References
- Schäffer , C. E. and J⊘rgensen , C. K. 1965 . Mol. Phys. , 9 : 401
- Yamatera , H. 1958 . Bull. Chem. Soc. Jpn. , 31 : 95
- McClure , D. S. 1961 . Proc. VI ICCC , 498 New York : McMillan .
- Vanquickenborne , L. G. and Verdonck , E. 1976 . Inorg. Chem. , 15 : 454
- 1977 . ibid , 23 : 67 for a discussion of charge transfer spectra from a ligand field point of view.
- Kirk , A. D. 1973 . Mol. Photochem. , 5 : 127
- Strauss , D. and Ford , P. C. 1977 . J. Chem. Soc. Chem. Commun. , 1977 : 194
- Vanquickenborne , L. G. and Ceulemans , A. 1981 . Advances in Solution Chemistry , 91 New York : Plenum .
- Actually, the available empirical evidence does not enable one to make an unambiguous choice between an associative and a dissociative mechanism. For d6 systems, however, the evidence in favor of a dissociative mechanism is definitely more convincing.9 Moreover, both for d3 and d6 complexes, it can be shown that an associative reaction mechanism does not lead to electronic selection rules.10
- Ford , P. C. Coord. Chem. Rev. , in press.
- Vanquickenhome , L. G. and Ceulemans , A. Coord. Chem. Rev. , submitted for publication.
- Riccieri , P. and Zinato , E. 1980 . Inorg. Chem. , 19 : 853, 3279
- Kirk , A. D. and Frederick , L. A. 1981 . Inorg. Chem. , 20 : 60
- Zinato , E. , Riccieri , P. and Prelati , M. 1981 . Inorg. Chem. , 20 : 1432
- The predominant photoactive state is not the lowest excited doublet state; see a discussion of this point in Refs. 15 and 16.
- Adamson , A. W. and Fleischauer , P. D. 1975 . Concepts of Inorganic Photochemistry , New York : Wiley .
- Adamson , A. W. 1981 . Comments Inorg. Chem. , 1 : 33
- Vanquickenborne , L. G. and Ceulemans , A. 1978 . J. Am. Chem. Soc. , 100 : 475
- Vanquickenborne , L. G. and Ceulemans , A. 1978 . Inorg. Chem. , 17 : 2730
- Vanquickenborne , L. G. and Cedemans , A. 1979 . Inorg. Chem. , 18 : 3475
- Viaene , L. , D'Olieslager , J. , Ceulemans , A. and Vanquickenborne , L. G. 1979 . J. Am. Chem. Soc. , 101 : 1405
- Vanquickenborne , L. G. and Pierloot , K. 1981 . Inorg. Chem. , 20 : 3673
- Johnson , S. A. , Basolo , F. and Pearson , R. G. 1963 . J. Am. Chem. Soc. , 85 : 1741
- Bauer , R. A. and Basolo , F. 1969 . Inorg. Chem. , 8 : 2231
- Fay , R. C. , Girgis , A. Y. and Klahunde , U. 1970 . J. Am. Chem. Soc. , 92 : 7056
- Girgis , A. Y. and Fay , R. C. 1970 . J. Am. Chem. Soc. , 92 : 7061
- Gordon , J. G. and Holm , R. H. 1970 . J. Am. Chem. Soc. , 92 : 5319
- Edwards , J. O. , Monacelli , F. and Ortaggi , G. 1974 . Inorg. Chim. Acta , 11 : 47
- Archer , R. D. 1969 . Coord. Chem. Rev. , 4 : 243
- Archer , R. D. , Suydam , L. J. and Dollberg , D. D. 1971 . J. Am. Chem. Soc. , 93 : 6837
- Slater , J. C. 1960 . Quantum Theory of Atomic Structure , Vol. I , New York : McGraw-Hill .
- Katriel , J. and Pauncz , R. 1977 . Adv. Quant. Chem. , 10 : 143
- If ΔE = E2 - E1, > 0, the virial condition E + T = 0 imposes ΔT = T2 - T1 < 0: the state with higher total energy has the smaller kinetic energy. This can be accounted for qualitatively by expanding the wave function (scaling procedure) from state 1 to 2. An expansion will also lower the absolute value of the nuclear attraction energy: L2 < L1 and therefore ΔL = L2 - L1 > 0. So, qualitatively, the cancellation idea is sound: ΔT and ΔL have opposite sign. Quantitatively, however, the value of Δ H = ΔT + ΔL is far too different from zero to justify its neglect: in fact, ΔL H is several times Δ C.
- Vanquickenborne , L. G. and Haspeslagh , L. 1982 . Inorg. Chern. , 21 : 2448
- Davidson , E. R. 1965 . J. Chem. Phys. , 42 : 4199
- J⊘rgensen , C. K. 1971 . Modern Aspects of Ligand Field Theory , Amsterdam : Elsevier .
- Wachters , A. J. H. and Nieuwpoort , W. C. 1972 . Phys. Rev. B , 5 : 4291
- Vanquickeborne , L. G. to he published.