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Comments on Inorganic Chemistry
A Journal of Critical Discussion of the Current Literature
Volume 7, 1988 - Issue 4
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Original Articles

Oxyanion Chelates of Cobalt(III). Oxygen Exchange, Chelate Ring Opening and Closing, and Hydrolysis of Monodentates

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Pages 171-193 | Published online: 13 Dec 2006

References

  • Basolo , F. and Pearson , R. G. 1967 . Mechanisms of Inorganic Reactions , Sec. Ed. , 223 – 228 . New York : Wiley . M. L. Tobe, A. P. Schweeb and R. Romeo, Inorg. Chem. 21, 1185 (1982)
  • Keppert , D. L. 1977 . Prog. Inorg. Chem. , 23 : 1
  • Galli , C. , Illuminati , G. , Mandolini , L. and Tamborra , P. 1977 . J. Am. Chem. Soc. , 99 : 2591 For a recent general article see A. J. Kirby, Adv. Phys. Org. Chem. 17, 183 (1980)
  • Buckingham , D. A. and Sutton , P. A. in press . Accounts Chem. Res. , For anhydrides and esters direct addition of coordinated solvent to carbon occurs even in the absence of chelation (i.e. in the formation of monodentate species). For a recent account of both types of reaction with Co(III) complexes see
  • Andrade , C. , Jordan , R. B. and Taube , H. 1970 . Inorg. Chem. , 9 : 711
  • Jackman , L. M. , Dormish , J. F. , Scott , R. M. , Portman , R. H. and Minard , R. D. 1979 . Inorg. Chem. , 18 : 1503
  • Jones , D. R. , Lindoy , L. F. and Sargeson , A. M. 1983 . J. Am. Chem. Soc. , 105 : 7327 have shown exclusive Co-O cleavage in 0.4 mol dm3 NaOH, and we (unpublished data) have shown that chelation of monodentate phosphate at pH 8 occurs entirely by substitution at the metal
  • McKenzie , D. , O'Connor , C. and Odell , A. L. 1966 . J. Chem. Soc. A , : 184
  • Francis , D. J. and Jordan , R. B. 1972 . Inorg. Chem. , 11 : 1170
  • Palmer , D. A. and Van Eldik , R. 1983 . Chem. Rev. , 83 : 651
  • Buckingham , D. A. and Clark , C. R. in press . Aust. J. Chem. ,
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  • Barraclough , C. G. and Tobe , M. L. 1961 . J. Chem. Soc. , : 1993 C. G. Barraclough and R. S. Murray, J. Chem. Soc. 7047 (1965)
  • Buckingham , D. A. , Clark , C. R. , Robinson , W. T. and Simpson , J. S. Inorg. Chem. , submitted
  • Scheidegger , H. A. 1966 . Ph.D. Thesis Zürich : Eigenössichen Technischen Hochschule .

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