. Inorganic-Compounds and Radicals . Water Research , 19 ( 8 ) : 993 – 1004 .
  • Hungerford , J.M. , Christian , G.D. , Ruzicka , J. and Giddings , J.C. 1985 . Reaction-Rate Measurement by Flow-Injection Analysis Using the Gradient Stopped-Flow Method . Analytical Chemistry , 57 ( 9 ) : 1794 – 1798 .
  • Hunt , N.K. and Mariñas , B.J. 1997 . Kinetics of Escherichia coli inactivation with ozone . Water Research , 31 ( 6 ) : 1355 – 1362 .
  • Kim , D. , Tang , G. , Hasan , S. , Mariñas , B.J. , Couillard , L. , Shukairy , H.M. and Kim , J.H. 2006 . Simultaneous Simulation of Pathogen Inactivation and Bromate Formation in Full-Scale Ozone Contactors . Journal American Water Works Association , submitted
  • Kim , J.H. , Rennecker , J.L. , Tomiak , R.B. , Mariñas , B.J. , Miltner , R.J. and Owens , J.H. 2002a . Inactivation of Cryptosporidium Oocysts in a Pilot-Scale Ozone Bubble-Diffuser Contactor. II: Model Validation and Application . ASCE Journal of Environmental Engineering , 128 ( 6 ) : 522 – 532 .
  • Kim , J.H. , Tomiak , R.B. and Mariñas , B.J. 2002b . Inactivation of Cryptosporidium Oocysts in a Pilot-Scale Ozone Bubble-Diffuser Contactor. I: Model Development . ASCE Journal of Environmental Engineering , 128 ( 6 ) : 514 – 521 .
  • Kim , J.H. , von Gunten , U. and Mariñas , B.J. 2004 . Modeling Bromate Formation and Cryptosporidium parvum Inactivation in Synthetic Waters . Environmental Science and Technology , 38 : 2232 – 2241 .
  • Langlais , B. , Reckhow , D.A. and Brink , D.R. 1991 . Ozone in Water Treatment: Application and Engineering , Chelsea, MI : American Water Works Association Research Foundation, Denver, Colorado, and Lewis Publishers .
  • Nemes , A. , Fabian , I. and van Eldik , R. 2000 . Kinetics and Mechanism of the Carbonate Ion Inhibited Aqueous Ozone Decomposition . Journal of Physical Chemistry A , 104 ( 34 ) : 7995 – 8000 .
  • Onari , Y. 1988 . Determination of Ozone Decomposition Rate by Flow-Injection Technique . Analytical Sciences , 4 ( 6 ) : 645 – 648 .
  • Park , H.S. , Hwang , T.M. , Kang , J.W. , Choi , H. and Oh , H.J. 2001 . Characterization of Raw Water for the Ozone Application Measuring Ozone Consumption Rate . Water Research , 35 ( 14 ) : 3515 – 3515 .
  • Park , J.S. , Choi , H. and Cho , J. 2004 . Kinetic Decomposition of Ozone and para-Chlorobenzoic Acid (pCBA) during Catalytic Ozonation . Water Research , 38 ( 9 ) : 2285 – 2292 .
  • Rakness , K.L. , Najam , I. , Elovitz , M. , Rexing , D. and Via , S. 2005 . Cryptosporidium Log-Inactivation with Ozone Using Effluent CT10, Geometric Mean CT10, Extended Integrated CT10 and Extended CSTR Calculations . Ozone: Science and Engineering , 27 : 335 – 350 .
  • Růźička , J. 1988 . Flow Injection Analysis , 2nd , New York : John Wiley & Sons .
  • Sehested , K. , Holcman , J. , Bjergbakke , E. and Hart , E.J. 1984 . A Pulse Radiolytic Study of the Reaction OH + O3 in Aqueous Medium . Journal of Physical Chemistry , 88 ( 18 ) : 4144 – 4147 . Additions and Corrections (1985), 89(2):388.
  • Sehested , K. , Holcman , J. and Hart , E.J. 1983 . Rate Constants and Products of the Reactions of eaq-, O2 −, and H with Ozone in Aqueous Solution . Journal of Physical Chemistry , 87 ( 11 ) : 1951 – 1954 .
  • Staehelin , J. , Bühler , R.E. and Hoigné , J. 1984 . Ozone Decomposition in Water Studied by Pulse-Radiolysis.2. OH and HO4 as Chain Intermediates . Journal of Physical Chemistry , 88 ( 24 ) : 5999 – 6004 .
  • Staehelin , J. and Hoigné , J. 1982 . Decomposition of Ozone in Water - Rate of Initiation by Hydroxide Ions and Hydrogen-Peroxide . Environmental Science & Technology , 16 ( 10 ) : 676 – 681 .
  • Straka , M.R. , Gordon , G. and Pacey , G.E. 1985 . Residual Aqueous Ozone Determination by Gas-Diffusion Flow-Injection Analysis . Analytical Chemistry , 57 ( 9 ) : 1799 – 1803 .
  • Straka , M.R. , Pacey , G.E. and Gordon , G. 1984 . Residual Ozone Determination by Flow-Injection Analysis . Analytical Chemistry , 56 ( 11 ) : 1973 – 1975 .
  • Tang , G. , Adu-Sarkodie , K. , Kim , D. , Kim , J.H. , Teefy , S. , Shukairy , H.M. and Mariñas , B.J. 2005 . Modeling Cryptosporidium parvum Oocyst Inactivation and Bromate Formation in a Full-Scale Ozone Contactor . Environmental Science and Technology , 39 : 9343 – 9350 .
  • Tomiyasu , H. and Gordon , G. 1984 . Colorimetric Determination of Ozone in Water Based on Reaction with Bis(Terpyridine)Iron(Ii) . Analytical Chemistry , 56 ( 4 ) : 752 – 754 .
  • United States Environmental Protection Agency (USEPA) . 2006a . National Primary Drinking Water Regulations: Long Term 2 Enhanced Surface Water Treatment Rule , 71 ( 3 ) : 654 Final Rule, Federal Register,
  • United States Environmental Protection Agency (USEPA) . 2006b . National Primary Drinking Water Regulations: Stage 2 Disinfectants and Disinfection Byproducts Rule , 71 ( 2 ) : 388 Final Rule, Federal Register,
  • von Gunten , U. and Hoigné , J. 1994 . Bromate Formation During Ozonation of Bromide-Containing Waters - Interaction of Ozone and Hydroxyl Radical Reactions . Environmental Science & Technology , 28 ( 7 ) : 1234 – 1242 .
  • Westerhoff , P. , Song , R. , Amy , G. and Minear , R. 1997 . Applications of Ozone Decomposition Models . Ozone: Science & Engineering , 19 ( 1 ) : 55 – 73 .
  • Zhou , H. , Smith , D.W. and Stanley , S.J. 1994 . Modeling of Dissolved Ozone Concentration Profiles in Bubble Columns . ASCE Journal of Environmental Engineering , 120 ( 4 ) : 821 – 839 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.