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Invited Article

The magic of cyanobiphenyls: celebrity molecules

Pages 678-687 | Received 11 Oct 2014, Published online: 27 Mar 2015

References

  • Gray GW. Reminiscences from a life with liquid crystals. Liq Cryst. 1998;24:5–14. doi:10.1080/026782998207523.
  • Bevan TDC, Manninen AJ, Cook JB, Hook JR, Hall HE, Vachaspati T, Volovik GE. Momentum creation by vortices in superfluid 3He as a model of primordial baryogenesis. Nature. 1997;386:689–692. doi:10.1038/386689a0.
  • Vorländer D. Einfluß der molekularen Gestalt auf den krystallinisch-flüssigen Zustand (Influence of the molecular structure on the crystalline-liquid state). Berichte Der Deutschen Chemischen Gesellschaft. 1907;40:1970–1972 (translated in Sluckin TJ, Dunmur DA, Stegemeyer H, Crystals that flow: classic papers from the history of liquid crystals, 2004; Taylor and Francis, London and New York: 84-87.). doi:10.1002/cber.190704002101
  • Gray GW. Advances in synthesis and the role of molecular geometry in liquid crystallinity. Mol Cryst Liq Cryst. 1969;7:127–151. doi:10.1080/15421406908084868.
  • Kelker H, Scheuble B. A liquid-crystalline (nematic) phase with a particularly low solidification point. Angew Chem Int Ed. 1969;8:884–885. doi:10.1002/anie.196908841.
  • Cummins PG, Dunmur DA, Jessup NE. The dielectric properties of nematic MBBA in the presence of electric and magnetic fields. In: Johnson JF, Porter RS, editors. Liquid crystals and ordered fluids Vol. 2. New York (NY): Plenum Press; 1974. p. 341–350.
  • Gray GW, Harrison KJ, Nash JA, Constant J, Hulme DS, Kirton J, Raynes EP. Stable, low melting nematogens of positive dielectric anisotropy for display devices. In: Johnson JF, Porter RS, editors. Liquid crystals and ordered fluids Vol. 2. New York (NY): Plenum Press; 1974. p. 617–643.
  • Gray GW, Harrison KJ, Nash JA. New family of nematic liquid crystals for displays. Electron Lett. 1973;9:130–131. doi:10.1049/el:19730096.
  • Hilsum C. The anatomy of a discovery – biphenyl liquid crystals. In: Howells ER, editor. Technology of chemicals and materials for electronics. Chichester: Ellis Horwood; 1984. p. 43–58.
  • Szivessy G. Zur Bornschen Dipolstheorie der anisotropen Flüssigkeiten (On Born’s dipole theory of anisotropic fluids). Zeit Für Physik. 1925;34:474–484. doi:10.1007/BF01328490.
  • Dunmur DA, Palffy-Muhoray P. A mean field theory of dipole-dipole correlation in nematic liquid crystals. Mol Phys. 1992;76:1015–1023. doi:10.1080/00268979200101821.
  • Ashford A, Constant J, Kirton J, Raynes EP. Electro-optic performance of a new room-temperature nematic liquid crystal. Electron Lett. 1973;9:118–120. doi:10.1049/el:19730086.
  • Cummins PG, Dunmur DA, Laidler DA. The dielectric properties of nematic 4-4ʹ-n-pentylcyanobiphenyl. Mol Cryst Liq Cryst. 1975;30:109–123. doi:10.1080/15421407508082846.
  • Dunmur DA, Manterfield MR, Miller WH, Dunleavy JK. The dielectric and optical properties of the homologous series of cyano-alkyl-biphenyl liquid crystals. Mol Cryst Liq Cryst. 1978;45:127–144. doi:10.1080/00268947808084998.
  • Dunmur DA, Miller WH. Volumetric studies of the homologous series of alkyl-cyano-biphenyl liquid crystals. J De Phys. 1979;40:141–146.
  • Dunmur DA, Fukuda A, Luckhurst GR, editors. Physical properties of liquid crystals: nematics. EMIS data review series no. 25. London: INSPEC, Institution of Electrical Engineers; 2001.
