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Original Articles

Orientational order of guest molecules in aligned liquid crystal as measured by EPR and UV–vis techniques

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Pages 1135-1145 | Received 27 Nov 2012, Accepted 10 Apr 2013, Published online: 10 May 2013

References

  • Feringa , BL , van Delden , RA , Koumura , N and Geertsema , EM . 2012 . Chiroptical molecular switches . Chem Rev , 100 : 1789 – 1816 .
  • Coles , H and Morris , S. 2010 . Liquid-crystal lasers . Nat Photonics. , 4 : 676 – 685 .
  • Liu , YJ , Zheng , YB , Shi , J , Huang , H , Walker , TR and Huang , TJ. 2009 . Optically switchable gratings based on azo-dye-doped, polymer-dispersed liquid crystals . Opt Lett. , 34 : 2351 – 2353 .
  • Fuh , AY-G , Tsai , M-S , Huang , L-J and Liu , T-C. 1999 . Optically switchable gratings based on films doped with a guest-host dye . Appl Phys Lett. , 74 : 2572 – 2574 .
  • Simoni , F , Cipparrone , G , Mazzulla , A and Pagliusi , P. 1999 . Polymer dispersed liquid crystals: effects of photorefractivity and local heating on holoraphic recording . Chem Phys. , 245 : 429 – 436 .
  • Michl , J and Thulstrup , EW. 1986 . Spectroscopy with polarized light: solute alignment by photoselection in liquid crystals, polymers and membranes , New York , NY : VCH Publishers .
  • Bauman , D , Moryson , H and Wolarz , E. 1994 . Study of nematic order in guest-host mixtures by polarized optical spectroscopy . J Mol Struct. , 325 : 169 – 175 .
  • Bauman , D , Chrzumnicka , E and Wolarz , E. 2000 . Molecular orientation in liquid crystalline side chain polymers doped with dichroic dye as studied by optical spectroscopy methods . Mol Cryst Liq Cryst. , 352 : 67 – 76 .
  • Wolarz , E , Chrzumnicka , E , Fischer , T and Stumpe , J. 2007 . Orientational properties of 1,3,4-oxadiazoles in liquid-crystalline materials determined by electronic absorption and fluorescence measurements . Dyes Pigments. , 75 : 753 – 760 .
  • Chapoy , LL and DuPre , DB. 1979 . Polarized fluorescence measurements of orientational order in a uniaxial liquid crystal . J Chem Phys. , 70 : 2550 – 2553 .
  • Luckhurst , G and Yeates , RN. 1976 . Orientational order of a spin probe dissolved in nematic liquid crystals . J Chem Soc Faraday Trans 2. , 72 : 996 – 1009 .
  • Le Masurier , PJ and Luckhurst , GR. 1998 . Structural studies of the intercalated smectic C phases formed by the non-symmetric α-(4-cyanobiphenyl-4′-yloxy)-ω-(4-alkylanilinebenzylidene-4′-oxy) alkane dimers using EPR spectroscopy . J Chem Soc Faraday Trans. , 94 : 1593 – 1601 .
  • Luckhurst , GR. 2006 . On the creation of director disorder in nematic liquid crystals . Thin Solid Films. , 509 : 36 – 48 .
  • Imrie , CT , Ionescu , D and Luckhurst , GR. 1997 . Molecular organization of the polymer backbone in a side group liquid crystal polymer . An ESR investigation. Macromolecules. , 30 : 4597 – 4600 .
  • Arcioni , A , Bacchiocchi , C , Vecchi , I , Venditti , G and Zannoni , C . 2004 . A comparison of the effects of dispersed hydrophobic or hydrophilic aerosil nanoparticles on the order and dynamics of the 5CB liquid crystal . Chem Phys Lett. , 396 : 433 – 441 .
  • Arcioni , A , Bacchiocchi , C , Vecchi , I , Venditti , G and Zannoni , C. 2002 . Electron spin resonance studies of order and dynamics in a nematic liquid crystal containing a dispersed hydrophobic aerosil . J Phys Chem B. , 106 : 9245 – 9251 .
  • Oganesyan , VS , Kuprusevicius , E , Gopee , H and Cammidge , AN. 2009 . Electron paramagnetic resonance spectra simulation directly from molecular dynamics trajectories of a liquid crystal with a doped paramagnetic spin probe . Phys Rev Lett. , 102 013005-1–013005-4
  • Kuprusevicius , E , Edge , R , Gopee , H , Cammidge , AN , McInnes , EJL , Wilson , MR and Oganesyan , VS. 2010 . Prediction of EPR spectra of liquid crystals with doped spin probes from fully atomistic molecular dynamics simulations: exploring molecular order and dynamics at the phase transition . Chem Eur J. , 16 : 11558 – 11562 .
  • Chami , F , Wilson , MR and Oganesyan , VS. 2012 . Molecular dynamics and EPR spectroscopic studies of 8CB liquid crystal . Soft Matter. , 8 : 6823 – 6833 .
  • Meirovitch , E , Igner , D , Igner , E , Mora , G and Freed , JH. 1982 . Electron-spin relaxation and ordering in smectic and supercooled nematic liquid crystals . J Chem Phys. , 77 : 3915 – 3938 .
  • Wassmer , KH , Ohmes , E , Portugall , M , Ringsdorf , H and Kothe , GJ. 1985 . Molecular order and dynamics of liquid-crystal side-chain polymers: an electron spin resonance study employing rigid nitroxide spin probes . J Am Chem Soc. , 107 : 1511 – 1519 .
