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Articles

Low-temperature dynamics of (S)-4-(1-methylheptyloxy)-4ʹ-cyanobiphenyl (8*OCB) and (S)-4-(2-methylbutyl)-4ʹ-cyanobiphenyl (5*CB) in disordered crystalline and glassy phases

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Pages 94-101 | Received 23 Feb 2018, Accepted 29 Apr 2018, Published online: 15 May 2018

References

  • Angell CA. Formation of glasses from liquids and biopolymers. Science. 1995;267:1924–1935.
  • Sorai M, Seki S. Heat capacity of N-(o-Hydroxy-p-Methoxybenzylidene)-p-Butylaniline: a glassy nematic liquid crystal. Mol Cryst Liq Cryst. 1973;23:299–327.
  • Juszynska E, Massalska-Arodź M, Zieliński PM, et al. DSC studies of neohexanol and its isomers. Phase Transitions. 2006;79:899–909.
  • Massalska-Arodz M, Williams G, Smith IK, et al. Molecular dynamics and crystallization behaviour of isopentylcyanobiphenyl as Studied by dielectric relaxation spectroscopy. J Chem Soc Faraday Trans. 1998;94:387–394.
  • Vogel H. Phys Z. 1921;22:645–646.
  • Fulcher SG. Analysis of recent measurements of the viscosity of glasses. J Am Ceram Soc. 1925;8:339–355.
  • Tammann G, Hesse W. Die Abhängigkeit der Viscosität von der Temperatur bei unterkühlten Flüssigkeiten. Anorg Allg Chem. 1926;156:245–257.
  • Johari GP, Goodby JW. Dielectric relaxations in a supercooled liquid and glassy smectic phase. J Chem Phys. 1982;77:5165–5172.
  • Buchenau U. Neutron scattering at the glass transition. In: Riste T, Sherrington D, editors.Phase transitions and relaxation in systems with competing energy scales. Dordrecht: Kluwer Academic Press; 1993. p. 233–257.
  • Wuttke J, Hernandez J, Li G, et al. Neutron and light scattering study of supercooled glycerol. Phys Rev Lett. 1994;72:3052–3055.
  • Yamamuro O, Harabe K, Matsuo T, et al. Boson peaks of glassy mono- and polyalcohols studied by inelastic neutron scattering. J Phys: Condens Matter. 2000;12:5143–5154.
  • Novikov VN, Sokolov AP. Poisson’s ratio and the fragility of glass-forming liquids. Nature. 2004;431:961–963.
  • Greaves GN, Meneau F, Majerus O, et al. Identifying vibrations that destabilize crystals and characterize the glassy state. Science. 2005;308:1299–1303.
  • Schirmacher W. The boson peak. Phys Status Solidi B. 2013;250:937.
  • Mayer J, Krawczyk J, Massalska-Arodź M, et al. Neutron-scattering study of low-energy excitations in some organic glass formers. Physica B. 2006;371:249–256.
  • Anderson PW, Halperin BI, Varma CM. Anomalous low-temperature thermal properties of glasses and spin glasses. Phil Mag. 1972;25:1–9.
  • Phillips WA. Tunneling states in amorphous solids. J Low Temp Phys. 1972;7:351.
  • Ackerman DA, Moy D, Potter RC, et al. Glassy behavior of crystalline solids at low temperatures. Phys Rev B. 1981;23:3886–3993.
  • Phillips WA. Two-level states in glasses. Rep Prog Phys. 1987;50:1657–1708.
  • Pohl RO, Liu X, Thompson E. Low-temperature thermal conductivity and acoustic attenuation in amorphous solids. Rev Mod Phys. 2002;74:991–1014.
  • Leslie-Pelecky D, Birge N. Dielectric measurements of themodel glass transition in orientationally disordered cyclo-octanol. Phys Rev B. 1994;18:13250–13258.
  • Chen W, Wunderlich B. Nanophase separation of small and large molecules, invited feature article. Macromol Chem Phys. 1999;200:283–311.
  • Massalska-Arodź M, Ściesińska E, Ściesiński J, et al. Organic glass formers with elongated molecules as studied by dielectric and complementary methods. In: Galewski Z, Sobczyk L, editors. Dielectric properties of liquid crystals. India: Transworld Research Network; 2007. p. 159–182.
  • Jasiurkowska M, Juszyńska E, Kolek Ł, et al. Signatures of glass transition in partially ordered phases. Liq Cryst. 2013;40:1442–1463.
  • Inaba A, Suzuki H, Krawczyk J, et al. Disorder in crystalline phases of chiral glass formers 5*CB and 8*OCB evidenced by the low temperature heat capacity. Chem Phys Lett. 2008;463:90–93.
  • Suzuki H, Inaba A, Krawczyk J, et al. Thermodynamic properties of chiral liquid crystalline material (S)-4-(2-methylbutyl)-4ʹ-cyanobiphenyl (5*CB). J Chem Thermodyn. 2008;40:1232–1242.
  • Mayer J, Witko W, Massalska-Arodź M, et al. Polymorphism of right handed (S) 4-(2-Methylbutyl) 4ʹ-Cyanobiphenyl. Phase Transitions. 1999;69:199–213.
  • Mayer J, Massalska-Arodź M, Krawczyk J. Calorimetric and dielectric studies of relaxation accompanying a glass transition in the chiral 5*CB. Mol Cryst Liq Cryst. 2001;366:211–220.
  • Inaba A, Massalska-Arodź M, Suzuki H, et al. (S)-4-(2-methylbutyl)-4ʹ-cyanobiphenyl (5*CB) glass former: are the crystalline polymorphs ordered? Mol. Cryst Liq Cryst. 2011;540:102–110.
  • Saito K, Massalska-Arodź M, Ikeuchi S, et al. Thermodynamic study on a chiral glass former, 4-(1-Methylheptyloxy)-4ʹ-Cyanobiphenyl. JPhys Chem B. 2004;108:5785–5790.
  • Ściesiński J, Ściesińska E, Massalska-Arodź M. Scanning mode of the upgraded FTS-14 digilab spectrometer - study of 8*OCB polymorphism. J Mol Struct. 2001;596:229–234.
  • Massalska-Arodź M, Williams G, Thomas DK, et al. Molecular dynamics and crystallization behaviour of chiral isooctyloxycyanobiphenyl as studied by dielectric relaxation spectroscopy. J Phys Chem B. 1999;103:4197–4205.
  • Ściesiński J, Ściesińska E, Massalska-Arodź M, et al. Polymorphism of righthanded octyloxycyanobiphenyl. IEEE T Dielect El In. 2001;8:522–526.
  • Witko W, Ściesiński J, Ściesińska E, et al. Studies of polymorphism of right handed (S)4-(2 Methylbutyl)-4ʹ-Cyanobiphenyl. Mol Cryst Liq Cryst. 1999;330:391–399.
  • Suzuki H, Inaba A, Krawczyk J, et al. Quasi-elastic neutron scattering of cyanobiphenyl compounds with different terminal chains. J Non Cryst Solids. 2011;357:734–739.
  • Inaba A, Suzuki H, Krawczyk J, et al. Unpublished results.
  • Heinz Maier-Leibnitz Zentrum. SPHERES: backscattering spectrometer. J Large-Scale Res Facil. 2015;1:A30.

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