  • Hulme DS, Raynes EP, Harrison KJ. Eutectic mixtures of nematic 4ʹ-substituted 4-cyanobiphenyls. J Chem Soc Chem Commun. 1974;98–99. doi:10.1039/c39740000098.
  • Gray GW, Harrison KJ, Nash JA, Raynes EP. New cholesteric liquid crystals for displays. Electron Lett. 1973;9:616–617. doi:10.1049/el:19730454.
  • Gray GW, McDonnell DG. Synthesis and liquid crystal properties of chiral alkyl-cyano-biphenyls (and some –p-terphenyls) and of some relate chiral compounds derived from biphenyl. Mol Cryst Liq Cryst. 1976;37:189–211. doi:10.1080/15421407608084356.
  • Bernschneider-Reif S, Becker W, editors. The history of the future: a 100 years of liquid crystals at Merck. Darmstadt: Merck KGaA; 2004.
  • Bernschneider-Reif S, Becker W, editors. Coincidence and courage: 40 years of liquid crystals research at Merck. Darmstadt: Merck KGaA; 2008.
  • Castellano JA. Liquid gold. Singapore: World Scientific; 2005.
  • Dunmur DA, Sluckin TJ. Soap, science and flat-screen TVs. Oxford: Oxford University Press; 2011.
  • Roviello A, Sirigu A. Mesophasic structures in polymers. A preliminary account on the mesophases of some poly-alkanoates of the p,p’-dihydroxy-α,α’-di-methyl benzalazine. J Polym Sci B: Polym Lett. 1975;13:455–463.
  • Finkelmann H, Ringsdorf H, Wendorff JH. Model considerations and examples of enantiotropic liquid crystalline polymers. Makromol Chem. 1978;179:273–276. doi:10.1002/macp.1978.021790129.
  • Imrie CT, Karasz FE, Attard GS. Effect of backbone flexibility on the transitional properties of side-chain liquid-crystalline polymers. Macromol. 1993;26:3803–3810. doi:10.1021/ma00067a013.
  • Guichard B, Poirier V, Noël C, Reyx D, Le Borgne A, Leblance M, Large M, Kajzar F. Synthesis and characterization of polyoxetanes containing 4-cyanobiphenyl-based side groups for nonlinear optical applications. Macromol Chem Phys. 1996;197:3631–3656. doi:10.1002/macp.1996.021971112.
  • Richardson R, Ponomarenko SA, Boiko NI, Shibaev VP. Liquid crystalline dendrimer of the fifth generation: from lamellar to columnar structure in thermotropic mesophases. Liq Cryst. 1999;26:101–108. doi:10.1080/026782999205605.
  • Baars MWPL, Söntjens SHM, Fischer HM, Peerlings HWI, Meijer EW. Liquid-crystalline properties of poly(propylene imine) dendrimers functionalized with cyanobiphenyl mesogens at the periphery. Chem Eur J. 1998;4:2456–2466. doi:10.1002/(SICI)1521-3765(19981204)4:12<2456::AID-CHEM2456>3.0.CO;2-L.
  • Dardel B, Guillon D, Heinrich B, Deschenaux R. Fullerene-containing liquid-crystalline dendrimers. J Mater Chem. 2001;11:2814–2831. doi:10.1039/b103798f.
  • Draper M, Saez IM, Cowling SJ, Gai P, Heinrich B, Donnio B, Guillon D, Goodby JW. Self-assembly and shape morphology of liquid-crystalline gold metamaterials. Adv Funct Mater. 2011;21:1260–1278. doi:10.1002/adfm.201001606.
  • Bruce DW, Lalinde E, Styring P, Dunmur DA, Maitlis PM. Novel transition metal-containing nematic and smectic liquid crystals. J Chem Soc Chem Commun. 1986;581–582. doi:10.1039/c39860000581.
  • Adams H, Bailey NA, Bruce DW, Dunmur DA, Lalinde E, Marcos M, Ridgway C, Smith AJ, Styring P, Maitlis PM. Mesogenic transition metal complexes. Liquid crystal phase behaviour and crystal and molecular structure of some nitrile complexes of the platinum metals. Liq Cryst. 1987;2:381–393. doi:10.1080/02678298708086683.