  • Xu , D , Budil , DE , Ober , CK and Freed , JH. 1996 . Rotational diffusion and order parameters of a liquid crystalline polymer studied by ESR: molecular weigt dependence . J Phys Chem. , 100 : 15867 – 15872 .
  • Freed , JH. 1976 . “ Theory of slow tumbling ESR spectra for nitroxides ” . In Spin labeling: theory and applications , Edited by: Berliner , LJ . 53 – 132 . New York , NY : Plenum .
  • Schneider , DJ and Freed , JH . 1989 . “ Calculating slow motional magnetic resonance spectra. A user's guide ” . In Biological magnetic resonance , Edited by: Berliner , LJ and Reuben , J . 1 – 75 . New York , NY : Plenum .
  • AKh , Vorobiev and Chumakova , NA. 2005 . Determination of orientation distribution function of anisotropic paramagnetic species by analysis of ESR spectra angular dependence . J Magn Reson. , 175 : 146 – 157 .
  • Yankova , TS , AYu , Bobrovsky and AKh , Vorobiev . 2012 . Order parameters P2, P4 and P6 of aligned nematic liquid-crystalline polymer as determined by numerical simulation of electron paramagnetic resonance spectra . J Phys Chem B. , 116 : 6010 – 6016 .
  • Chumakova , NA and AKh , Vorobiev . 2012 . Simulation of rigid-limit and slow-motion EPR spectra for extraction of quantitative dynamic and orientational information. In: Kokorin AI, editor. Nitroxides – theory, experiment and applications [Internet] . Rijeka: InTech , : 57 – 112 . Available from: http://dx.doi.org/10.5772/48067, ISBN 978-953-51-0722-4. [cited 2013 Apr 30]; p
  • AKh , Vorobiev , Yankova , TS and Chumakova , NA. 2012 . Orientation distribution function and order parameters of oriented spin probe . Chem Phys. , 409 : 61 – 73 .
  • Imazeki , S , Mukoh , A , Tanaka , N and Kinoshita , M. 1993 . Unusual orientational behavior of anthraquinone dyes in nematic cyanophenylcyclohexane derivatives . Mol Cryst Liq Cryst. , 225 : 197 – 210 .
  • Vecchi , I , Arcioni , A , Bacchiocchi , C , Tiberio , G , Zanitaro , P and Zannoni , C. 2007 . Expected and unexpected behavior of the orientational order and dynamics induced by azobenzene solutes in a nematic . J Phys Chem B. , 111 : 3355 – 3362 .
  • Chigrinov , VG , Kozenkov , VM and Kwok , H-S. Photoalignment of liquid crystalline materials , West Sussex : Wiley; 2008 .
  • Fischer , Th , Laesker , L , Stumpe , J and Kostromin , SG . 1994 . Photoinduced optical anisotropy in films of photochromic liquid crystalline polymers . J Photochem Photobiol A , 80 : 453 – 459 .
  • Nakatsuji , S , Fujino , M , Hasegawa , S , Akutsu , H , Yamada , J and Gurman , VS . 2007 . Vorobiev Akh. Azobenzene derivatives carrying a nitroxide radical . J Org Chem. , 72 : 2021 – 2029 .
  • Elyashevich , G , Kozlov , A and Moneva , I. 1998 . Study of polyethylene orientation in the course of porous structure formation . Polym Sci, Ser B. , 40 : 71 – 74 .
  • Bobrovsky , A , Shibaev , V , Elyashevitch , G , Rosova , E , Shimkin , A , Shirinyan , V , Bubnov , A , Kaspar , M , Hamplova , V and Glogarova , M. 2008 . New photosensitive polymer composites based on oriented porous polyethylene filled with azobenzene-containing LC mixture: reversible photomodulation of dichroism and birefringence . Liq Cryst. , 35 : 533 – 539 .
  • Bobrovsky , A , Shibaev , V , Elyashevich , G , Rosova , E , Shimkin , A , Shirinyan , V and Cheng , K-L. 2010 . Photocromic composites based on porous stretched polyethylene filled by nematic liquid crystal mixtures . Polym Adv Technol. , 21 ( 2 ) : 100 – 112 .
  • Dennis , JE , Gay , DM and Welsch , RE. 1981 . An adaptive nonlinear least-squares algorithm . ACM Trans Math Software. , 7 : 348 – 368 .
  • Zannoni , C. 1979 . “ Distribution functions and order parameters ” . In The molecular physics of liquid crystals , Edited by: Luckhurst , GR and Gray , GW . 51 – 83 . New York , NY : Academic Press .
  • Blinov , L. Structure and properties of liquid crystals , 2011 New York , NY : Springer Science Business Media B.V .
  • Budil , DE , Lee , S , Saxena , S and Freed , JH. 1996 . Nonlinear-least-squares analysis of slow-motion EPR spectra in one and two dimensions using a modified Levenberg-Marquardt algorithm . J Magn Reson A. , 120 : 155 – 189 .
  • Cusati , T , Granucci , G , Persico , M and Spighi , G. 2008 . Oscillator strength and polarization of the forbidden n→π* band of trans-azobenzene: a computational study . J Chem Phys. , 128 : 194312-1 – 194312-9 .
  • Cusati , T , Granucci , G , Martínez-Nunez , E , Martini , F , Persico , M and Vazquez , S. 2012 . Semiempirical hamiltonian for simulation of azobenzene photochemistry . J Phys Chem A. , 116 : 98 – 110 .
  • Weingart , O , Lan , Z , Koslowski , A and Thiel , W. 2011 . Chiral pathways and periodic decay in cis-azobenzene photodynamics . J Phys Chem Lett. , 2 : 1506 – 1509 .

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