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Research Article

Unusual electric-field-induced transformations in the dark conglomerate phase of a bent-core liquid crystal

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Pages 800-811 | Received 17 Dec 2013, Accepted 16 Jan 2014, Published online: 06 Feb 2014

References

  • Ros MB, Serrano JL, de la Fuente MR, Folcia CL. Banana-shaped liquid crystals: a new field to explore. J Mater Chem. 2005;15:5093–5098.
  • Takezoe H, Takanishi Y. Bent-core liquid crystals: their mysterious and attractive world. Jpn J Appl Phys. 2006;45:597–625.
  • Reddy R, Tschierske C. Bent-core liquid crystals: polar order, superstructural chirality and spontaneous desymmetrisation in soft matter systems. J Mater Chem. 2006;16:907–961.
  • Link DR, Natale G, Shao R, Maclennan JE, Körblova E, Clark NA, Walba DM. Spontaneous formation of macroscopic chiral domains in a fluid smectic phase of achiral molecules. Science. 1997;278:1924–1927.
  • Alaasar M, Prehm M, Nagaraj M, Vij JK, Tschierke C. A liquid crystalline phase with uniform tilt, local polar order and capability of symmetry breaking. Adv Mater. 2013;25:2186–2191.
  • Hough LE, Clark NA. Layer-scale optical chirality of liquid crystalline phases. Phys Rev Lett. 2005;95:107802-1-4.
  • Niwano H, Nakata M, Thisayukta J, Link DR, Takezoe H, Watanabe J. Chiral memory on transition between the B2 and B4 phases in an achiral banana-shaped molecular system. J Phys Chem B. 2004;108:14889–14896.
  • Hough LE, Jung HT, Krüerke D, Heberling MS, Nakata M, Jones CD, Chen D, Link DR, Zasadzinski J, Heppke G, Rabe JP, Stocker W, Körblova E, Walba DM, Glaser MA, Clark NA. Helical nanofilament phases. Science. 2009;325:456–460.
  • Walba DM, Eshdat L, Körblova E, Shoemaker RK. On the nature of the B4 banana phase: crystal or not a crystal. Cryst Growth Des. 2005;5:2091–2099.
  • Dantlgraber G, Eremin A, Diele S, Hauser A, Kresse H, Pelzl G, Tschierske C. Chirality and macroscopic polar order in a ferroelectric smectic liquid crystalline phase formed by achiral polyphilic bent-core molecules. Angew Chem Int Ed. 2002;41:2408–2412.
  • Dantlgraber G, Diele S, Tschierske C. The first liquid crystalline dimers consisting of two banana-shaped mesogenic units: a new way for switching between ferroelectricity and antiferroelectricity with bent-core molecules. Chem Commun. 2002;2768–2769.
  • Thisayukta J, Nakeyama Y, Kawauchi S, Takezoe H, Watanabe J. Distinct formation of a chiral smectic phase in achiral banana-shaped molecules with a central core based on a 2,7-dihydroxynaphthalene unit. J Am Chem Soc. 2000;122:7441–7448.
  • Ortega J, Folcia CL, Etxbarria J, Gimeno N, Ros MB. Interpretation of unusual textures in the B2 phase of a liquid crystal composed of bent-core molecules. Phys Rev E. 2003;68:011707-1-4.
  • Ortega J, Folcia CL, Etxebarria J, Gimeno N, Ros MB. Interpretation of unusual textures in the B2 phase of a liquid crystal composed of bent-core molecules. Phys Rev E. 2003;68:11707-1-4.
  • Zhang Y, Baumeister U, Tschierske C, O’Callaghan MJ, Walker C. Achiral bent-core molecules with a series of linear or branched carbosilane termini: dark conglomerate phases, supramolecular chirality and macroscopic polar order. Chem Mater. 2010;22:2869–2884.
  • Weissflog W, Schröder MW, Diele S, Pelzl G. Field induced formation of the polar SmCP phase above the SmCP-Isotropic transition. Adv Mater. 2003;15:630–633.
  • Wirth I, Diele S, Eremin A, Pelzl G, Grande S, Kovalenko L, Pancenko N, Weissflog W. New variants of polymorphism in banana-shaped mesogens with cyano-substituted central core. J Mater Chem. 2001;11:1642–1650.
  • Lee SK, Shi L, Tokita M, Takezoe H, Watanabe J. Chirality transfer between weakly birefringent and electric-field-induced highly birefringent B2 phases in a bent-core mesogen. J Phys Chem B. 2007;111:8698–8701.
  • Chen D, Shao R, Maclennan JE, Glaser MA, Korblova E, Walba DM, Gimeno N, Ros MB, Clark NA. Topography of bent-core liquid crystals at the air/liquid crystal interface. Liq Cryst. 2013;40:1730–1735.
  • Ocak H, Eran BB, Prehm M, Tschierkse C. Effects of molecular chirality on superstructural chirality in liquid crystalline dark conglomerate phases. Soft Matter. 2012;8:7773–7783.