  • Pucci D, Donnio B. Metal-containing liquid crystals. In: Goodby JW, Collings PJ, Kato T, Tschierske C, Gleeson HF, Raynes P, editors. Handbook of liquid crystals. 2nd ed, Vol. 5. Weinheim: Wiley-VCH; 2014. p. 175–241.
  • Barnes PJ, Douglass AG, Heeks SK, Luckhurst GR. An enhanced odd-even effect of liquid crystal dimers orientational order in the α,ω-bis(4′-cyanobiphenyl-4-yl)alkanes. Liq Cryst. 1993;13:603–613. doi:10.1080/02678299308026332.
  • Emsley JW, Luckhurst GR, Shilstone GN, Sage I. The preparation and properties of the α,ω-bis(44′-cyanobiphenyloxy)alkanes: nematogenic molecules with a flexible core. Mol Cryst Liq Cryst. 1984;102:223–233. doi:10.1080/01406568408070532.
  • Imrie CT, Luckhurst GR. Liquid crystal dimers and oligomers. In: Goodby JW, Collings PJ, Kato T, Tschierske C, Gleeson HF, Raynes P, editors. Handbook of liquid crystals. 2nd ed. Vol. 7. Weinheim: Wiley-VCH; 2014. p. 137–210.
  • Imrie CT, Luckhurst GR. Liquid crystal trimers. The synthesis and characterisation of the4,4′-bis[ω-(4-cyanobiphenyl-4′-yloxy)alkoxy]biphenyls. J Mater Chem. 1998;8:1339–1343. doi:10.1039/a801128a.
  • Mehl GH, Goodby JW. Substituted siloxysilanes and the structure of oligomeric liquid crystals. Chem Commun. 1999;1999:13–14. doi:10.1039/a807549b.
  • Lunkwitz R, Tschierske C, Diele S. Formation of smectic and columnar liquid crystalline phases by cyclotriveratrylene (CTV) and cyclotetraveratrylene (CTTV) derivatives incorporating calamitic structural units. J Mater Chem. 1997;7:2001–2011. doi:10.1039/a702034a.
  • Cestari M, Diez-Berart S, Dunmur DA, Ferrarini A, De La Fuente MR, Jackson DJB, Lopez DO, Luckhurst GR, Perez-Jubindo MA, Richardson RM, Salud J, Timimi BA, Zimmermann H. Phase behaviour and properties of the liquid crystal dimer 1ʹ’,7ʹ’-bis(4-cyanobiphenyl-4ʹ-yl)heptane: a twist-bend nematic liquid crystal. Phys Rev E. 2011;84:031704-1-20. doi:10.1103/PhysRevE.84.031704.
  • Meyer RB. Structural problems in liquid crystal physics. In: Balian R, Weil G, editors. Les Houches summer school in theoretical physics, 1973. New York (NY): Gordon and Breach; 1976. p. 273–343.
  • Dozov I. On the spontaneous symmetry breaking in the mesophases of achiral banana-shaped molecules. Europhys Lett. 2001;56:247–253. doi:10.1209/epl/i2001-00513-x.
  • Wilson MR. Calculation of nematic mesophase properties using realistic potentials. In: Dunmur DA, Fukuda A, Luckhurst GR, editors. Physical properties of liquid crystals: nematics. EMIS data review series no. 25. London: INSPEC, Institution of Electrical Engineers; 2001. p. 635–643.
  • Picken SJ, Van Gunsteren WF, Van Duijnen P, De Jeu WH. A molecular dynamics study of the nematic phase of 4-n-pentyl-4ʹ-cyanobiphenyl. Liq Cryst. 1989;6:357–371. doi:10.1080/02678298908029087.
  • Cacelli I, Prampolini G, Tani A. Atomistic simulation of a nematogen using a force field derived from quantum chemical calculations. J Phys Chem. 2005;109:3531–3538. doi:10.1021/jp045716l.
  • Capar MI, Nar A, Ferrarini A, Frezza E, Greco C, Zakharov AV, Valulenko AA. Molecular structure and elastic properties of thermotropic liquid crystals: integrated molecular dynamics—statistical mechanical theory vs molecular field approach. J Chem Phys. 2013;138:114902-1-8. doi:10.1063/1.4794920.

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