  • Yan F, Hixson CA, Earl DJ. Computer simulations of linear rigid particles that form chiral superstructures and tilted smectic phases. Soft Matter. 2009;5:4477–4483.
  • Kawauchi S, Choi S-W, Fukuda K, Kishikawa K, Watanabe J, Takezoe H. Why achiral rod-like compound with ester group amplifies chiral power in chiral mesophase. Chem Lett. 2007;36:750–751.
  • Earl D, Osipov MA, Takezoe H, Takanishi Y, Wilson MR. Induced and spontaneous deracemization in bent-core liquid crystal phases and in other phases doped with bent-core molecules. Phys Rev E. 2005;71:021706-1-11.
  • Takezoe H. Spontaneous achiral symmetry breaking in liquid crystalline phases. Top Curr Chem. 2012;318:303–330.
  • Jeong HS, Tanaka S, Yoon DK, Choi S-W, Kim YH, Kawauchi S, Araoka F, Takezoe H, Jung H-T. Spontaneous chirality induction and enantiomer separation in liquid crystals composed of achiral rod-shaped 4-arylbenzoate esters. J Am Chem Soc. 2009;131:15055–15060.
  • Kurosu H, Kawasaki M, Hirose M, Yamada M, Kang S, Thisayukta J, Sone M, Takezoe H, Solid-state WJ. C-13 NMR study of chiral twisted conformation attributable to chirality in smectic phases of achiral banana-shaped molecules. J Phys Chem A. 2004;108:4674–4678.
  • Keith C, Reddy RA, Prehm M, Baumeister U, Kresse H, Chao JL, Hahn H, Lang H, Tschierske C. Layer frustration, polar order and chirality in liquid crystalline phases of silys-terminated achiral bent-core molecules. Chem Eur J. 2007;13:2556–2577.
  • Hough LE, Jung HT, Krüerke D, Heberling MS, Nakata M, Jones CD, Chen D, Link DR, Zasadzinski J, Heppke G, Rabe JP, Stocker W, Körblova E, Walba DM, Glaser MA, Clark NA. Chiral isotropic liquids from achiral molecules. Science. 2009;325:452–456.
  • Chen D, Shen Y, Zhu C, Hough LE, Gimeno N, Glaser MA, Maclennan JE, Ros MB, Clark NA. Interface structure of the dark conglomerate liquid crystal phase. Soft Matter. 2011;7:1879–1883.
  • Görtz V, Southern CD, Roberts NW, Gleeson HF, Goodby JW. Unusual properties of a bent-core liquid-crystalline fluid. Soft Matter. 2009;5:463–471.
  • Southern CD, Brimicombe PD, Siemianowski SD, Jaradat S, Roberts N, Görtz V, Goodby JW, Gleeson HF. Thermotropic biaxial nematic order parameters. Europhys Lett. 2008;82:56001-1-6.
  • Kaur S, Belaissaoui A, Goodby JW, Görtz V, Gleeson HF. Nonstandard electroconvection in a bent-core oxadiazole material. Phys Rev E. 2011;83:041704-1-12.
  • Kaur S, Addis J, Greco C, Ferrarini V, Görtz V, Goodby JW, Gleeson HF. Understanding the distinctive elastic constants in an oxadiazole bent-core nematic liquid crystal. Phys Rev E. 2012;86:041703-1-11.
  • Kaur S, Liu H, Addis J, Greco C, Ferrarini V, Görtz V, Goodby JW, Gleeson HF. The influence of structure on the elastic, optical and dielectric properties of nematic phases formed from bent-core molecules. J Mater Chem C. 2013;1:6667–6676.
  • Southern CD. Order parameter measurements and phase behaviour in bent core liquid crystal systems [PhD thesis]. Manchester: University of Manchester; 2008.
  • Dierking I. Textures of liquid crystals. Weinheim: Wiley-VCH Verlag; 2003.
  • Choi SW, Kang S, Takanishi Y, Ishikawa K, Watanabe J, Takezoe H. Intrinsic chiral domains enatioselectively segregated from twisted nematic cells of bent-core mesogens. Chirality. 2007;19:250–254.
  • Yoon HG, Roberts NW, Gleeson HF. An experimental investigation of discrete changes in pitch in a thin, planar chiral nematic device. Liq Cryst. 2006;33:503–510.
  • Polak RD, Crawford GP, Kostival BC, Doane JW, Žumer S. Optical determination of the saddle-splay elastic constant K24 in nematic liquid crystals. Phys Rev E. 1994;49:R978–R980.
  • Pergamenshchik VM, Žumer S. Surface variations of the density and scalar order parameter and the elastic constants of a uniaxial nematic phase. Phys Rev E. 1995;59:R2531–R2534.
  • Barbero G, Pergamenshchik VM. Intermediate periodic saddle-splay nematic phase in the vicinity of a nematic-smectic-A transition. Phys Rev E. 2002;66:051706-1-10.
  • Tian L, Goodby JW, Görtz V, Gleeson HF. The magnitude and temperature dependence of the Kerr constant in liquid crystal blue phases and the dark conglomerate phase. Liq Cryst. 2013;40:1446–1454.
  • Nagaraj M, Görtz V, Goodby JW, Gleeson HF. Electrically tunable refractive index in the dark conglomerate phase of a bent-core liquid crystal. Appl Phys Lett. 2014;104:021903–1–5.

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